Synthesis of CuⅡ/ZIF-8 Metal-organic Framework Catalyst and Its Application in the Aerobic Oxidation of Alcohols

doi:10.1007/s40242-019-9133-2

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (5): 860-865.doi: 10.1007/s40242-019-9133-2

Synthesis of Cu^Ⅱ/ZIF-8 Metal-organic Framework Catalyst and Its Application in the Aerobic Oxidation of Alcohols

HOU Junying, HAO Jianjun, WANG Yaya, LIU Jingchun

College of Mechanical and Electrical Engineering, Agricultural University of Hebei Province, Baoding 071001, P. R. China

收稿日期:2019-05-10 出版日期:2019-10-01 发布日期:2019-09-24
通讯作者: HOU Junying E-mail:junyinghou@126.com
基金资助:
Supported by the Research Foundation of Agriculture University of Hebei for Talented Scholars, China(No.YJ201815) and the Scientific and Technology Fund of Agriculture University of Hebei, China(No.LG201817).

Synthesis of Cu^Ⅱ/ZIF-8 Metal-organic Framework Catalyst and Its Application in the Aerobic Oxidation of Alcohols

HOU Junying, HAO Jianjun, WANG Yaya, LIU Jingchun

College of Mechanical and Electrical Engineering, Agricultural University of Hebei Province, Baoding 071001, P. R. China

Received:2019-05-10 Online:2019-10-01 Published:2019-09-24
Contact: HOU Junying E-mail:junyinghou@126.com
Supported by:
Supported by the Research Foundation of Agriculture University of Hebei for Talented Scholars, China(No.YJ201815) and the Scientific and Technology Fund of Agriculture University of Hebei, China(No.LG201817).

摘要/Abstract

摘要： The three-dimensional copper-doped zeolitic imidazolate framework ZIF-8(Cu^Ⅱ/ZIF-8) was prepared by a metal ion exchange process, using reaction of three different copper salts, zinc nitrate hexahydrate[Zn(NO)₃·6H₂O] and 2-methylimidazole(2-MeIM) under nitrogen atmosphere at the room temperature. The TEM and PXRD results indicated that the morphology of Cu^Ⅱ/ZIF-8 was rhombic dodecahedron and the structure was intact after copper was doped into the porous ZIF-8. The synthesized Cu(NO₃)₂/ZIF-8 heterogeneous catalyst showed an excellent activity for the aerobic oxidation of primary alcohols employing molecular oxygen as oxidant. Moreover, the Cu(NO₃)₂/ZIF-8 heterogeneous catalyst can cycled 15 times without leaching of copper.

关键词: Metal organic framework, Heterogeneous catalyst, Molecular oxygen

Abstract: The three-dimensional copper-doped zeolitic imidazolate framework ZIF-8(Cu^Ⅱ/ZIF-8) was prepared by a metal ion exchange process, using reaction of three different copper salts, zinc nitrate hexahydrate[Zn(NO)₃·6H₂O] and 2-methylimidazole(2-MeIM) under nitrogen atmosphere at the room temperature. The TEM and PXRD results indicated that the morphology of Cu^Ⅱ/ZIF-8 was rhombic dodecahedron and the structure was intact after copper was doped into the porous ZIF-8. The synthesized Cu(NO₃)₂/ZIF-8 heterogeneous catalyst showed an excellent activity for the aerobic oxidation of primary alcohols employing molecular oxygen as oxidant. Moreover, the Cu(NO₃)₂/ZIF-8 heterogeneous catalyst can cycled 15 times without leaching of copper.

Key words: Metal organic framework, Heterogeneous catalyst, Molecular oxygen

HOU Junying, HAO Jianjun, WANG Yaya, LIU Jingchun. Synthesis of Cu^Ⅱ/ZIF-8 Metal-organic Framework Catalyst and Its Application in the Aerobic Oxidation of Alcohols[J]. 高等学校化学研究, 2019, 35(5): 860-865.

HOU Junying, HAO Jianjun, WANG Yaya, LIU Jingchun. Synthesis of Cu^Ⅱ/ZIF-8 Metal-organic Framework Catalyst and Its Application in the Aerobic Oxidation of Alcohols[J]. Chemical Research in Chinese Universities, 2019, 35(5): 860-865.

参考文献

[1] Chen B., Wang L. Y., Gao S., ACS Catal., 2015, 5(10), 675
[2] Varma R. S., Saini R. K., Tetrahedron Lett., 1998, 39(12), 1481
[3] Kamimura A., Nozaki Y., Ishikawa S., Inoue R., Nakayama M., Tetrahedron Lett., 2011, 52(4), 538
[4] Jiang H. M., Sun T. Y., Wang X., Xie Y. M., Zhang X. H., Wu Y. D., Schaefer H. F., Org. Lett., 2017, 19(24), 6502
[5] Gogoi N., Begum T., Dutta S., Bora U., Gogoi P. K., RSC Adv., 2015, 5, 95344
[6] Hou J. Y., Luan Y., Tang J., Wensley A. M., Yang M., Lu Y. F., J. Mol. Catal. A:Chem., 2015, 407, 53
[7] Zhang G. S., Xing X. F., Guan Y., Zhou A. Q., Zhang X. M., Xu X. H., Repo T., Chem. J. Chinese Universities, 2013, 34(4), 900
[8] Zavahir S., Xiao Q., Sarina S., Zhao J., Bottle S., Wellard M., Jia J. F., Jing L. Q., Huang Y. M., Blinco J. P., Wu H. S., Zhu H. Y., ACS Catal., 2016, 6(6), 3580
[9] Dutta D., Phukan A., Dutta D. K., Mol. Catal., 2018, 451, 178
[10] Iron M. A., Szpilman A. M., Chem. Eur. J., 2017, 23, 1368
[11] Semmelhack M. F., Schmid C. R., Cortes D. A., Chou C. S., J. Am. Chem. Soc., 1984, 106, 3374
[12] Xie X. M., Stahl S. S., J. Am. Chem. Soc., 2015, 137, 3767
[13] Chandra P., Jonas A. M., Fernandes A. E., ACS Catal., 2018, 8(7), 6006
[14] Vanoye L., Pablos M., de Bellefon C., Favre-Reguillon A., Adv. Synth. Catal., 2015, 357, 739
[15] Solomon E. I., Stahl S. S., Chem. Rev., 2018, 118, 2299
[16] Grayson J. D., Partridge B. M., ACS Catal., 2019, 9(5), 4296
[17] Corma A., Angew. Chem. Int. Ed., 2016, 55, 6112
[18] Parmeggiani C., Matassini C., Cardona F., Green Chem., 2017, 19, 2030
[19] Li F. H., Hu D. R., Yuan Y. H., Luo B. B., Song Y. B., Xiao S. T., Chen G. H., Fang Y. W., Lu F. S., Mol. Catal., 2018, 452, 75
[20] Dhakshinamoorthy A., Asiri A. M., Garcia H., Chem. Commun., 2017, 53, 10851
[21] Kirchon A., Feng L., Drake H. F., Joseph E. A., Zhou H. C., Chem. Soc. Rev., 2018, 47, 8611
[22] Kalmutzki M. J., Hanikel N., Yaghi O. M., Sci. Adv., 2018, 4, 9180
[23] Furukawa H., Ko N., Go Y. B., Aratani N., Choi S. B., Choi E., Yazaydin A. O., Snurr R. Q., O'Keeffe M., Kim J., Yaghi O. M., Science, 2010, 329, 424
[24] Zhao J., Wang W. Y., Tang H. L., Ramella D., Luan Y., Mol. Catal., 2018, 456, 57
[25] Xue D. X., Belmabkhout Y., Shekhah O., Jiang H., Adil K., Cairna A. J., Eddaoudi M., J. Am. Chem. Soc., 2015, 137, 5034
[26] Li Y. A., Zhao C. W., Zhu N. X., Liu Q. K., Chen G. J., Liu J. B., Zhao X. D., Ma J. P., Zhang S. J., Dong Y. B., Chem. Commun., 2015, 51, 17672
[27] Dhakshinamoorthy A., Asiri A. M., Garcia H., Chem. Eur. J., 2016, 22, 8012
[28] Chen S. C., Li N., Tian F., Chai N. N., He M. Y., Chen Q., Mol. Catal. 2018, 450, 104
[29] Kumar P., Pournara A., Kim K. H., Bansal V., Rapti S., Manos M. J., Prog. Mater. Sci., 2017, 86, 25
[30] Noori Y., Akhbari K., RSC Adv., 2017, 7, 1782
[31] Marshall R. J., Forgan R. S., Eur. J. Inorg. Chem., 2016, 27, 4310
[32] Fu Y. H., Xu L., Shen H. M., Yang H., Zhang F. M., Zhu W. D., Fan M. H., Chem. Eng. J., 2016, 299, 135
[33] Sun D. R., Sun F. X., Deng X. Y., Li Z. H., Inorg. Chem., 2015, 54, 8639
[34] Stubbs A. W., Braglia L., Borfecchia E., Meyer R. J., Roman-Leshkov Y., Lamberti C., Dinca M., ACS Catal., 2018, 8(1), 596
[35] Kida K., Okita M., Fujita K., Tanaka S., Miyake Y., CrystEngComm., 2013, 15, 1794
[36] Bai L., Li M., Guan J. Q., Chemistry Select., 2018, 3, 581
[37] Zhang X. W., Huang N., Wang G., Dong W. J., Yang M., Luan Y., Shi Z., Micropor. Mesopor. Mat., 2013, 177, 47
[38] Schejn A., Aboulate A., Balan L., Falk V., Lavevee J., Medjahdi G., Aranda L., Mozet K., Schneider R., Catal. Sci. Technol., 2015, 5, 1829
[39] Du P. C., Dong Y. N., Liu C., Wei W. L., Liu D., Liu P., J. Colloid Interf. Sci., 2018, 518, 57
[40] Ethiraj J., Bonino F., Lamberti C., Bordiga S., Micropor. Mesopor. Mat., 2015, 207, 90
[41] Li Y., Wee L. H., Martens J. A., Vankelecom I. F. J., J. Memb. Sci., 2017, 523, 561
[42] Wu C. S., Xiong Z. H., Li C., Zhang J. M., RSC Adv., 2015, 5, 82127
[43] James J. B., Lin Y. S., J. Phys. Chem. C, 2016, 120, 14015
[44] Hou J. Y., Luan Y., Yu J., Qi Y., Wang G., Lu Y. F., New J. Chem., 2016, 40, 10127
[45] Wang J. J., Liu C. S., Chang Z., Yan L. F., Bu X. H., Chinese J. Inorg. Chem., 2006, 22, 8
[46] Gamez P., Arends I. W. C. E., Reedijk J., Sheldon R. A., Chem. Commun., 2003, 2142
[47] Luan Y., Qi Y., Gao H. Y., Zheng N. N., Wang G., J. Mater. Chem. A, 2014, 2, 20588

Synthesis of Cu^Ⅱ/ZIF-8 Metal-organic Framework Catalyst and Its Application in the Aerobic Oxidation of Alcohols

Synthesis of Cu^Ⅱ/ZIF-8 Metal-organic Framework Catalyst and Its Application in the Aerobic Oxidation of Alcohols

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 12

编辑推荐

Metrics

本文评价

[1]	MA Yanfu, WANG Liwei, LIU Jian. Single Atom Catalysts in Liquid Phase Selective Hydrogenations[J]. 高等学校化学研究, 2022, 38(5): 1163-1171.
[2]	YOU Peiye, WEI Rongjia, NING Guohong, LI Dan. An Eosin Y Encapsulated Cu(I) Covalent Metal Organic Framework for Efficient Photocatalytic Sonogashira Cross-coupling Reaction[J]. 高等学校化学研究, 2022, 38(2): 415-420.
[3]	XUE Jingqi, LI Feng, ZHAI Xue, LI Dan, GUO Lijun, LI Cuiqin. Multiwalled Carbon Nanotubes Modified with Silylated-salicylaldimine Co(II) and Pd(II) Complexes as Precatalysts in Ethylene Oligomerization[J]. 高等学校化学研究, 2022, 38(2): 552-561.
[4]	HUANG Jin, CAI Yichen, YU Yulv, WANG Yuan. Conversion of CO₂ to Multi-carbon Compounds over a CoCO₃ Supported Ru-Pt Catalyst Under Mild Conditions[J]. 高等学校化学研究, 2022, 38(1): 223-228.
[5]	ZHANG Zhoujing, LIU Chuang, Ozioma AKAKURU, XU Wenjing, WU Aiguo, ZHANG Yewei. ICG and Sunitinib-loaded NH₂-MOFs for Folate-mediated Hepatocellular Carcinoma Dual-modal Therapy[J]. 高等学校化学研究, 2021, 37(4): 967-974.
[6]	PAN Tingting, YANG Kaijie, HAN Yu. Recent Progress of Atmospheric Water Harvesting Using Metal-Organic Frameworks[J]. 高等学校化学研究, 2020, 36(1): 33-40.
[7]	ZHANG Yanmei, ZHANG Fan, ZHANG Xiang, XU Yingmei, QI Xiaohui, QUAN Chunshan. Assembly and Post-modification of Fe₃O₄@MIL-100(Fe) for Knoevenagel Condensation[J]. 高等学校化学研究, 2018, 34(4): 655-660.
[8]	MA Jun, LAN Yang, MAO Hui, LIAO Yang, ZHAO Shilin. Preparation of Pt/γ-Al₂O₃-C Heterogeneous Catalyst for Highly Selective Hydrogenation of Cinnamaldehyde Towards Cinnamyl Alcohol[J]. 高等学校化学研究, 2017, 33(4): 660-665.
[9]	LIU Jun, LAN Lixin, WU Chao, LI Rong, LIU Xuanyan. Agglomerated Pd Catalysts and Their Applications in Hydrogen Production from Formic Acid Decomposition at Room Temperature[J]. 高等学校化学研究, 2016, 32(2): 272-277.
[10]	LIU Shi-yong. Colloid of Delaminated Layered Double Hydroxides: a Novel Type of LDH-based Catalyst[J]. 高等学校化学研究, 2010, 26(4): 612-616.
[11]	YANG Ke-er, TONG Shan-ling, YAN Yan, KANG En-hua, XIAO Feng-shou, LI Qing, CHANG Xin, FANG Chi-guang. Catalytic Oxidative Conversion from Naphthol to 2-Hydroxy-1, 4-naphthoquinone over Iron Porphyrin Catalysts by Molecular Oxygen in an Alkaline 2-Propanol Solution[J]. 高等学校化学研究, 2005, 21(3): 326-333.
[12]	GUO Jun, WANG Ning, JIAO Qing-ze, JIANG Da-zhen, YANG Guang-hu, MIN En-ze. Catalytic Oxidation of Cyclohexene with Molecular Oxygen on Hydrotalcite-like Compounds[J]. 高等学校化学研究, 1995, 11(3): 256-258.