Self-cleaning Anti-fouling TiO2/Poly(aryl ether sulfone) Composite Ultrafiltration Membranes

doi:10.1007/s40242-019-8401-5

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (4): 714-720.doi: 10.1007/s40242-019-8401-5

Self-cleaning Anti-fouling TiO₂/Poly(aryl ether sulfone) Composite Ultrafiltration Membranes

GENG Wenzhe, JIANG Hongchuan, YANG Xia, FENG Yong, WANG Xinyu, GENG Zhi, HUO Mingxin

Jilin Engineering Lab for Water Pollution Control and Resources Recovery, College of Environment, Northeast Normal University, Changchun 130117, P. R. China

收稿日期:2018-12-21 修回日期:2019-02-26 出版日期:2019-08-01 发布日期:2019-08-01
通讯作者: GENG Zhi E-mail:gengz100@nenu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.51508078, 51478095), the Jilin Provincial Science and Technology Development Project of China(No.20160520023JH), the Science and Technology Research Project of the Jilin Provincial Education Department, China(No.JJKH20180021KJ), and the Fundamental Research Funds for the Central Universities of China(No.2412018ZD016).

Self-cleaning Anti-fouling TiO₂/Poly(aryl ether sulfone) Composite Ultrafiltration Membranes

GENG Wenzhe, JIANG Hongchuan, YANG Xia, FENG Yong, WANG Xinyu, GENG Zhi, HUO Mingxin

Jilin Engineering Lab for Water Pollution Control and Resources Recovery, College of Environment, Northeast Normal University, Changchun 130117, P. R. China

Received:2018-12-21 Revised:2019-02-26 Online:2019-08-01 Published:2019-08-01
Contact: GENG Zhi E-mail:gengz100@nenu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.51508078, 51478095), the Jilin Provincial Science and Technology Development Project of China(No.20160520023JH), the Science and Technology Research Project of the Jilin Provincial Education Department, China(No.JJKH20180021KJ), and the Fundamental Research Funds for the Central Universities of China(No.2412018ZD016).

摘要/Abstract

摘要： A series of novel TiO₂/poly(aryl ether sulfone) ultrafiltration membranes with anti-fouling and self-cleaning properties was designed and prepared. First, anti-photocatalytic degraded fluorine contained poly(aryl ether sulfone) matrix(PAES-F) was synthesized. Then the composite membranes were prepared via TiO₂ nanoparticles and PAES-F polymer matrix by solution blending and non-solvent induced phase inversion methods. Further, separation efficiency, fouling behavior and self-cleaning property of the composite ultrafiltration(UF) membranes were investigated by dead-end filtration experiments using a polyacrylamide solution. The composite UF membranes exhibited outstanding self-cleaning efficiency and anti-photocatalytic degraded property after exposure to simulated sunlight irradiation. The water flux recovery ratios(F_RR) of the optimal composite UF membranes could reach 74.24%, which was attributable to photocatalytic degradation of the organic contaminant by TiO₂. And the retention rates of the composite UF membranes could maintain over 97%, which indicated the excellent photocatalytic degradation resistance of the fluorine contained PAES-F matrix. The novel high performance composite UF membranes have a broad application prospect in water treatment.

关键词: Poly(aryl ether sulfone), Ultrafiltration, Anti-fouling, Self-cleaning, Titanium dioxide

Abstract: A series of novel TiO₂/poly(aryl ether sulfone) ultrafiltration membranes with anti-fouling and self-cleaning properties was designed and prepared. First, anti-photocatalytic degraded fluorine contained poly(aryl ether sulfone) matrix(PAES-F) was synthesized. Then the composite membranes were prepared via TiO₂ nanoparticles and PAES-F polymer matrix by solution blending and non-solvent induced phase inversion methods. Further, separation efficiency, fouling behavior and self-cleaning property of the composite ultrafiltration(UF) membranes were investigated by dead-end filtration experiments using a polyacrylamide solution. The composite UF membranes exhibited outstanding self-cleaning efficiency and anti-photocatalytic degraded property after exposure to simulated sunlight irradiation. The water flux recovery ratios(F_RR) of the optimal composite UF membranes could reach 74.24%, which was attributable to photocatalytic degradation of the organic contaminant by TiO₂. And the retention rates of the composite UF membranes could maintain over 97%, which indicated the excellent photocatalytic degradation resistance of the fluorine contained PAES-F matrix. The novel high performance composite UF membranes have a broad application prospect in water treatment.

Key words: Poly(aryl ether sulfone), Ultrafiltration, Anti-fouling, Self-cleaning, Titanium dioxide

GENG Wenzhe, JIANG Hongchuan, YANG Xia, FENG Yong, WANG Xinyu, GENG Zhi, HUO Mingxin. Self-cleaning Anti-fouling TiO₂/Poly(aryl ether sulfone) Composite Ultrafiltration Membranes[J]. 高等学校化学研究, 2019, 35(4): 714-720.

参考文献 40

[1]	Yang Z., Yuan B., Huang X., Zhou J. Y., Cai J., Yang H., Li A. M., Cheng R. S., Water Research, 2012, 46, 107
[2]	Zahrim A. Y., Tizaoui C., Hilal N., Desalination, 2011, 266, 1
[3]	Zhang Y. H., Liu L. F., Yang F. L., Journal of Applied Polymer Science, 2016, 133, 43597
[4]	Deegan A. M., Shaik B., Nolan K., Urell K., Oelgemöller M., Tobin J., Morrissey A., International Journal of Environmental Science and Technology, 2011, 8, 649
[5]	Aravinda P., Subramanyan V., Ferro S., Gopalakrishnan R., Water Research, 2016, 93, 230
[6]	Kang G. D., Cao Y. M., Journal of Membrane Science, 2014, 463, 145
[7]	Baker R. W., Membrane Technology and Applications, 2nd Edition, Wiley-VCH, Chichester, 2004
[8]	Guo J., Sotto A., Martín A., Kim J., Journal of Industrial and Engineering Chemistry, 2017, 45, 257
[9]	Koh M., Clark M. M., Howe K. J., Journal of Membrane Science, 2005, 256, 169
[10]	Zhao C. S., Xue J. M., Ran F., Sun S. D., Progress in Materials Science, 2013, 58, 76
[11]	Werber J. R., Osuji C. O., Nature Reviews Materials, 2016, 1, 1
[12]	Greenleea L. F., Lawlerb D. F., Freemana B. D., Marrotc B., Moulin P., Water Res., 2009, 43, 2317
[13]	Bruggen B. V. D., Journal of Applied Polymer Science, 2009, 114, 630
[14]	Zhang M. Y., Liu Z. Y., Gao Y., Shu L., RSC Advance, 2017, 7, 42919
[15]	Zhang J. G., Xu Z. W., Mai W., Min C. Y., Zhou B. M., Shan M. J., Li Y. L., Yang C. Y., Wang Z., Qian X. M., Journal of Materials Chemistry A, 2013, 1, 3101
[16]	Zhou Q., Xu S., Zhu C. X., Cao B. Y., Kausar F., Xu A. H., Yuan W. Z., Zhang Y. M., Journal of Materials Science, 2017, 52, 11737
[17]	Liu S. S., Fang F., Wu J. J., Zhang K. S., Desalination, 2015, 375, 121
[18]	Wang Z. T., Wang H. X., Liu J. D., Zhang Y. T., Desalination, 2014, 344, 313
[19]	Wang Y. J., Liu L. F., Hong J. D., Cao J., Deng C. L., Journal of Membrane Science, 2018, 564, 372
[20]	Zinadini S., Zinatizadeh A. A., Rahimi M., Vatanpour V., Zangeneh H., Journal of Membrane Science, 2014, 453, 292
[21]	Li J. F., Xu Z. L., Yang H., Yu L. Y., Liu M., Applied Surface Science, 2009, 255, 4725
[22]	Huang L. H., He Y., Jin L. Y., Hou X. W., Miao L. Y., Lü C. L., Chem. Res. Chinese Universities, 2018, 34(2), 318
[23]	Geng Z., Yu Y., Zhu S. Y., Yu H. B., Liu J. C., Bian D. J., Yang X., Huo H. L., Huo M. X., Chem. Res. Chinese Universities, 2017, 33(1), 36
[24]	Zhu K., Wang G. B., High Performance Polymers, 2017, 30, 602
[25]	Barth C., Goncalves M. C., Pires A. T. N., Roeder J., Wolf B. A., Journal of Membrane Science, 2000, 169, 287
[26]	Zhao C. S., Xue J. M., Ran F., Sun S. D., Progress in Materials Science, 2013, 58, 76
[27]	Clech P. L., Lee E. K., Chen V., Water Research, 2006, 40, 323
[28]	Pekakis P. A., Xekoukoulotakis N. P., Mantzavinos D., Water Research, 2006, 40, 1276
[29]	Leong S., Razmjou A., Wang K., Hapgood K., Zhang X. W., Wang H. T., Journal of Membrane Science, 2014, 472, 167
[30]	Xiao Y. T., Xu S. S., Li Z. H., An X. H., Zhou L., Zhang Y. L., Shiang F. Q., Chinese Science Bulletin, 2010, 55, 1345
[31]	Geng Z., Yang X., Boo C., Zhu S. Y., Lu Y., Fan W., Huo M. X., Elimelech M., Yang X., Journal of Membrane Science, 2017, 529, 1
[32]	Zhang X., Du A. J., Lee P., Sun D. D., Leckie J. O., Applied Catalysis B:Environmental, 2008, 84, 262
[33]	Zhang G. L., Lu S. F., Zhang L., Meng Q., Shen C., Zhang J. W., Journal of Membrane Science, 2013, 436, 163
[34]	Vatanpour V., Madaeni S. S., Khataee A. R., Salehi E., Zinadini S., Monfared H. A., Desalination, 2012, 292, 19
[35]	He T. S., Zhou Z. F., Xu W. B., Ren F. M., Ma H. H., Wang J., Polymer, 2009, 50, 3031
[36]	Wu A. Y., Kotaki M., Ye L., Lu X., Polymer, 2007, 48, 512
[37]	Zhang Z., Meng Q., Chung T. C. M., Polymer, 2009, 50, 707
[38]	Soroko I., Livingston A., Journal of Membrane Science, 2009, 343, 189
[39]	Li J. F., Xu Z. L., Yang H., Yu L. Y., Liu M., Applied Surface Science, 2009, 255, 4725
[40]	Yang Y., Zhang H., Wang P., Zheng Q., Li J., Journal of Membrane Science, 2007, 288, 231

Self-cleaning Anti-fouling TiO₂/Poly(aryl ether sulfone) Composite Ultrafiltration Membranes

Self-cleaning Anti-fouling TiO₂/Poly(aryl ether sulfone) Composite Ultrafiltration Membranes

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