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高等学校化学研究 ›› 2013, Vol. 29 ›› Issue (4): 617-620.doi: 10.1007/s40242-013-3067-x

• Articles • 上一篇    下一篇

Synthesis and Characterization of SnO2-TiO2 Nanocomposite withRutile-phase via Hydrothermal Method at Low Temperature

WANG Yuan-rui1,2, LI Wen-yan3, ZHOU Bing1, ZHAO Xu1   

  1. 1. College of Chemistry, Jilin University, Changchun 130012, P. R. China;
    2. School of Chemical Engineering, Changchun University of Technology, Changchun 130012, P. R. China;
    3. Water Quality Monitoring Center, Changchun Water Group, Changchun 130012, P. R. China
  • 收稿日期:2013-02-22 修回日期:2013-04-17 出版日期:2013-08-01 发布日期:2013-07-15
  • 通讯作者: ZHAO Xu E-mail:zhaoxu@jlu.edu.cn
  • 基金资助:

    Supported by the Jilin Provincial Science and Technology Development Funds, China(No.20100334) and the Jilin Provincial Education Department's "12th Five-Year" Scientific and Technological Research Projects, China[No.126(2013)].

Synthesis and Characterization of SnO2-TiO2 Nanocomposite withRutile-phase via Hydrothermal Method at Low Temperature

WANG Yuan-rui1,2, LI Wen-yan3, ZHOU Bing1, ZHAO Xu1   

  1. 1. College of Chemistry, Jilin University, Changchun 130012, P. R. China;
    2. School of Chemical Engineering, Changchun University of Technology, Changchun 130012, P. R. China;
    3. Water Quality Monitoring Center, Changchun Water Group, Changchun 130012, P. R. China
  • Received:2013-02-22 Revised:2013-04-17 Online:2013-08-01 Published:2013-07-15
  • Contact: ZHAO Xu E-mail:zhaoxu@jlu.edu.cn
  • Supported by:

    Supported by the Jilin Provincial Science and Technology Development Funds, China(No.20100334) and the Jilin Provincial Education Department's "12th Five-Year" Scientific and Technological Research Projects, China[No.126(2013)].

摘要：

With Ti(SO4)2, SnCl4·5H2O and urea as raw materials, SnO2-TiO2 nanocomposites were synthesized via low temperature hydrothermal method at 80―100 ℃ in aqueous solutions. The morphologies of the products were altered systematically by varying the Ti/Sn molar ratio of the reactants, and rutile-phase particles were obtained with an average diameter of about 52.2 nm at a molar ratio of Ti/Sn=7.5. The surface composition of the composite was revealed by X-ray photoelectron spectroscopy(XPS) and X-ray diffraction(XRD) to be solely TiO2 with a rutile structure. This new composite material exhibits a high ultraviolet absorption capacity, and its photocatalytic activity for phenol oxidation is much lower than that of the commercial titania nanoparticles(P25).

关键词: Rutile, Titanium dioxide, Stannum dioxide, Core-shell, UV-shielding

Abstract:

With Ti(SO4)2, SnCl4·5H2O and urea as raw materials, SnO2-TiO2 nanocomposites were synthesized via low temperature hydrothermal method at 80―100 ℃ in aqueous solutions. The morphologies of the products were altered systematically by varying the Ti/Sn molar ratio of the reactants, and rutile-phase particles were obtained with an average diameter of about 52.2 nm at a molar ratio of Ti/Sn=7.5. The surface composition of the composite was revealed by X-ray photoelectron spectroscopy(XPS) and X-ray diffraction(XRD) to be solely TiO2 with a rutile structure. This new composite material exhibits a high ultraviolet absorption capacity, and its photocatalytic activity for phenol oxidation is much lower than that of the commercial titania nanoparticles(P25).

Key words: Rutile, Titanium dioxide, Stannum dioxide, Core-shell, UV-shielding