Zirconium Doped Hydrotalcite-based NiAl Mixed Oxides-Enhanced Performance for Adsorption of SO2 and NO

doi:10.1007/s40242-019-8324-1

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (3): 490-497.doi: 10.1007/s40242-019-8324-1

Zirconium Doped Hydrotalcite-based NiAl Mixed Oxides-Enhanced Performance for Adsorption of SO₂ and NO

ZHAO Ling^1,2, ZHANG Yu¹, LI Lexin¹, XING Yating¹, WANG Shuai¹, Christopher J. MARTYNIUK²

1. School of Ecology and Environment, Inner Mongolia University, Huhhot 010021, P. R. China;
2. College of Veterinary Medicine, University of Florida, Gainesville, FL 32611, USA

收稿日期:2018-10-08 修回日期:2019-01-28 出版日期:2019-06-01 发布日期:2019-03-27
通讯作者: ZHAO Ling E-mail:nmzhl@hotmail.com
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21866022, 21347001, 21567018), the Inner Mongolia Natural Science Foundation, China(Nos.2013MS0203, 2017MS0214), the Project of the Inner Mongolia Engineering Research Center of Coal Chemical Wastewater Treatment & Resourcelization, China and the College Students' Innovative Training Program of Inner Mongolia University, China(No.201817402).

Zirconium Doped Hydrotalcite-based NiAl Mixed Oxides-Enhanced Performance for Adsorption of SO₂ and NO

ZHAO Ling^1,2, ZHANG Yu¹, LI Lexin¹, XING Yating¹, WANG Shuai¹, Christopher J. MARTYNIUK²

1. School of Ecology and Environment, Inner Mongolia University, Huhhot 010021, P. R. China;
2. College of Veterinary Medicine, University of Florida, Gainesville, FL 32611, USA

Received:2018-10-08 Revised:2019-01-28 Online:2019-06-01 Published:2019-03-27
Contact: ZHAO Ling E-mail:nmzhl@hotmail.com
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21866022, 21347001, 21567018), the Inner Mongolia Natural Science Foundation, China(Nos.2013MS0203, 2017MS0214), the Project of the Inner Mongolia Engineering Research Center of Coal Chemical Wastewater Treatment & Resourcelization, China and the College Students' Innovative Training Program of Inner Mongolia University, China(No.201817402).

摘要/Abstract

摘要： In the present study, the adsorptive behavior of zirconium doped hydrotalcite-based NiAl mixed oxides for reducing NO and SO₂ was compared. According to the experimental results, the Zr⁴⁺ cations were partially dissolved in crystalline NiO phase. With the addition of Zr, new centers for oxygen release and storage were formed, Lewis acid strength increased, and weakly and strongly alkaline sites were expanded. Moreover, in situ FTIR(Fourier transform infrared spectroscopy) investigation demonstrated that the amounts of surface bisulfite, sulfite, nitrite and nitrate species of ZrNiAlO were much more than those of NiAlO. On the whole, this study concluded that the addition of Zr⁴⁺ to NiAlO works to improve this compound as major absorbent for SO₂ and NO.

关键词: SO₂, NO, Adsorption, ZrNiAlO mixed oxide

Abstract: In the present study, the adsorptive behavior of zirconium doped hydrotalcite-based NiAl mixed oxides for reducing NO and SO₂ was compared. According to the experimental results, the Zr⁴⁺ cations were partially dissolved in crystalline NiO phase. With the addition of Zr, new centers for oxygen release and storage were formed, Lewis acid strength increased, and weakly and strongly alkaline sites were expanded. Moreover, in situ FTIR(Fourier transform infrared spectroscopy) investigation demonstrated that the amounts of surface bisulfite, sulfite, nitrite and nitrate species of ZrNiAlO were much more than those of NiAlO. On the whole, this study concluded that the addition of Zr⁴⁺ to NiAlO works to improve this compound as major absorbent for SO₂ and NO.

Key words: SO₂, NO, Adsorption, ZrNiAlO mixed oxide

ZHAO Ling, ZHANG Yu, LI Lexin, XING Yating, WANG Shuai, Christopher J. MARTYNIUK. Zirconium Doped Hydrotalcite-based NiAl Mixed Oxides-Enhanced Performance for Adsorption of SO₂ and NO[J]. 高等学校化学研究, 2019, 35(3): 490-497.

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Zirconium Doped Hydrotalcite-based NiAl Mixed Oxides-Enhanced Performance for Adsorption of SO₂ and NO

Zirconium Doped Hydrotalcite-based NiAl Mixed Oxides-Enhanced Performance for Adsorption of SO₂ and NO

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