One Step Hydrothermal Synthesis of Flower-shaped Co3O4 Nanorods on Nickel Foam as Supercapacitor Materials and Their Excellent Electrochemical Performance

doi:10.1007/s40242-018-8073-6

高等学校化学研究 ›› 2018, Vol. 34 ›› Issue (6): 882-886.doi: 10.1007/s40242-018-8073-6

One Step Hydrothermal Synthesis of Flower-shaped Co₃O₄ Nanorods on Nickel Foam as Supercapacitor Materials and Their Excellent Electrochemical Performance

WANG Chen¹, MENG Yanshuang^1,3, WANG Lei¹, ZHU Fuliang^1,3, ZHANG Yue²

1. School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, P. R. China;
2. Department of Mechanical and Industrial Engineering, Texas A & M University-Kingsville, Kingsville, TX 78363, USA;
3. State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou 730050, P. R. China

收稿日期:2018-03-04 出版日期:2018-12-01 发布日期:2018-08-03
通讯作者: MENG Yanshuang, ZHANG Yue E-mail:mengyanshuang@163.com;yue.zhang@tamuk.edu
基金资助:
Supported by the National Natural Science Foundation of China(Nos.51364024, 51404124) and the Foundation for Innovation Groups of Basic Research in Gansu Province, China(No.1606RJIA322).

One Step Hydrothermal Synthesis of Flower-shaped Co₃O₄ Nanorods on Nickel Foam as Supercapacitor Materials and Their Excellent Electrochemical Performance

WANG Chen¹, MENG Yanshuang^1,3, WANG Lei¹, ZHU Fuliang^1,3, ZHANG Yue²

1. School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, P. R. China;
2. Department of Mechanical and Industrial Engineering, Texas A & M University-Kingsville, Kingsville, TX 78363, USA;
3. State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou 730050, P. R. China

Received:2018-03-04 Online:2018-12-01 Published:2018-08-03
Contact: MENG Yanshuang, ZHANG Yue E-mail:mengyanshuang@163.com;yue.zhang@tamuk.edu
Supported by:
Supported by the National Natural Science Foundation of China(Nos.51364024, 51404124) and the Foundation for Innovation Groups of Basic Research in Gansu Province, China(No.1606RJIA322).

摘要/Abstract

摘要： Flower-shaped Co₃O₄nanorods directly grown on nickel foam(Co₃O₄/NF) were prepared by one step hydrothermal method at low temperature. Co₃O₄nanorods are directly connected with the nickel foam, and no binder is needed as an additive, so the Co₃O₄/NF electrode has good electrical conductivity. This flower-shaped structure makes larger surface area of Co₃O₄nanorods that exposes to the electrolyte, thus promoting the redox reaction. The Co₃O₄/NF electrode shows a high specific capacitance of 2005.34 F/g at the current density of 0.5 A/g and a high capacitance retention of 98.0% after 5000 cycles. The high superior capacitive performance with high specific capaci-tance and the excellent cyclic performance indicate that the one step hydrothermal method has great potential application in supercapacitors.

关键词: Supercapacitor, Co₃O₄/NF, Hydrothermal, Nanorod

Abstract: Flower-shaped Co₃O₄nanorods directly grown on nickel foam(Co₃O₄/NF) were prepared by one step hydrothermal method at low temperature. Co₃O₄nanorods are directly connected with the nickel foam, and no binder is needed as an additive, so the Co₃O₄/NF electrode has good electrical conductivity. This flower-shaped structure makes larger surface area of Co₃O₄nanorods that exposes to the electrolyte, thus promoting the redox reaction. The Co₃O₄/NF electrode shows a high specific capacitance of 2005.34 F/g at the current density of 0.5 A/g and a high capacitance retention of 98.0% after 5000 cycles. The high superior capacitive performance with high specific capaci-tance and the excellent cyclic performance indicate that the one step hydrothermal method has great potential application in supercapacitors.

Key words: Supercapacitor, Co₃O₄/NF, Hydrothermal, Nanorod

WANG Chen, MENG Yanshuang, WANG Lei, ZHU Fuliang, ZHANG Yue. One Step Hydrothermal Synthesis of Flower-shaped Co₃O₄ Nanorods on Nickel Foam as Supercapacitor Materials and Their Excellent Electrochemical Performance[J]. 高等学校化学研究, 2018, 34(6): 882-886.

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One Step Hydrothermal Synthesis of Flower-shaped Co₃O₄ Nanorods on Nickel Foam as Supercapacitor Materials and Their Excellent Electrochemical Performance

One Step Hydrothermal Synthesis of Flower-shaped Co₃O₄ Nanorods on Nickel Foam as Supercapacitor Materials and Their Excellent Electrochemical Performance

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