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高等学校化学研究 ›› 2016, Vol. 32 ›› Issue (3): 433-436.doi: 10.1007/s40242-016-5450-x

• Articles • 上一篇    下一篇

Microwave-assisted One-pot Synthesis of Ag NPs/C and Its Application in H2O2 and Glucose Detection

GE Chenjiao1,2, LU Wenbo2, SUN Xuping2, TIAN Jian1   

  1. 1. Clean Energy Technology Laboratory, Changchun University of Science and Technology, Changchun 130022, P. R. China;
    2. State Key Lab of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China
  • 收稿日期:2015-11-20 修回日期:2015-12-18 出版日期:2016-06-01 发布日期:2015-12-26
  • 通讯作者: TIAN Jian E-mail:tianjian@cust.edu.cn
  • 基金资助:

    Supported by the National Natural Science Foundation of China(No.21175129), the National Basic Research Program of China(No.2011CB935800) and the Scientific and Technological Development Plan Project of Jilin Province, China(No. 20100534).

Microwave-assisted One-pot Synthesis of Ag NPs/C and Its Application in H2O2 and Glucose Detection

GE Chenjiao1,2, LU Wenbo2, SUN Xuping2, TIAN Jian1   

  1. 1. Clean Energy Technology Laboratory, Changchun University of Science and Technology, Changchun 130022, P. R. China;
    2. State Key Lab of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China
  • Received:2015-11-20 Revised:2015-12-18 Online:2016-06-01 Published:2015-12-26
  • Contact: TIAN Jian E-mail:tianjian@cust.edu.cn
  • Supported by:

    Supported by the National Natural Science Foundation of China(No.21175129), the National Basic Research Program of China(No.2011CB935800) and the Scientific and Technological Development Plan Project of Jilin Province, China(No. 20100534).

摘要：

The facile preparation of Ag NPs/C via a one-pot strategy was carried out by microwave treatment of a mixed aqueous solution of AgNO3 and glucose at 180℃ for 20 min without the presence of extra reducing agent. The as-synthesized Ag NPs/C showed high catalytic performance toward the reduction of H2O2. The H2O2 sensor constructed with as-synthesized Ag NPs/C exhibited a short amperometric response time of less than 2 s. The linear range was approximately (0.1-50) mmol/L(r=0.997), and the detection limit was approximately 3.3 μmol/L at a signal-to-noise ratio of 3. A glucose biosensor was fabricated by immobilizing glucose oxidase onto Ag NPs/C- modified glassy carbon electrode to detect glucose. The glucose sensor had a wide linear response range of 2-22 mmol/L(r=0.999) and a detection limit of 190 μmol/L.

关键词: Carbon, Ag nanoparticles, Microwave, H2O2, Glucose

Abstract:

The facile preparation of Ag NPs/C via a one-pot strategy was carried out by microwave treatment of a mixed aqueous solution of AgNO3 and glucose at 180℃ for 20 min without the presence of extra reducing agent. The as-synthesized Ag NPs/C showed high catalytic performance toward the reduction of H2O2. The H2O2 sensor constructed with as-synthesized Ag NPs/C exhibited a short amperometric response time of less than 2 s. The linear range was approximately (0.1-50) mmol/L(r=0.997), and the detection limit was approximately 3.3 μmol/L at a signal-to-noise ratio of 3. A glucose biosensor was fabricated by immobilizing glucose oxidase onto Ag NPs/C- modified glassy carbon electrode to detect glucose. The glucose sensor had a wide linear response range of 2-22 mmol/L(r=0.999) and a detection limit of 190 μmol/L.

Key words: Carbon, Ag nanoparticles, Microwave, H2O2, Glucose