Sulfonated Polyarylene Ether Sulfone (SPES) and Ga2O3 Based Hybrid Polymer Electrolyte Membrane for Direct Methanol Fuel Cells (DMFCs)

doi:10.1007/s40242-016-5362-9

高等学校化学研究 ›› 2016, Vol. 32 ›› Issue (2): 318-324.doi: 10.1007/s40242-016-5362-9

• Articles • 上一篇

Sulfonated Polyarylene Ether Sulfone (SPES) and Ga₂O₃ Based Hybrid Polymer Electrolyte Membrane for Direct Methanol Fuel Cells (DMFCs)

MIAO Shoulei, ZHANG Haiqiu, CHEN Zhimin, WANG Bin, LI Xiaobo, WU Yiqun

Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, Heilongjiang University, Harbin 150080, P. R. China

收稿日期:2015-09-16 修回日期:2016-02-14 出版日期:2016-04-01 发布日期:2016-03-14
通讯作者: ZHANG Haiqiu, WU Yiqun E-mail:zhanghaiqiu@126.com;yqwu@siom.ac.cn
基金资助:
Suppoted by the National Natural Science Foundation of China(No.51202061).

Sulfonated Polyarylene Ether Sulfone (SPES) and Ga₂O₃ Based Hybrid Polymer Electrolyte Membrane for Direct Methanol Fuel Cells (DMFCs)

MIAO Shoulei, ZHANG Haiqiu, CHEN Zhimin, WANG Bin, LI Xiaobo, WU Yiqun

Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, Heilongjiang University, Harbin 150080, P. R. China

Received:2015-09-16 Revised:2016-02-14 Online:2016-04-01 Published:2016-03-14
Contact: ZHANG Haiqiu, WU Yiqun E-mail:zhanghaiqiu@126.com;yqwu@siom.ac.cn
Supported by:
Suppoted by the National Natural Science Foundation of China(No.51202061).

摘要/Abstract

摘要：

Novel hybrid polymer electrolyte membrane, based on sulfonated polyarylene ether sulfone(SPES) and Ga₂O₃, was prepared and characterized. The structure of the composite membrane substantially modified the properties of SPES in terms of thermal stability, mechanical properties, methanol permeability, and so on. The structure and performance of the hybrid membrane were investigated by means of Fourier transform infrared spectrophotometry(FTIR), scanning electron microscopy(SEM), electrochemical impedance spectroscopy(EIS), thermal gravimetric analysis(TGA), and water uptake(WU) test. The hybrid polymer electrolyte membrane containing a certain quantity of Ga₂O₃ was found to gain good proton transport characteristics, particularly at relatively high temperatures. In addition, this membrane reduced methanol permeability and improved thermal stability in comparison to an unfilled reference membrane. The hybrid membrane was found suitably to be used as a polymer electrolyte membrane(PEM) in direct methanol fuel cells(DMFCs).

关键词: Proton exchange membrane, Property, Sulfonated polyarylene ether sulfone, Hybrid membrane

Abstract:

Key words: Proton exchange membrane, Property, Sulfonated polyarylene ether sulfone, Hybrid membrane

MIAO Shoulei, ZHANG Haiqiu, CHEN Zhimin, WANG Bin, LI Xiaobo, WU Yiqun. Sulfonated Polyarylene Ether Sulfone (SPES) and Ga₂O₃ Based Hybrid Polymer Electrolyte Membrane for Direct Methanol Fuel Cells (DMFCs)[J]. 高等学校化学研究, 2016, 32(2): 318-324.

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Sulfonated Polyarylene Ether Sulfone (SPES) and Ga₂O₃ Based Hybrid Polymer Electrolyte Membrane for Direct Methanol Fuel Cells (DMFCs)

Sulfonated Polyarylene Ether Sulfone (SPES) and Ga₂O₃ Based Hybrid Polymer Electrolyte Membrane for Direct Methanol Fuel Cells (DMFCs)

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