Shape-controlled Synthesis of Fe3O4 Nanocrystals with Incontinuous Multicavities

doi:10.1007/s40242-016-5383-4

高等学校化学研究 ›› 2016, Vol. 32 ›› Issue (2): 159-164.doi: 10.1007/s40242-016-5383-4

Shape-controlled Synthesis of Fe₃O₄ Nanocrystals with Incontinuous Multicavities

ZHAN Conghong², CHENG Rongmin², FANG Beibei¹, ZHAO Lijun¹

1. Key Laboratory of Automobile Materials, Ministry of Education, School of Materials Science and Engineering, Jilin University, Changchun 130022, P. R. China;
2. College of Chemistry, Jilin University, Changchun 130012, P. R. China

收稿日期:2015-10-04 修回日期:2015-11-06 出版日期:2016-04-01 发布日期:2015-11-23
通讯作者: ZHAO Lijun E-mail:lijunzhao@jlu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.51501068).

Shape-controlled Synthesis of Fe₃O₄ Nanocrystals with Incontinuous Multicavities

ZHAN Conghong², CHENG Rongmin², FANG Beibei¹, ZHAO Lijun¹

1. Key Laboratory of Automobile Materials, Ministry of Education, School of Materials Science and Engineering, Jilin University, Changchun 130022, P. R. China;
2. College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2015-10-04 Revised:2015-11-06 Online:2016-04-01 Published:2015-11-23
Contact: ZHAO Lijun E-mail:lijunzhao@jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.51501068).

摘要/Abstract

摘要：

In the solvothermal synthesis process, the effect of NaOH dosages of from 0.3 g to 4.0 g on the morphology evolution(from nanoparticles to octahedra) of Fe₃O₄ crystals was carefully investigated. Meanwhile, the growth process of Fe₃O₄ crystals at different reaction time was also investigated. Furthermore, it has been found that the particle size and crystallinity of Fe₃O₄ crystals can be controlled by the dosages of NaOH. In this paper, the increases of both the reaction time and the NaOH concentrations correspond to a minimization process of surface energy for Fe₃O₄ crystals. During the synthesis process, the addition of N₂H₄·H₂O and ethylene glycol in the magnetite not only facilitated the narrow distribution of particle size but also contributed to the formation of incontinuous multicavities with a diameter of about 5 nm.

关键词: Fe₃O₄ nanocrystal, Incontinuous multicavity, Magnetic property

Abstract:

Key words: Fe₃O₄ nanocrystal, Incontinuous multicavity, Magnetic property

ZHAN Conghong, CHENG Rongmin, FANG Beibei, ZHAO Lijun. Shape-controlled Synthesis of Fe₃O₄ Nanocrystals with Incontinuous Multicavities[J]. 高等学校化学研究, 2016, 32(2): 159-164.

ZHAN Conghong, CHENG Rongmin, FANG Beibei, ZHAO Lijun. Shape-controlled Synthesis of Fe₃O₄ Nanocrystals with Incontinuous Multicavities[J]. Chemical Research in Chinese Universities, 2016, 32(2): 159-164.

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Shape-controlled Synthesis of Fe₃O₄ Nanocrystals with Incontinuous Multicavities

Shape-controlled Synthesis of Fe₃O₄ Nanocrystals with Incontinuous Multicavities

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