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高等学校化学研究 ›› 2014, Vol. 30 ›› Issue (3): 405-408.doi: 10.1007/s40242-014-3417-3

• Articles • 上一篇    下一篇

Mild and Efficient Synthesis of 1-(6-Chloroquinoxalin-2-yl)-2-[4-(trifluoromethyl)-2,6-dinitrophenyl] Hydrazine Derivatives by Microwave Irradiation

MILAD Taheri, HANIYEH Alavi, HAMIDEH Nazari   

  1. Department of Chemistry, Islamic Azad University, Tehran 14735/334, Iran
  • 收稿日期:2013-09-30 修回日期:2013-12-09 出版日期:2014-06-01 发布日期:2014-05-24
  • 通讯作者: MILAD Taheri E-mail:miladtaheri1@hotmail.co.uk

Mild and Efficient Synthesis of 1-(6-Chloroquinoxalin-2-yl)-2-[4-(trifluoromethyl)-2,6-dinitrophenyl] Hydrazine Derivatives by Microwave Irradiation

MILAD Taheri, HANIYEH Alavi, HAMIDEH Nazari   

  1. Department of Chemistry, Islamic Azad University, Tehran 14735/334, Iran
  • Received:2013-09-30 Revised:2013-12-09 Online:2014-06-01 Published:2014-05-24
  • Contact: MILAD Taheri E-mail:miladtaheri1@hotmail.co.uk

摘要:

Some 1-(6-chloroquinoxalin-2-yl)-2-[4-(trifluoromethyl)-2,6-dinitrophenyl] hydrazine derivatives have been synthesized via both conventional and microwave assisted organic synthesis(MAOS) methods. The MAOS method is more effective on synthesizing these compounds than the conventional method in regard to the higher chemical yields of products(76%―98%) and the shorter reaction time(1―15 min).

关键词: 2,6-Dichloroquinoxaline, 2-Chloro-1-3-dinitro-5-triflouromthylbenzene hydrazine hydrate, Methyl hydrazine, Microwave assistant organic synthesis(MAOS)

Abstract:

Some 1-(6-chloroquinoxalin-2-yl)-2-[4-(trifluoromethyl)-2,6-dinitrophenyl] hydrazine derivatives have been synthesized via both conventional and microwave assisted organic synthesis(MAOS) methods. The MAOS method is more effective on synthesizing these compounds than the conventional method in regard to the higher chemical yields of products(76%―98%) and the shorter reaction time(1―15 min).

Key words: 2,6-Dichloroquinoxaline, 2-Chloro-1-3-dinitro-5-triflouromthylbenzene hydrazine hydrate, Methyl hydrazine, Microwave assistant organic synthesis(MAOS)