FTIR Spectroscopic Study of Crystallization of Uniaxial Drawn Syndiotactic Polystyrene/Carbon Nanotube Nanocomposite Films

高等学校化学研究 ›› 2012, Vol. 28 ›› Issue (1): 153-155.

FTIR Spectroscopic Study of Crystallization of Uniaxial Drawn Syndiotactic Polystyrene/Carbon Nanotube Nanocomposite Films

ZHANG Jin-hao^1,2, YANG Ji-ping^1*, YUAN Cui-ping^1,2, CHEN Guang-ming^2*

1. School of Materials Science and Engineering, Beihang University, Beijing 100191, P. R. China;
2. Beijing National Laboratory for Molecular Sciences(BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

收稿日期:2011-02-23 修回日期:2011-04-28 出版日期:2012-01-25 发布日期:2011-12-27
基金资助:
Supported by the National Natural Science Foundation of China(No.50873103) and the K. C. Wong Education Foundation of Hong Kong, China.

FTIR Spectroscopic Study of Crystallization of Uniaxial Drawn Syndiotactic Polystyrene/Carbon Nanotube Nanocomposite Films

ZHANG Jin-hao^1,2, YANG Ji-ping^1*, YUAN Cui-ping^1,2, CHEN Guang-ming^2*

1. School of Materials Science and Engineering, Beihang University, Beijing 100191, P. R. China;
2. Beijing National Laboratory for Molecular Sciences(BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Received:2011-02-23 Revised:2011-04-28 Online:2012-01-25 Published:2011-12-27
Supported by:
Supported by the National Natural Science Foundation of China(No.50873103) and the K. C. Wong Education Foundation of Hong Kong, China.

摘要/Abstract

摘要： The crystallization of uniaxial hot drawn syndiotactic polystyrene/multi-walled carbon nanotube (sPS/MWCNT) nanocomposite films was studied by FTIR spectroscopy. The effects of MWCNT content, draw ratio and drawing temperature on the sPS crystallinity were investigated. The sPS/MWCMT nanocomposite films show reduced crystallinities with the increase of MWCNT content. In addition, with the increase of draw ratio, both the pure sPS and the sPS/MWCNT nanocomposite drawn films exhibit increased crystallinity. The effect of drawing temperature on the sPS crystallization is complex. In a temperature range of 100―135 ℃, the crystallinity decreases with drawing temperature, whereas it increases at 140 ℃ for both pure sPS and its nanocomposite films.

关键词: Carbon nanotube, Crystallization, FTIR spectroscopy, Nanocomposite, Syndiotactic polystyrene

Abstract: The crystallization of uniaxial hot drawn syndiotactic polystyrene/multi-walled carbon nanotube (sPS/MWCNT) nanocomposite films was studied by FTIR spectroscopy. The effects of MWCNT content, draw ratio and drawing temperature on the sPS crystallinity were investigated. The sPS/MWCMT nanocomposite films show reduced crystallinities with the increase of MWCNT content. In addition, with the increase of draw ratio, both the pure sPS and the sPS/MWCNT nanocomposite drawn films exhibit increased crystallinity. The effect of drawing temperature on the sPS crystallization is complex. In a temperature range of 100―135 ℃, the crystallinity decreases with drawing temperature, whereas it increases at 140 ℃ for both pure sPS and its nanocomposite films.

Key words: Carbon nanotube, Crystallization, FTIR spectroscopy, Nanocomposite, Syndiotactic polystyrene

ZHANG Jin-hao, YANG Ji-ping, YUAN Cui-ping, CHEN Guang-ming. FTIR Spectroscopic Study of Crystallization of Uniaxial Drawn Syndiotactic Polystyrene/Carbon Nanotube Nanocomposite Films[J]. 高等学校化学研究, 2012, 28(1): 153-155.

[1]	GAO Huimin, SHI Rui, ZHU Youliang, QIAN Hujun and LU Zhongyuan. Coarse-grained Dynamics Simulation in Polymer Systems: from Structures to Material Properties[J]. 高等学校化学研究, 2022, 38(3): 653-670.
[2]	LI Yangbei, LIU Shaojia, ZHAO Hewei and GUO Lin. Strong and Tough TPU Fibers with Orientedly Aligned CNTs Reinforced by Amorphous ZrO₂[J]. 高等学校化学研究, 2022, 38(3): 763-768.
[3]	LAN Weifei, HU Ruifeng, HUANG Danrong, DONG Xu, SHEN Gangyi, CHANG Shan, DAI Dongsheng. Palladium Nanoparticles/Graphdiyne Oxide Nanocomposite with Excellent Peroxidase-like Activity and Its Application for Glutathione Detection[J]. 高等学校化学研究, 2022, 38(2): 529-534.
[4]	XUE Jingqi, LI Feng, ZHAI Xue, LI Dan, GUO Lijun, LI Cuiqin. Multiwalled Carbon Nanotubes Modified with Silylated-salicylaldimine Co(II) and Pd(II) Complexes as Precatalysts in Ethylene Oligomerization[J]. 高等学校化学研究, 2022, 38(2): 552-561.
[5]	CHAI Jingshan, LI Qiushi, ZHAO Yu, LIU Yang. Nanocomposites Facilitate the Removal of Aβ Fibrils for Neuroprotection[J]. 高等学校化学研究, 2022, 38(2): 522-528.
[6]	Hakan, AHAL, Gülben TORĞUT, Erdal CANPOLAT. Optimization of Electrical Conductivity of SA-graphene Nanocomposites Using Response Surface Methodology[J]. 高等学校化学研究, 2022, 38(2): 596-602.
[7]	ZHANG Xiaosi, YANG Miao, TIAN Peng, LIU Zhongmin. Progress in Seed-assisted Synthesis of (Silico) Aluminophosphate Molecular Sieves[J]. 高等学校化学研究, 2022, 38(1): 1-8.
[8]	PAN Chuanqi, LIU Xiaoxuan, ZHANG Xiang, MAO Feihong, XU Peiyan, ZHU Yuhua, DENG Hongtao, LUO Zhu, SUN Hongwei, ZHANG Lizhi, GUO Yanbing. Fabrication and Excellent Antibacterial Activity of Well-defined CuO/Graphdiyne Nanostructure[J]. 高等学校化学研究, 2021, 37(6): 1341-1347.
[9]	ZHAO Xue, ZHANG Xinrui, LIU Qidong, ZHANG Zeyao, LI Yan. Growth of Single-walled Carbon Nanotubes on Substrates Using Carbon Monoxide as Carbon Source[J]. 高等学校化学研究, 2021, 37(5): 1125-1129.
[10]	DONG Xin, CHEN Xi, ZHOU Zhaohui. Efficient Synthesis of p-Hydroxyphenyl Ethanol from Hydrogenation of Methyl p-Hydroxyphenylacetate with CNTs-promoted Cu-Zr Catalyst[J]. 高等学校化学研究, 2021, 37(3): 745-750.
[11]	DOU Yaying, ZHANG Yantao, GUO Feng, SHEN Yanbin, CHEN Gang, WEI Yingjin, XIE Zhaojun, ZHOU Zhen. Hierarchical Porous Carbon Nanotube Spheres for High-performance K-O₂ Batteries[J]. 高等学校化学研究, 2021, 37(2): 254-258.
[12]	YANG Liming, GUO Lixin, YU Hao, WANG Guan, SUN Jiangman, ZHANG Pengfei, GU Xinggui, TANG Ben Zhong. Organic Nanocrystals Based on a Solid-emission-tunable AIEgen for Cell Imaging[J]. 高等学校化学研究, 2021, 37(1): 129-136.
[13]	YU Fangyuan, WANG Kai, WANG Chuan, HE Xinxia, LIAO Yang, ZHAO Shilin, MAO Hui, LI Xiaoting, MA Jun. Anthraquinone Covalently Modified Carbon Nanotubes for Efficient and Steady Electrocatalytic H₂O₂ Generation[J]. 高等学校化学研究, 2020, 36(6): 1332-1338.
[14]	YAN Baolin, LIU Dapeng, FENG Xilan, SHAO Mingzhe, ZHANG Yu. Ru Nanoparticles Supported on Co-Embedded N-Doped Carbon Nanotubes as Efficient Electrocatalysts for Hydrogen Evolution in Basic Media[J]. 高等学校化学研究, 2020, 36(3): 425-430.
[15]	YANG Zuojun, WU Xueyan, MA Chao, HOU Chengcheng, XU Shumao, WEI Xiao, WANG Kaixue, CHEN Jiesheng. Cu₂SnSe₃/CNTs Composite as a Promising Anode Material for Sodium-ion Batteries[J]. 高等学校化学研究, 2020, 36(1): 91-96.

FTIR Spectroscopic Study of Crystallization of Uniaxial Drawn Syndiotactic Polystyrene/Carbon Nanotube Nanocomposite Films

FTIR Spectroscopic Study of Crystallization of Uniaxial Drawn Syndiotactic Polystyrene/Carbon Nanotube Nanocomposite Films

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价