Microwave Assisted Synthesis of 3,3',3″,3'″-o-, p-Phenylenedi-methylidinetetrakis-(4-hydroxy-2H-1-benzopyran-2-one)

高等学校化学研究 ›› 2010, Vol. 26 ›› Issue (6): 933-936.

Microwave Assisted Synthesis of 3,3',3″,3'″-o-, p-Phenylenedi-methylidinetetrakis-(4-hydroxy-2H-1-benzopyran-2-one)

AN Lin¹, LIU Dong-mei², WANG Jin-xiang² and YAN Chao-guo^2*

1. College of Pharmacy, Xuzhou Medical College, Xuzhou 221004, P. R. China;
2. College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. China

收稿日期:2010-01-21 修回日期:2010-03-17 出版日期:2010-11-25 发布日期:2010-12-01
通讯作者: YAN Chao-guo E-mail:cgyan@yzu.edu.cn
作者简介:YAN Chao-guo. E-mail: cgyan@yzu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.20672091).

Microwave Assisted Synthesis of 3,3',3″,3'″-o-, p-Phenylenedi-methylidinetetrakis-(4-hydroxy-2H-1-benzopyran-2-one)

AN Lin¹, LIU Dong-mei², WANG Jin-xiang² and YAN Chao-guo^2*

1. College of Pharmacy, Xuzhou Medical College, Xuzhou 221004, P. R. China;
2. College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. China

Received:2010-01-21 Revised:2010-03-17 Online:2010-11-25 Published:2010-12-01
Contact: YAN Chao-guo E-mail:cgyan@yzu.edu.cn
About author:YAN Chao-guo. E-mail: cgyan@yzu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.20672091).

摘要/Abstract

摘要： Under microwave irradiation, 2,2'-alkoxy-bridging or 4,4'-alkoxy-bridging dibenzaldehydes reacted with 4-hydroxycoumarin in DMF to give a series of 3,3',3″,3'″-o- and 3,3',3″,3'″-p-phenylenedimethylidinetetrakis-(4- hydroxy-2H-1-benzopyran-2-ones) in moderate yields. The structures of the synthetic coumarin derivatives were characterized with IR, 1H NMR and MS spectroscopy as well as X-ray single crystallography.

关键词: Microwave irradiation, One-pot reaction, Coumarin, Benzopyran-2-one

Abstract: Under microwave irradiation, 2,2'-alkoxy-bridging or 4,4'-alkoxy-bridging dibenzaldehydes reacted with 4-hydroxycoumarin in DMF to give a series of 3,3',3″,3'″-o- and 3,3',3″,3'″-p-phenylenedimethylidinetetrakis-(4- hydroxy-2H-1-benzopyran-2-ones) in moderate yields. The structures of the synthetic coumarin derivatives were characterized with IR, 1H NMR and MS spectroscopy as well as X-ray single crystallography.

Key words: Microwave irradiation, One-pot reaction, Coumarin, Benzopyran-2-one

AN Lin, LIU Dong-mei, WANG Jin-xiang and YAN Chao-guo*. Microwave Assisted Synthesis of 3,3',3″,3'″-o-, p-Phenylenedi-methylidinetetrakis-(4-hydroxy-2H-1-benzopyran-2-one)[J]. 高等学校化学研究, 2010, 26(6): 933-936.

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Microwave Assisted Synthesis of 3,3',3″,3'″-o-, p-Phenylenedi-methylidinetetrakis-(4-hydroxy-2H-1-benzopyran-2-one)

Microwave Assisted Synthesis of 3,3',3″,3'″-o-, p-Phenylenedi-methylidinetetrakis-(4-hydroxy-2H-1-benzopyran-2-one)

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