Synthesis and Characterization of Novel Thiosemicarbazones Bearing Sugar Moieties

高等学校化学研究 ›› 2006, Vol. 22 ›› Issue (6): 738-741.doi:

Synthesis and Characterization of Novel Thiosemicarbazones Bearing Sugar Moieties

YANG Bo, ZHANG Shu-sheng and LI Hui-xiang

College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China

收稿日期:2005-11-24 修回日期:1900-01-01 出版日期:2006-11-25 发布日期:2006-11-25
通讯作者: ZHANG Shu-sheng E-mail:shushzhang@126.com

Synthesis and Characterization of Novel Thiosemicarbazones Bearing Sugar Moieties

YANG Bo, ZHANG Shu-sheng and LI Hui-xiang

College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China

Received:2005-11-24 Revised:1900-01-01 Online:2006-11-25 Published:2006-11-25
Contact: ZHANG Shu-sheng E-mail:shushzhang@126.com

摘要/Abstract

关键词: Thiosemicarbazone, Sugar, Synthesis, Characterization

Abstract: Six novel thiosemicarbazones containing sugar and thiosemicarbazide moieties were synthesized by a five-step procedure using D-galactose and D-xylose as the starting materials and the corresponding glycosyl isothiocyanates as the intermediates. The target compounds were characterized by IR, ¹H NMR, and elemental analysis. The coupling constants between H1 and H2 in the sugar rings, all fall within the range of J=9.2—10.0 Hz, confirming the β-configuration of the compounds.

Key words: Thiosemicarbazone, Sugar, Synthesis, Characterization , Thiosemicarbazone, Sugar, Synthesis, Characterization

YANG Bo, ZHANG Shu-sheng , LI Hui-xiang. Synthesis and Characterization of Novel Thiosemicarbazones Bearing Sugar Moieties[J]. 高等学校化学研究, 2006, 22(6): 738-741.

YANG Bo, ZHANG Shu-sheng , LI Hui-xiang. Synthesis and Characterization of Novel Thiosemicarbazones Bearing Sugar Moieties[J]. Chemical Research in Chinese Universities, 2006, 22(6): 738-741.

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Synthesis and Characterization of Novel Thiosemicarbazones Bearing Sugar Moieties

Synthesis and Characterization of Novel Thiosemicarbazones Bearing Sugar Moieties

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