A New Tin Graphite Intercalation Compound for Lithium Ion Batteries

高等学校化学研究 ›› 2006, Vol. 22 ›› Issue (5): 639-642.doi:

A New Tin Graphite Intercalation Compound for Lithium Ion Batteries

XIE Hai-ming^1,2, YAN Xue-dong¹, YU Hai-ying¹, ZHANG Ling-yun¹, YANG Gui-ling¹, XU Yang¹ and WANG Rong-shun¹

1. Department of Chemistry, Northeast Normal University, Changchun 130024, P. R. China;
2. Department of Chemistry, Inner Mongolia University for Nationalities, Tongliao 028043, P. R. China

收稿日期:2005-11-17 修回日期:1900-01-01 出版日期:2006-09-25 发布日期:2006-09-25
通讯作者: WANG Rong-shun E-mail:wangrs@nenu.edu.cn

A New Tin Graphite Intercalation Compound for Lithium Ion Batteries

XIE Hai-ming^1,2, YAN Xue-dong¹, YU Hai-ying¹, ZHANG Ling-yun¹, YANG Gui-ling¹, XU Yang¹ and WANG Rong-shun¹

1. Department of Chemistry, Northeast Normal University, Changchun 130024, P. R. China;
2. Department of Chemistry, Inner Mongolia University for Nationalities, Tongliao 028043, P. R. China

Received:2005-11-17 Revised:1900-01-01 Online:2006-09-25 Published:2006-09-25
Contact: WANG Rong-shun E-mail:wangrs@nenu.edu.cn

摘要/Abstract

关键词: Lithium ion battery, Anode material, Sn-GIC

Abstract: A new composite material was fabricated by intercalating tin nanoparticles into graphite. The tin graphite intercalation compound(Sn-GIC) was prepared by the interactions of tin tetrachloride with KC₈(K-GIC) in tetrahydrofuran(THF). As the anode of lithium ion batteries, Sn-GIC presents a steady reversible capacity(363 mA·h/g) and a good cycling performance in comparison with Sn and SnO₂, it suggests that the association of tin with graphite not only improves the reversible capacities, but also prevents the volume changes resulted from lithium insertion and extraction with tin during a charge-discharge process.

Key words: Lithium ion battery, Anode material, Sn-GIC, Lithium ion battery, Anode material, Sn-GIC

XIE Hai-ming , YAN Xue-dong , YU Hai-ying , ZHANG Ling-yun , YANG Gui-ling , XU Yang , WANG Rong-shun . A New Tin Graphite Intercalation Compound for Lithium Ion Batteries[J]. 高等学校化学研究, 2006, 22(5): 639-642.

XIE Hai-ming , YAN Xue-dong , YU Hai-ying , ZHANG Ling-yun , YANG Gui-ling , XU Yang , WANG Rong-shun . A New Tin Graphite Intercalation Compound for Lithium Ion Batteries[J]. Chemical Research in Chinese Universities, 2006, 22(5): 639-642.

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A New Tin Graphite Intercalation Compound for Lithium Ion Batteries

A New Tin Graphite Intercalation Compound for Lithium Ion Batteries

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