Direct Pyrolysis of Molybdophosphate-based Ionic Salt for One-step Synthesis of N,P Co-doped Carbon/MoO3-x Hybrids with Superior Lithium Storage Performance

doi:10.1007/s40242-019-9149-7

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (5): 842-847.doi: 10.1007/s40242-019-9149-7

Direct Pyrolysis of Molybdophosphate-based Ionic Salt for One-step Synthesis of N,P Co-doped Carbon/MoO_3-x Hybrids with Superior Lithium Storage Performance

ZHANG Lifeng^1,2, SHEN Kechao¹, JIANG Yongtao¹, GUO Yu¹, LIU Yi^1,2, GUO Shouwu^1,3

1. School of Materials Science and Engineering, Shaanxi University of Science and Technology, Xi'an 710021, P. R. China;
2. Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science and Technology, Xi'an 710021, P. R. China;
3. School of Electronic Information and Electrical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

收稿日期:2019-05-25 出版日期:2019-10-01 发布日期:2019-09-24
通讯作者: ZHANG Lifeng, GUO Shouwu E-mail:zhanglifeng@sust.edu.cn;swguo@sjtu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21203116, 51602184) and the Platform Construction of Energy Storage Materials and Devices in Shaanxi University of Science and Technology, China(No.0126-126021802).

Direct Pyrolysis of Molybdophosphate-based Ionic Salt for One-step Synthesis of N,P Co-doped Carbon/MoO_3-x Hybrids with Superior Lithium Storage Performance

ZHANG Lifeng^1,2, SHEN Kechao¹, JIANG Yongtao¹, GUO Yu¹, LIU Yi^1,2, GUO Shouwu^1,3

1. School of Materials Science and Engineering, Shaanxi University of Science and Technology, Xi'an 710021, P. R. China;
2. Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science and Technology, Xi'an 710021, P. R. China;
3. School of Electronic Information and Electrical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

Received:2019-05-25 Online:2019-10-01 Published:2019-09-24
Contact: ZHANG Lifeng, GUO Shouwu E-mail:zhanglifeng@sust.edu.cn;swguo@sjtu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21203116, 51602184) and the Platform Construction of Energy Storage Materials and Devices in Shaanxi University of Science and Technology, China(No.0126-126021802).

摘要/Abstract

摘要： N, P co-doped carbon/MoO_3-x hybrids(NPC/MoO_3-x) were synthesized via one-step pyrolysis of molybdophosphate-based ionic salt precursor. Doped carbon and oxygen vacancies(OVs) were synchronously introduced into the NPC/MoO_3-x hybrids without any other redundant procedure. As anodes for lithium-ion batteries, the NPC/MoO_3-x hybrids delivered a high initial Coulombic efficiency(ICE) of 81% as well as high charge capacity of 516 mA·h/g after 100 cycles at 1 A/g, indicating the excellent reversibility and rate capability. The enhanced lithium storage performance was attributed to the rational combination of surface engineering and OVs, which is beneficial to the more active sites and fast ionic/electronic transport.

关键词: Lithium ion battery, Anode, Molybdenum oxide, Doped carbon, Oxygen vacancy

Abstract: N, P co-doped carbon/MoO_3-x hybrids(NPC/MoO_3-x) were synthesized via one-step pyrolysis of molybdophosphate-based ionic salt precursor. Doped carbon and oxygen vacancies(OVs) were synchronously introduced into the NPC/MoO_3-x hybrids without any other redundant procedure. As anodes for lithium-ion batteries, the NPC/MoO_3-x hybrids delivered a high initial Coulombic efficiency(ICE) of 81% as well as high charge capacity of 516 mA·h/g after 100 cycles at 1 A/g, indicating the excellent reversibility and rate capability. The enhanced lithium storage performance was attributed to the rational combination of surface engineering and OVs, which is beneficial to the more active sites and fast ionic/electronic transport.

Key words: Lithium ion battery, Anode, Molybdenum oxide, Doped carbon, Oxygen vacancy

ZHANG Lifeng, SHEN Kechao, JIANG Yongtao, GUO Yu, LIU Yi, GUO Shouwu. Direct Pyrolysis of Molybdophosphate-based Ionic Salt for One-step Synthesis of N,P Co-doped Carbon/MoO_3-x Hybrids with Superior Lithium Storage Performance[J]. 高等学校化学研究, 2019, 35(5): 842-847.

参考文献

[1] Yang Z., Zhang J., Kintner-Meyer M. C. W., Lu X., Choi D., Lemmon J. P., Chem. Rev., 2011, 111, 3577
[2] Goodenough J. B., Energy Environ. Sci., 2014, 7, 14
[3] Xie D., Xia X. H., Zhong Y., Wang Y. D., Wang D. H., Wang X. L., Tu J. P., Adv. Energy Mater., 2016, 7, 1601804
[4] Poizot P. L. S. G., Laruelle S., Grugeon S., Dupont L., Tarascon J. M., Natrue, 2000, 407, 496
[5] Zhu C., Mu X., van Aken P. A., Yu Y., Maier J., Angew. Chem. Int. Ed., 2014, 45, 2152
[6] Xiao Q., Fan Y., Wang X., Susantyoko R. A., Zhang Q., Energy Environ. Sci., 2014, 7, 655
[7] He P., Yu H., Li D., Zhou H., J. Mater. Chem., 2012, 22, 3680
[8] Guo Q. B., Ma Y. F., Chen T. T., Xia Q. Y., Yang M., Xia H., Yu Y., ACS Nano, 2017, 11, 12658
[9] Zhang J., Shi Y., Ding Y., Peng L. L., Zhang W. K., Yu G. H., Adv. Energy Mater., 2017, 7, 1602876
[10] Chen L., Jiang H., Jiang H. B., Zhang H. X., Guo S. J., Hu Y. J., Li C. Z., Adv. Energy Mater., 2017, 7, 1602782
[11] Xue D. F., Zhu D. Z., Xiong W., Cao T. C., Wang Z. W., Lv Y. K., Li L. C., Liu M. X., Gan L. H., ACS Sustainable Chem. Eng., 2019, 7, 7024
[12] Wu H. L., Xia L., Ren J., Zheng Q. J., Xu C. G., Lin D. M., J. Mater. Chem. A, 2017, 5, 20458
[13] Song Z. Y., Duan H., Li L. C., Zhu D. Z., Cao T. C., Lv Y. K., Xiong W., Wang Z. W., Liu M. X., Gan L. H., Chem. Eng. J., 2019, 372, 1216
[14] Zhu L. W., Wu J., Zhang Q., Li X. K., Li Y. M., Cao X. B., J. Colloid Interf. Sci., 2017, 510, 32
[15] Yan J. J., Zhu D. Z., Lv Y. K., Xiong W., Liu M. X., Gan L. H., Chin. Chem. Lett., 2019, DOI:10.1016/j.cclet.2019.05.035
[16] Wang Q. D., Li Y. M., Wang K., Zhou J. T., Zhu L. W., Gu L., Hu J., Cao X. B., Electrochim. Acta, 2017, 257, 250
[17] Xie D., Xia X. H., Tang W. J., Zhong Y., Wang Y. D., Wang D. H., Wang X. L., Tu J. P., J. Mater. Chem. A, 2017, 5, 7578
[18] Wang X. J., Nesper R., Villevieille C., Novák P., Adv. Energy Mater., 2013, 3, 606
[19] Sun Y., Hu X., Luo W., Huang Y., ACS Nano, 2011, 5, 7100
[20] Qiu J., Yang Z. X., Li Y., J. Mater. Chem. A, 2015, 3, 24245
[21] Hu X. L., Zhang W., Liu X. X., Mei Y. N., Huang Y. H., Chem. Soc. Rev., 2015, 3, 2376
[22] Noerochim L., Wang J. Z., Wexler D., Chao Z., Liu H. K., J. Power Sources, 2013, 228, 198
[23] Meduri P., Clark Ezra., Kim J. H., Dayalan E., Sumanasekera G. U., Sunkara M. K., Nano Lett., 2012, 12, 1784
[24] Schaub R., Wahlstrçm E., Rønnau A., Lægsgaard E., Stensgaard I., Besenbacher F., Science, 2003, 299, 377
[25] Xu Y., Zhou M., Wang X., Wang C. L., Liang L. Y., Grote F. B., Wu M. H., Mi Y., Lei Y., Angew. Chem., 2015, 54, 8892
[26] Kim H. S., Cook J. B., Lin H., Ko J. S., Tolbert S. H., Ozolins V., Dunn B., Nature Mater., 2017, 16, 454
[27] Yang C. L., Liu X. W., Yang Z. Z., Gu L., Yu Y., Adv. Mater. Interfaces, 2016, 3, 1600730
[28] Li Y. F., Wang D. D., An Q. Y., Ren B., Rong Y. G., Yao Y., J. Mater. Chem. A, 2016, 4, 5402
[29] Xu G. Q., Liu P., Ren Y. R., Huang X. B., Peng Z. G., Tang Y. G., Wang H. Y., J. Power Sources, 2017, 361, 1
[30] Lin S., Zheng Y., Xu L. M., Wang S. M., Chem. J. Chinese Universities, 2000, 21(8), 1248
[31] Yang H., Qi X., Wen L., Lu C., Cheng G., Ind. Eng. Chem. Res., 2011, 50, 58
[32] Liu M. X., Gan L. H., Xiong W., Xu Z. J., Zhu D. Z., Chen L. W., J. Mater. Chem. A, 2014, 2, 2555
[33] Wang C. L., Sun L. S., Wang X. X., Cheng Y., Yin D. M., Yuan D. X., Li Q., Wang L. M., ChemElectroChem, 2017, 4, 2915
[34] Liu J., Wei A. X., Chen M. H., Xia X. H., J. Mater. Chem. A, 2018, 6, 3857
[35] Li X., Xu J. T., Mei L., Zhang Z. J., Cui C. Y., Liu H. K., Ma J. M., Dou S. X., J. Mater. Chem. A, 2015, 3, 3257

Direct Pyrolysis of Molybdophosphate-based Ionic Salt for One-step Synthesis of N,P Co-doped Carbon/MoO_3-x Hybrids with Superior Lithium Storage Performance

Direct Pyrolysis of Molybdophosphate-based Ionic Salt for One-step Synthesis of N,P Co-doped Carbon/MoO_3-x Hybrids with Superior Lithium Storage Performance

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	LI Yang, WANG Xian, LIU Jie, JIN Zhao, LIU Changpeng, GE Junjie, XING Wei. Anode Catalytic Dependency Behavior on Ionomer Content in Direct CO Polymer Electrolyte Membrane Fuel Cell[J]. 高等学校化学研究, 2022, 38(5): 1251-1257.
[2]	ZHANG Ziqi, WANG Hanbo, LI Yuxin, XIE Minggang, LI Chunguang, LU Haiyan, PENG Yu, and SHI Zhan. Confined Pyrolysis Synthesis of Well-dispersed Cobalt Copper Bimetallic Three-dimensional N-Doped Carbon Framework as Efficient Water Splitting Electrocatalyst[J]. 高等学校化学研究, 2022, 38(3): 750-757.
[3]	XU Jing, MIAO Sijia, TANG Duihai, ZHANG Wenting, ZHAO Zhen, QIAO Zhen-An. Molten Salts Strategy for the Synthesis of CoP Nanoparticles Entrapped, N,P co-Doped Mesoporous Carbons as Electrocatalysts for Hydrogen Evolution[J]. 高等学校化学研究, 2022, 38(1): 237-242.
[4]	YE Peng, LIU Yongchao, MA Jian, WANG Yueda, FENG Xuyong, XIANG Hongfa, SUN Yi, LIANG Xin, YU Yan. Enhanced Electrochemical Performance of Na_0.67Fe_0.5Mn_0.5O₂Cathode with SnO₂ Modification[J]. 高等学校化学研究, 2021, 37(5): 1130-1136.
[5]	HU Rong, FANG Yongzheng, LIU Xiaoyu, ZHU Kai, CAO Dianxue, YI Jin, WANG Guiling. Synthesis of SnS₂ Ultrathin Nanosheets as Anode Materials for Potassium Ion Batteries[J]. 高等学校化学研究, 2021, 37(2): 311-317.
[6]	FANG Hengyi, GAO Suning, ZHU Zhuo, REN Meng, WU Quan, LI Haixia, LI Fujun. Recent Progress and Perspectives of Sodium Metal Anodes for Rechargeable Batteries[J]. 高等学校化学研究, 2021, 37(2): 189-199.
[7]	LEI Chong, LI Wenzheng, WANG Gongwei, ZHUANG Lin, LU Juntao, XIAO Li. Improving the Catalytic Efficiency of NiFe-LDH/ATO by Air Plasma Treatment for Oxygen Evolution Reaction[J]. 高等学校化学研究, 2021, 37(2): 293-297.
[8]	WANG Wen-Peng, ZHANG Juan, LI Xue-Ting, YIN Ya-Xia, XIN Sen, GUO Yu-Guo. Stabilizing the Electrochemistry of Lithium-Selenium Battery via In situ Gelated Polymer Electrolyte: A Look from Anode[J]. 高等学校化学研究, 2021, 37(2): 298-303.
[9]	HU Tao, YANG Weiwei, WANG Cheng, BU Yali, JIN Feng, ZHANG Dongwen, GU Min, LIU Wenhui, LIANG Qinghua, LIU Ruiqing, FENG Xiaomiao, MA Yanwen. Multilayer Porous Vanadium Nitride Microsheets Anodes for Highly Stable Na-ion Batteries[J]. 高等学校化学研究, 2021, 37(2): 286-292.
[10]	WANG Dong, LI Zhenwei, ZHANG Qian, LIU Jie, YANG Yu, HAN Jishu, WANG Lei. Small Things Make a Big Difference: the Small-molecule Cross-linker of Robust Water-soluble Network Binders for Stable Si Anodes[J]. 高等学校化学研究, 2021, 37(2): 304-310.
[11]	MA Cui, QIU Licheng, BAO Jian, ZHOU Yongning. Hexagonal FeNi₂Se₄@C Nanoflakes as High Performance Anode Materials for Sodium-ion Batteries[J]. 高等学校化学研究, 2021, 37(2): 318-322.
[12]	WU Ying, YAO Yu, WANG Lifeng, YU Yan. Recent Progress on Modification Strategies of Alloy-based Anode Materials for Alkali-ion Batteries[J]. 高等学校化学研究, 2021, 37(2): 200-209.
[13]	LI Yinyin, WU Qiannan, ZHANG Kai, HU Bin, LIN Yanhong, WANG Dejun, XIE Tengfeng. Boosting Photocatalytic Oxygen Evolution: Purposely Constructing Direct Z-Scheme Photoanode by Modulating the Interface Electric Field[J]. 高等学校化学研究, 2020, 36(6): 1059-1067.
[14]	XU Laiqiang, LI Jiayang, LI Yitong, CAI Peng, LIU Cheng, ZOU Guoqiang, HOU Hongshuai, HUANG Lanping, JI Xiaobo. Nitrogen-doped Carbon Coated Na₃V₂(PO₄)₃ with Superior Sodium Storage Capability[J]. 高等学校化学研究, 2020, 36(3): 459-466.
[15]	WANG Haitao, TANG Yongbing. Artificial Solid Electrolyte Interphase Acting as “Armor” to Protect the Anode Materials for High-performance Lithium-ion Battery[J]. 高等学校化学研究, 2020, 36(3): 402-409.