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高等学校化学研究 ›› 2004, Vol. 20 ›› Issue (2): 146-148.

• Articles • 上一篇    下一篇

Crystal Structure of Bis (O,O'-diisopropyl dithiophosphate):[(C3H7O)2PS2]2

ZHANG Shu-sheng, LI Xue-mei, WANG Jin-li, WAN Jun, JIAO Kui   

  1. College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P.R. China
  • 收稿日期:2003-05-25 出版日期:2004-04-24 发布日期:2011-08-06
  • 基金资助:

    Supported by the National Natural Science Foundation of China(No.20275020), the Natural Science Foundation of Shandong Province(No.Z2002B02) and the Outstanding Adult-Young Scientific Research Encouraging Foundation of Shandong Province (No.03BS081).

Crystal Structure of Bis (O,O'-diisopropyl dithiophosphate):[(C3H7O)2PS2]2

ZHANG Shu-sheng, LI Xue-mei, WANG Jin-li, WAN Jun, JIAO Kui   

  1. College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P.R. China
  • Received:2003-05-25 Online:2004-04-24 Published:2011-08-06
  • Supported by:

    Supported by the National Natural Science Foundation of China(No.20275020), the Natural Science Foundation of Shandong Province(No.Z2002B02) and the Outstanding Adult-Young Scientific Research Encouraging Foundation of Shandong Province (No.03BS081).

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摘要： The crystal and molecular structures of [(C3H7O)2PS2]2 (CCDC No.217201) were determined by means of X-ray crystallography. It crystallized in a triclinic system with space group P-1 and lattice parameters a=0.82794(3) nm, b=0.84764(2) nm, c=0.85034(3) nm, α=97.78(3)°, β=110.77(3)°, γ= 94. 95 (3)°,V= 0. 54701(9) nm3, Z= 1. In this molecule, the two diisopropyl dithiophosphate groups, [(C3H7O)2PS2]2,which are parallel to each other, are linked by an S-S bond and there exist inversion centers in the molecule.In the structure, the P＝S bonds in the two dithiophosphate units are trans-oriented to each other.

关键词: X-ray crystallography, Dithiophosphate, Centrosymmetry

Abstract: The crystal and molecular structures of [(C3H7O)2PS2]2 (CCDC No.217201) were determined by means of X-ray crystallography. It crystallized in a triclinic system with space group P-1 and lattice parameters a=0.82794(3) nm, b=0.84764(2) nm, c=0.85034(3) nm, α=97.78(3)°, β=110.77(3)°, γ= 94. 95 (3)°,V= 0. 54701(9) nm3, Z= 1. In this molecule, the two diisopropyl dithiophosphate groups, [(C3H7O)2PS2]2,which are parallel to each other, are linked by an S-S bond and there exist inversion centers in the molecule.In the structure, the P＝S bonds in the two dithiophosphate units are trans-oriented to each other.

Key words: X-ray crystallography, Dithiophosphate, Centrosymmetry