A Novel Hydrogen-bonded Three-dimensional Network Complex Containing Nickel

高等学校化学研究 ›› 2004, Vol. 20 ›› Issue (2): 127-130.

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A Novel Hydrogen-bonded Three-dimensional Network Complex Containing Nickel

WANG Li, LI Juan, WANG En-bo

Institute of Polyoxometalate Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun 130024, P.R. China

收稿日期:2003-06-30 出版日期:2004-04-24 发布日期:2011-08-06
基金资助:
Supported by the National Natural Science Foundation of China(No.20171010).

A Novel Hydrogen-bonded Three-dimensional Network Complex Containing Nickel

WANG Li, LI Juan, WANG En-bo

Institute of Polyoxometalate Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun 130024, P.R. China

Received:2003-06-30 Online:2004-04-24 Published:2011-08-06
Supported by:
Supported by the National Natural Science Foundation of China(No.20171010).

摘要/Abstract

摘要： A novel complex, (H₃O)₂[Ni(2,6-pydc)₂]·2H₂O was synthesized in an aqueous solution and characterized by means of single-crystal X-ray diffraction, elemental analyses and IR spectra. The X-ray structural analysis revealed that the novel compound forms three-dimensional(3D) networks by both π-π stacking and hydrogen-bonding interactions. The crystal data for the complex are a = 13. 853 (3) nm, b= 9. 6892 (19) nm,c=13.732(3) nm, α=90. 00°, β=115.52(3)°, γ=90.00°, Z=3, R₁=0.0786, wR₂=0.1522.

关键词: &pi, -&pi, Stacking, Hydrogen-bonding interaction, Three-dimensional(3D) network, 2, 6-Pyridinedicarboxylic acid

Abstract: A novel complex, (H₃O)₂[Ni(2,6-pydc)₂]·2H₂O was synthesized in an aqueous solution and characterized by means of single-crystal X-ray diffraction, elemental analyses and IR spectra. The X-ray structural analysis revealed that the novel compound forms three-dimensional(3D) networks by both π-π stacking and hydrogen-bonding interactions. The crystal data for the complex are a = 13. 853 (3) nm, b= 9. 6892 (19) nm,c=13.732(3) nm, α=90. 00°, β=115.52(3)°, γ=90.00°, Z=3, R₁=0.0786, wR₂=0.1522.

Key words: π-&pi, Stacking, Hydrogen-bonding interaction, Three-dimensional(3D) network, 2,6-Pyridinedicarboxylic acid

WANG Li, LI Juan, WANG En-bo. A Novel Hydrogen-bonded Three-dimensional Network Complex Containing Nickel[J]. 高等学校化学研究, 2004, 20(2): 127-130.

WANG Li, LI Juan, WANG En-bo. A Novel Hydrogen-bonded Three-dimensional Network Complex Containing Nickel[J]. Chemical Research in Chinese Universities, 2004, 20(2): 127-130.

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A Novel Hydrogen-bonded Three-dimensional Network Complex Containing Nickel

A Novel Hydrogen-bonded Three-dimensional Network Complex Containing Nickel

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