Synthesis and Characterization of AlPO4-11 and MAPO-11 Single Crystals

高等学校化学研究 ›› 2004, Vol. 20 ›› Issue (2): 131-133.

Synthesis and Characterization of AlPO₄-11 and MAPO-11 Single Crystals

LI Jian-jun, LI Guo-dong, XI Chun-yu, GUO Ying, CHEN Jie-sheng

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130023, P.R. China

收稿日期:2003-05-26 出版日期:2004-04-24 发布日期:2011-08-06
基金资助:
Supported by the National Natural Science Foundation of China(No.29931010).

Synthesis and Characterization of AlPO₄-11 and MAPO-11 Single Crystals

LI Jian-jun, LI Guo-dong, XI Chun-yu, GUO Ying, CHEN Jie-sheng

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130023, P.R. China

Received:2003-05-26 Online:2004-04-24 Published:2011-08-06
Supported by:
Supported by the National Natural Science Foundation of China(No.29931010).

摘要/Abstract

摘要： The preparation of two types of molecular sieves AlPO₄-11 and MAPO-11 is reported. The particle size of the latter is hundreds of microns, about 10 times larger than that of the former. The XRD, IR and DTA spectra have demonstrated that magnesium has been introduced into the framework of AlPO₄-11. The successful preparation of large single crystal of MAPO-11 will open up a new area for the preparation of large molecular sieves crystals in the future. The large MAPO-11 crystal compound is a promising host for the host-guest assembly of composite materials.

关键词: Single crystal, MAPO-11, Molecular sieve, Host-guest

Abstract: The preparation of two types of molecular sieves AlPO₄-11 and MAPO-11 is reported. The particle size of the latter is hundreds of microns, about 10 times larger than that of the former. The XRD, IR and DTA spectra have demonstrated that magnesium has been introduced into the framework of AlPO₄-11. The successful preparation of large single crystal of MAPO-11 will open up a new area for the preparation of large molecular sieves crystals in the future. The large MAPO-11 crystal compound is a promising host for the host-guest assembly of composite materials.

Key words: Single crystal, MAPO-11, Molecular sieve, Host-guest

LI Jian-jun, LI Guo-dong, XI Chun-yu, GUO Ying, CHEN Jie-sheng. Synthesis and Characterization of AlPO₄-11 and MAPO-11 Single Crystals[J]. 高等学校化学研究, 2004, 20(2): 131-133.

LI Jian-jun, LI Guo-dong, XI Chun-yu, GUO Ying, CHEN Jie-sheng. Synthesis and Characterization of AlPO₄-11 and MAPO-11 Single Crystals[J]. Chemical Research in Chinese Universities, 2004, 20(2): 131-133.

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Synthesis and Characterization of AlPO₄-11 and MAPO-11 Single Crystals

Synthesis and Characterization of AlPO₄-11 and MAPO-11 Single Crystals

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