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高等学校化学研究 ›› 2002, Vol. 18 ›› Issue (4): 385-388.

• Articles • 上一篇    下一篇

Hydrothermal Synthesis and Characterization of a Novel Supramolecular Network Compound [Co(IN)2(H2O)4](IN=Isonicotinate)

JIA Hong-bin1,3, YU Jie-hui1, DING Hong1, XU Ji-qing1, YE Ling2, JING Wei-jie1, WANG Tie-gang1, XU Jia-ning1, QU Xue-jian1, LI Zeng-chun1,3   

  1. 1. College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P. R. China;
    2. Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P. R. China;
    3. Department of Chemistry, Inner Mongolia University for Nationalities, Tongliao 028000, P. R. China
  • 收稿日期:2002-01-18 出版日期:2002-12-24 发布日期:2011-08-04
  • 基金资助:

    Supported by the National Natural Science Foundation of China(No.29733090), the Research Funds for the Doctoral Program of Higher Education, the State Key Laboratory of Coordination Chemistry, Nanjing University and the Funds of Inner Mongolia Education Bureau, China(No.209925).

Hydrothermal Synthesis and Characterization of a Novel Supramolecular Network Compound [Co(IN)2(H2O)4](IN=Isonicotinate)

JIA Hong-bin1,3, YU Jie-hui1, DING Hong1, XU Ji-qing1, YE Ling2, JING Wei-jie1, WANG Tie-gang1, XU Jia-ning1, QU Xue-jian1, LI Zeng-chun1,3   

  1. 1. College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P. R. China;
    2. Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P. R. China;
    3. Department of Chemistry, Inner Mongolia University for Nationalities, Tongliao 028000, P. R. China
  • Received:2002-01-18 Online:2002-12-24 Published:2011-08-04
  • Supported by:

    Supported by the National Natural Science Foundation of China(No.29733090), the Research Funds for the Doctoral Program of Higher Education, the State Key Laboratory of Coordination Chemistry, Nanjing University and the Funds of Inner Mongolia Education Bureau, China(No.209925).

PDF (PC)

摘要： A novel supramolecular compound, [Co(IN)2(H2O)4](1), was synthesized by means of the hydrothermal method and its structure was characterized with elemental analysis, FT-IR spectrum, TGA and X-ray diffraction. Though the unit cell structure of the title compound is only monomeric, all these units as building blocks are assembled into a novel three-dimensional supramolecular network via the widely hydrogen-bonding and π-π stacking interactions.

关键词: Hydrothermal synthesis, Cobalt(Ⅱ) complex, X-Ray diffraction, Isonicotinate, Supramolecule

Abstract: A novel supramolecular compound, [Co(IN)2(H2O)4](1), was synthesized by means of the hydrothermal method and its structure was characterized with elemental analysis, FT-IR spectrum, TGA and X-ray diffraction. Though the unit cell structure of the title compound is only monomeric, all these units as building blocks are assembled into a novel three-dimensional supramolecular network via the widely hydrogen-bonding and π-π stacking interactions.

Key words: Hydrothermal synthesis, Cobalt(Ⅱ) complex, X-Ray diffraction, Isonicotinate, Supramolecule