Fenton Reagent Generated in Electrolysis Cell and Its Usage in Degradation and Decolorization of Dyes

高等学校化学研究 ›› 2002, Vol. 18 ›› Issue (1): 34-37.

Fenton Reagent Generated in Electrolysis Cell and Its Usage in Degradation and Decolorization of Dyes

CHEN Zhen¹, ZHENG Xi¹, CHEN Ri-yao¹, LAN Rui-fang¹, LIN Zhi-hong¹, CHEN Yu-feng¹, ZHANG Yi-kang²

1. Experiment Center, Fujian Normal University, Fuzhou 350007, P. R. China;
2. Linyi Normal College, Linyi 276001, P. R. China

收稿日期:2000-12-14 出版日期:2002-01-24 发布日期:2011-08-04
基金资助:
Supported by the Foundation of Fujian Education Committee(AJ00153).

Fenton Reagent Generated in Electrolysis Cell and Its Usage in Degradation and Decolorization of Dyes

CHEN Zhen¹, ZHENG Xi¹, CHEN Ri-yao¹, LAN Rui-fang¹, LIN Zhi-hong¹, CHEN Yu-feng¹, ZHANG Yi-kang²

1. Experiment Center, Fujian Normal University, Fuzhou 350007, P. R. China;
2. Linyi Normal College, Linyi 276001, P. R. China

Received:2000-12-14 Online:2002-01-24 Published:2011-08-04
Supported by:
Supported by the Foundation of Fujian Education Committee(AJ00153).

摘要/Abstract

摘要： The Electro-chemistry process to produce Fenton reagents has been described. The in situ oxidation of dyes, acid chrome and alizarin red(Fenton reagents) with electrogenerated hydroxyl radicals was investigated. The I-Vcyclic voltammograms were measured. The redox peaks of the dyes were not observed in the treated dye solutions instead of a couple of O₂/H₂O₂ redox peaks. The IR results indicate that acid chrome dye was decomposed into naphthylamine and phenol aminophenol sulfonic acid. The degradation and the decolorization of the dyes were comfirmed by the visible spectrum and the chemical analysis. The COD_cr removing rate was close to 80%.

关键词: Dye, Wastewater, Degradation, Decolorization

Abstract: The Electro-chemistry process to produce Fenton reagents has been described. The in situ oxidation of dyes, acid chrome and alizarin red(Fenton reagents) with electrogenerated hydroxyl radicals was investigated. The I-Vcyclic voltammograms were measured. The redox peaks of the dyes were not observed in the treated dye solutions instead of a couple of O₂/H₂O₂ redox peaks. The IR results indicate that acid chrome dye was decomposed into naphthylamine and phenol aminophenol sulfonic acid. The degradation and the decolorization of the dyes were comfirmed by the visible spectrum and the chemical analysis. The COD_cr removing rate was close to 80%.

Key words: Dye, Wastewater, Degradation, Decolorization

CHEN Zhen, ZHENG Xi, CHEN Ri-yao, LAN Rui-fang, LIN Zhi-hong, CHEN Yu-feng, ZHANG Yi-kang. Fenton Reagent Generated in Electrolysis Cell and Its Usage in Degradation and Decolorization of Dyes[J]. 高等学校化学研究, 2002, 18(1): 34-37.

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Fenton Reagent Generated in Electrolysis Cell and Its Usage in Degradation and Decolorization of Dyes

Fenton Reagent Generated in Electrolysis Cell and Its Usage in Degradation and Decolorization of Dyes

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