Nanostructured Columns from Self-assembly of Complementary Molecular Components

高等学校化学研究 ›› 2001, Vol. 17 ›› Issue (2): 193-197.

Nanostructured Columns from Self-assembly of Complementary Molecular Components

YANG Wen-sheng¹, YANG Bai-quan¹, JIANG Yue-shun¹, LI Tie-jin¹, LIU Ya-Juan²

1. Department of Chemistry, Jilin University, Changchun, 130023, P. R. China;
2. Institute of Information Technology, Jilin Agriculture University, Changchun, 130118, P. R. China

收稿日期:1999-01-18 出版日期:2001-04-24 发布日期:2011-08-04
基金资助:
Nanocolumn|Self-assembly|π-aromatic stacking|Molecular recognition

Nanostructured Columns from Self-assembly of Complementary Molecular Components

YANG Wen-sheng¹, YANG Bai-quan¹, JIANG Yue-shun¹, LI Tie-jin¹, LIU Ya-Juan²

1. Department of Chemistry, Jilin University, Changchun, 130023, P. R. China;
2. Institute of Information Technology, Jilin Agriculture University, Changchun, 130118, P. R. China

Received:1999-01-18 Online:2001-04-24 Published:2011-08-04
Supported by:
Supported by the National Natural Science Foundation of China.

摘要/Abstract

摘要： Nanostructured columns with a length about several tens of micrometer and a diameter of about 80 nm were obtained by molecular recognition directed self-assembly of a pair of comple mentary molecular components, 4-amino-2,6-didodecylamino-1,3,5-triazine (M) and 5- (4-dode cyloxybenzylidene)-(1H, 3H)-2,4,6-pyrimidinetrione (B) in chloroform. In this system, with positive cooperativity, r-aromatic stacking and van der Waals interactions as well as hydrogen bonds cause the formation of the nanocolumns.

关键词: Nanocolumn, Self-assembly, &pi, -aromatic stacking, Molecular recognition

Abstract: Nanostructured columns with a length about several tens of micrometer and a diameter of about 80 nm were obtained by molecular recognition directed self-assembly of a pair of comple mentary molecular components, 4-amino-2,6-didodecylamino-1,3,5-triazine (M) and 5- (4-dode cyloxybenzylidene)-(1H, 3H)-2,4,6-pyrimidinetrione (B) in chloroform. In this system, with positive cooperativity, r-aromatic stacking and van der Waals interactions as well as hydrogen bonds cause the formation of the nanocolumns.

Key words: Nanocolumn, Self-assembly, π-aromatic stacking, Molecular recognition

YANG Wen-sheng, YANG Bai-quan, JIANG Yue-shun, LI Tie-jin, LIU Ya-Juan. Nanostructured Columns from Self-assembly of Complementary Molecular Components[J]. 高等学校化学研究, 2001, 17(2): 193-197.

YANG Wen-sheng, YANG Bai-quan, JIANG Yue-shun, LI Tie-jin, LIU Ya-Juan. Nanostructured Columns from Self-assembly of Complementary Molecular Components[J]. Chemical Research in Chinese Universities, 2001, 17(2): 193-197.

[1]	CHEN Sisi, ZHANG Lei, YUAN Quan, TAN Jie. Current Advances in Aptamer-based Biomolecular Recognition and Biological Process Regulation[J]. 高等学校化学研究, 2022, 38(4): 847-855.
[2]	TANG Tianwei, LIU Yinghuan, JIANG Ying. Recent Progress on Highly Selective and Sensitive Electrochemical Aptamer-based Sensors[J]. 高等学校化学研究, 2022, 38(4): 866-878.
[3]	CHANG Kaili, SUN Peng, DONG Xin, ZHU Chunnan, LIU Xiaojun, ZHENG Dongyun, LIU Chao. Aptamers as Recognition Elements for Electrochemical Detection of Exosomes[J]. 高等学校化学研究, 2022, 38(4): 879-885.
[4]	GAO Huimin, SHI Rui, ZHU Youliang, QIAN Hujun and LU Zhongyuan. Coarse-grained Dynamics Simulation in Polymer Systems: from Structures to Material Properties[J]. 高等学校化学研究, 2022, 38(3): 653-670.
[5]	YANG Miao, WANG Wenjing, SU Kongzhao, YUAN Daqiang. Dimeric Calix[4]resorcinarene-based Porous Organic Cages for CO₂/CH₄ Separation[J]. 高等学校化学研究, 2022, 38(2): 428-432.
[6]	QIAO Junyi, LIU Xinyao, ZHANG Lirong, LIU Yunling. Self-assembly of 3p-Block Metal-based Metal-Organic Frameworks from Structural Perspective[J]. 高等学校化学研究, 2022, 38(1): 31-44.
[7]	FENG Enduo, TIAN Yang. Surface-enhanced Raman Scattering of Self-assembled Superstructures[J]. 高等学校化学研究, 2021, 37(5): 989-1007.
[8]	Andy Shun-Hoi CHEUNG, Sammual Yu-Lut LEUNG, Franky Ka-Wah HAU, Vivian Wing-Wah YAM. Supramolecular Self-assembly of Amphiphilic Alkynyl-platinum(II) 2,6-Bis(N-alkylbenzimidazol-2'-yl) pyridine Complexes[J]. 高等学校化学研究, 2021, 37(5): 1079-1084.
[9]	HAN Lin, WANG Yuang, TANG Wantao, LIU Jianbing, DING Baoquan. Bioimaging Based on Nucleic Acid Nanostructures[J]. 高等学校化学研究, 2021, 37(4): 823-828.
[10]	REN Yiqing, LIU Xinlong, GE Huan, GUO Yuanyuan, ZHANG Qiushuang, XIE Miao, WANG Ping, ZHU Xinyuan, ZHANG Chuan. A Combinatorial Approach Based on Nucleic Acid Assembly and Electrostatic Compression for siRNA Delivery[J]. 高等学校化学研究, 2021, 37(4): 906-913.
[11]	YANG Jia, ZHENG Rui, AN Hongwei, WANG Hao. In vivo Self-assembled Peptide Nanoprobes for Disease Diagnosis[J]. 高等学校化学研究, 2021, 37(4): 855-869.
[12]	LIU Zhiyu, LIANG Gaolin, ZHAN Wenjun. In situ Activatable Peptide-based Nanoprobes for Tumor Imaging[J]. 高等学校化学研究, 2021, 37(4): 889-899.
[13]	LI Lun, XUE Xiaoxia, SUN Yimeng, ZHAO Wuduo, LI Tiesheng, LIU Minghua, WU Yangjie. Self-assembly Palladacycle Thiophene Imine Monolayer—Investigating on Catalytic Activity and Mechanism for Coupling Reaction[J]. 高等学校化学研究, 2020, 36(5): 821-828.
[14]	ZHANG Junjie, WANG Can, DUAN Ruomeng, PENG Chencheng, YANG Biao, CAO Nan, ZHANG Haiming, CHI Lifeng. Two-dimensional Molecular Phase Transition of Alkylated-TDPB on Au(111) and Cu(111) Surfaces[J]. 高等学校化学研究, 2020, 36(4): 685-689.
[15]	LIU Shengtang, YANG Miao, LIU Cheng, TIAN Bailin, DING Mengning. Superlattice Structure from Re-stacked NiFe Layer Double Hydroxides for Oxygen Evolution Reaction[J]. 高等学校化学研究, 2020, 36(4): 680-684.

Nanostructured Columns from Self-assembly of Complementary Molecular Components

Nanostructured Columns from Self-assembly of Complementary Molecular Components

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价