A Study on 4,4′-Diaminobenzene Sulfonanilide(DABSA) and the Properties of Dyes Derived from DABSA

高等学校化学研究 ›› 2001, Vol. 17 ›› Issue (1): 77-87.

A Study on 4,4′-Diaminobenzene Sulfonanilide(DABSA) and the Properties of Dyes Derived from DABSA

WU Zu-Wang¹, WANG Li-Min¹, DAI Jian-Ying¹, WANG Shi-Rong¹, XIAO Jin-Qiu¹, LIU Xiu-Mei², HAN Xiu-Wen², ZHAO Qi², BAO Xin-He²

1. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China;
2. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Dalian 116024, China

收稿日期:1999-10-22 出版日期:2001-01-24 发布日期:2011-08-04
基金资助:
Supported by Dankong Dyestuff Foundation.

A Study on 4,4′-Diaminobenzene Sulfonanilide(DABSA) and the Properties of Dyes Derived from DABSA

WU Zu-Wang¹, WANG Li-Min¹, DAI Jian-Ying¹, WANG Shi-Rong¹, XIAO Jin-Qiu¹, LIU Xiu-Mei², HAN Xiu-Wen², ZHAO Qi², BAO Xin-He²

1. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China;
2. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Dalian 116024, China

Received:1999-10-22 Online:2001-01-24 Published:2011-08-04
Supported by:
Supported by Dankong Dyestuff Foundation.

摘要/Abstract

摘要： A single crystal of 4,4′-diaminobenzene sulfonanilide(DABSA) was determined by X-ray diffraction method. It is shown that the two benzene rings are non-planar with an angle of 55.1°. Owing to the non-planar configuration, the dyes derived from DABSA possess a lower substantivity on fiber but better permeability in substrate, the color of these azo dyes could be matched by two individual azo dyes locating on both sides of the DABSA molecule.

关键词: 4, 4'-Diaminobenzene sulfonanilide, Configuration, X-ray diffraction, Non-carcinogenic substituent for benzidine, Substantivity of dye, Azo-hydrazone tautomers

Abstract: A single crystal of 4,4′-diaminobenzene sulfonanilide(DABSA) was determined by X-ray diffraction method. It is shown that the two benzene rings are non-planar with an angle of 55.1°. Owing to the non-planar configuration, the dyes derived from DABSA possess a lower substantivity on fiber but better permeability in substrate, the color of these azo dyes could be matched by two individual azo dyes locating on both sides of the DABSA molecule.

Key words: 4,4'-Diaminobenzene sulfonanilide, Configuration, X-ray diffraction, Non-carcinogenic substituent for benzidine, Substantivity of dye, Azo-hydrazone tautomers

WU Zu-Wang, WANG Li-Min, DAI Jian-Ying, WANG Shi-Rong, XIAO Jin-Qiu, LIU Xiu-Mei, HAN Xiu-Wen, ZHAO Qi, BAO Xin-He . A Study on 4,4′-Diaminobenzene Sulfonanilide(DABSA) and the Properties of Dyes Derived from DABSA[J]. 高等学校化学研究, 2001, 17(1): 77-87.

[1]	CHEN Weijie, XIA Huicong, GUO Kai, JIN Wangzhe, DU Yu, YAN Wenfu, QU Gan, ZHANG Jianan. Atomically Dispersed Fe-N₄ Sites and Fe₃C Particles Catalyzing Polysulfides Conversion in Li-S Batteries[J]. 高等学校化学研究, 2022, 38(5): 1232-1238.
[2]	SHEN Congcong, CHEN Yuehua, FENG Beidou, CHI Hongying, ZHANG Hua. Polypyrrole Hollow Nanotubes Loaded with Au and Fe₃O₄ Nanoparticles for Simultaneous Determination of Ascorbic Acid, Dopamine, and Uric Acid[J]. 高等学校化学研究, 2022, 38(4): 941-948.
[3]	WANG Yue, WANG Jinling, MA Jianxin, ZHANG Yue, XU Na, WANG Xiuli. Multi-functional Photoelectric Sensor Based on a Three-fold Interpenetrated Cd(II) Coordination Polymer for Sensitively Detecting Different Ions[J]. 高等学校化学研究, 2022, 38(4): 1105-1110.
[4]	JIANG Jian. Observation of a 3-in-1 Russian-doll-like Complex in Solution[J]. 高等学校化学研究, 2022, 38(2): 497-499.
[5]	DI Zhengyi, MAO Yining, YUAN Heng, ZHOU Yan, JIN Jun, LI Cheng-Peng. Covalent Organic Frameworks(COFs) for Sequestration of⁹⁹TcO₄^–[J]. 高等学校化学研究, 2022, 38(2): 290-295.
[6]	ZHANG Tingting, LUO Pan, LAI Can, LIU Zheyi, JIN Yan, WANG Fangjun. Catalyst-free Photochemical Bromination of Unprotected Aromatic Amino Acid Derivatives by Using a Rotating Ultraviolet Photoreactor[J]. 高等学校化学研究, 2022, 38(2): 505-509.
[7]	YANG Miao, WANG Wenjing, SU Kongzhao, YUAN Daqiang. Dimeric Calix[4]resorcinarene-based Porous Organic Cages for CO₂/CH₄ Separation[J]. 高等学校化学研究, 2022, 38(2): 428-432.
[8]	ZHOU Xue, WANG Chao, CHU Yueying, WANG Qiang, XU Jun, DENG Feng. Mechanistic Insight into Ethanol Dehydration over SAPO-34 Zeolite by Solid-state NMR Spectroscopy[J]. 高等学校化学研究, 2022, 38(1): 155-160.
[9]	ZHANG Yunzhe, DAI Weili, WU Guangjun, GUAN Naijia, LI Landong. Catalytic Hydration of Aromatic Alkynes to Ketones over H-MFI Zeolites[J]. 高等学校化学研究, 2022, 38(1): 173-180.
[10]	LUO Li, WANG Sen, WU Zhiwei, QIN Zhangfeng, DONG Mei, WANG Jianguo, FAN Weibin. Influence of the ZSM-5 Support Acidity on the Catalytic Performance of Pd/ZSM-5 in Lean Methane Oxidation[J]. 高等学校化学研究, 2022, 38(1): 229-236.
[11]	LIANG Jun, FU Wenhua, LIU Chuang, LI Xiangcheng, WANG Yu, MA Duozheng, LI Yuekun, WANG Zhendong, YANG Weimin. Synthesis of FER Zeolite Using 4-(Aminomethyl) pyridine as Structure-directing Agent[J]. 高等学校化学研究, 2022, 38(1): 243-249.
[12]	DENG Tianyin, HE Xiaohui, LIU Haichao. Insights into the Active Acid Sites for Isosorbide Synthesis from Renewable Sorbitol and Cellulose on Solid Acid Catalysts[J]. 高等学校化学研究, 2022, 38(1): 257-264.
[13]	RONG Xin, LU Xiuli, LU Tongbu. Three-dimensional Pyrenyl Graphdiyne Supported Pd Nanoparticle as an Efficient and Easily Recyclable Catalyst for Reduction of 4-Nitrophenol[J]. 高等学校化学研究, 2021, 37(6): 1296-1300.
[14]	ZHU Ruonan, WANG Jun, LI Jie. Li₄Mn₅O₁₂Cathode for Both 3 V and 4 V Lithium-ion Batteries[J]. 高等学校化学研究, 2021, 37(5): 1031-1043.
[15]	LI Haiyan, LIU Mingyue, WANG Xiaoyu, WANG Hongsheng, MO Xiumei, WU Jinglei. Nanofiber Configuration of Electrospun Scaffolds Dictating Cell Behaviors and Cell-scaffold Interactions[J]. 高等学校化学研究, 2021, 37(3): 456-463.

A Study on 4,4′-Diaminobenzene Sulfonanilide(DABSA) and the Properties of Dyes Derived from DABSA

A Study on 4,4′-Diaminobenzene Sulfonanilide(DABSA) and the Properties of Dyes Derived from DABSA

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价