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高等学校化学研究 ›› 2000, Vol. 16 ›› Issue (3): 198-202.

• Articles • 上一篇    下一篇

A Novel Dimer——Heteropolytungstate with a Vanadium Atom as the Centre ——Synthesis and Structural Characterization of （H3O）4[VW12O40Na（H2O）4]2

LIU Zong-rui1,2, XU Lin1, WANG En-bo1, PENG Jun1, HU Chang-wen1, XING Yan3, LIN Yong-hua3, JIA Heng-qing3   

  1. 1. Department of Chemistry, Northeast Normal University, Changchun 130024, P. R. China;
    2. Inner Mongolia Teachers' College for Nationalities, Tongliao 028043, P. R. China;
    3. Changchun Insitute of Applied Chemistry, Acadamia of Sinica, Changchun 130022, P. R. China
  • 收稿日期:1999-05-27 出版日期:2000-08-24 发布日期:2011-10-22
  • 基金资助:

    Supported financially by the Key laboratory of Inorganic Hydrothermal Synthesis of Jilin University.

A Novel Dimer——Heteropolytungstate with a Vanadium Atom as the Centre ——Synthesis and Structural Characterization of （H3O）4[VW12O40Na（H2O）4]2

LIU Zong-rui1,2, XU Lin1, WANG En-bo1, PENG Jun1, HU Chang-wen1, XING Yan3, LIN Yong-hua3, JIA Heng-qing3   

  1. 1. Department of Chemistry, Northeast Normal University, Changchun 130024, P. R. China;
    2. Inner Mongolia Teachers' College for Nationalities, Tongliao 028043, P. R. China;
    3. Changchun Insitute of Applied Chemistry, Acadamia of Sinica, Changchun 130022, P. R. China
  • Received:1999-05-27 Online:2000-08-24 Published:2011-10-22
  • Supported by:

    Supported financially by the Key laboratory of Inorganic Hydrothermal Synthesis of Jilin University.

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摘要： A novel dimer-tungstovanadate, (H3O)4[VW12 O40 Na(H2O)4]2, was hydrothermally synthesized and structurally characterized by single crystal X ray diffraction, IRspectra, TGA-DSC thermal analysis and polarograpy. The yellowish crystal crystallized in the triclinic system, space group P1, a =1.4645(3) nm, b =1.4686(3) nm, c =1.4111(3) nm, α=111.82(2)°, β=93.17(3)°, γ=117.47(3)°, V =2.2106(8) nm3, Z=1, Dc=4.552 g·cm3 , λ(Mo Kα )=0.071073 nm, μ =31.402 mm-1 , F(000)=2648, R =0.0780. The title compound consists of two Keggin structure units linked together with two hydrated sodium cations to form a dimer with a porous structure with the pore dimension of 0.766 nm×0.7785 nm.

关键词: Synthesis, Crystal structure, Tungstovanadate

Abstract: A novel dimer-tungstovanadate, (H3O)4[VW12 O40 Na(H2O)4]2, was hydrothermally synthesized and structurally characterized by single crystal X ray diffraction, IRspectra, TGA-DSC thermal analysis and polarograpy. The yellowish crystal crystallized in the triclinic system, space group P1, a =1.4645(3) nm, b =1.4686(3) nm, c =1.4111(3) nm, α=111.82(2)°, β=93.17(3)°, γ=117.47(3)°, V =2.2106(8) nm3, Z=1, Dc=4.552 g·cm3 , λ(Mo Kα )=0.071073 nm, μ =31.402 mm-1 , F(000)=2648, R =0.0780. The title compound consists of two Keggin structure units linked together with two hydrated sodium cations to form a dimer with a porous structure with the pore dimension of 0.766 nm×0.7785 nm.

Key words: Synthesis, Crystal structure, Tungstovanadate