Heteropolytungstates Containing Organotin and Cobalt or Zinc Atom

高等学校化学研究 ›› 1999, Vol. 15 ›› Issue (4): 317-321.

Heteropolytungstates Containing Organotin and Cobalt or Zinc Atom

WANG Xiao-hong, FANG Xi-kui, LIU Jing-fu

Department of Chemistry, Northeast Normal University, Changchun 130024, P. R. China

收稿日期:1998-10-28 出版日期:1999-12-24 发布日期:2011-08-17
通讯作者: LIU Jing-fu
基金资助:
Supported by the National Natural Science Foundation of China.

Heteropolytungstates Containing Organotin and Cobalt or Zinc Atom

WANG Xiao-hong, FANG Xi-kui, LIU Jing-fu

Department of Chemistry, Northeast Normal University, Changchun 130024, P. R. China

Received:1998-10-28 Online:1999-12-24 Published:2011-08-17
Supported by:
Supported by the National Natural Science Foundation of China.

摘要/Abstract

摘要： Organotin substituted heteropolytungstates with cobalt or zinc atom as the central atom, K₆H[XW₁₁ O₃₉ (RSn)]· nH₂O (X=Zn, Co; R=CH₃OOCCH₂CH₂, CH₂O OCCH(CH₃)CH₂, NCCH₂CH₂) were prepared and characterized by elemental analysis, IR, UV-Vis spectroscopy, ESR, NMR spectroscopy and electrochemical study. The results show that these anions possess Keggin-like structures.

关键词: Organotin, Transition metal, Heteropolyanion

Abstract: Organotin substituted heteropolytungstates with cobalt or zinc atom as the central atom, K₆H[XW₁₁ O₃₉ (RSn)]· nH₂O (X=Zn, Co; R=CH₃OOCCH₂CH₂, CH₂O OCCH(CH₃)CH₂, NCCH₂CH₂) were prepared and characterized by elemental analysis, IR, UV-Vis spectroscopy, ESR, NMR spectroscopy and electrochemical study. The results show that these anions possess Keggin-like structures.

Key words: Organotin, Transition metal, Heteropolyanion

WANG Xiao-hong, FANG Xi-kui, LIU Jing-fu . Heteropolytungstates Containing Organotin and Cobalt or Zinc Atom[J]. 高等学校化学研究, 1999, 15(4): 317-321.

WANG Xiao-hong, FANG Xi-kui, LIU Jing-fu . Heteropolytungstates Containing Organotin and Cobalt or Zinc Atom[J]. Chemical Research in Chinese Universities, 1999, 15(4): 317-321.

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Heteropolytungstates Containing Organotin and Cobalt or Zinc Atom

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