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高等学校化学研究 ›› 1990, Vol. 6 ›› Issue (4): 271-275.

• Articles • 上一篇    下一篇

Synthesis and Crystal Structure of Tri(8-quinolinol) Yttrium-Tri(8-quinolinol) Nickel Perchlorate [YQ(HQ)2][NiQ3](ClO4)

Zhang Mingjie, Huang Chunhui, Xu Guangxian   

  1. Chemistry Department, Peking University, Beijing
  • 收稿日期:1990-06-17 出版日期:1990-12-24 发布日期:2011-09-09

Synthesis and Crystal Structure of Tri(8-quinolinol) Yttrium-Tri(8-quinolinol) Nickel Perchlorate [YQ(HQ)2][NiQ3](ClO4)

Zhang Mingjie, Huang Chunhui, Xu Guangxian   

  1. Chemistry Department, Peking University, Beijing
  • Received:1990-06-17 Online:1990-12-24 Published:2011-09-09

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摘要： The title compound was synthesised and the X-ray diffraction analysis shows that the crystal belongs to in monoclinic system, space group P21/n with α=16.972(4) A ,b=14.128(3)A , c=22.615(4)A ,β=103.16(2)°,V=528.14A3,F(000)=2264, Z=4. Both cation [YQ(HQ)2]2+ and anion [NiQ3]- are of distorded octahedral geometry with coordination number of 6. Its IRspectrum was recorded.

关键词: 8-Quinolinol, Yttrium, Nickel, Complex, Crystal structure

Abstract: The title compound was synthesised and the X-ray diffraction analysis shows that the crystal belongs to in monoclinic system, space group P21/n with α=16.972(4) A ,b=14.128(3)A , c=22.615(4)A ,β=103.16(2)°,V=528.14A3,F(000)=2264, Z=4. Both cation [YQ(HQ)2]2+ and anion [NiQ3]- are of distorded octahedral geometry with coordination number of 6. Its IRspectrum was recorded.

Key words: 8-Quinolinol, Yttrium, Nickel, Complex, Crystal structure