Protonated Mesoporous Aluminosilica Nanospheres Boosting Aza-Michael Cyclization and Diels-Alder Reaction

doi:10.1007/s40242-024-4033-5

高等学校化学研究 ›› 2024, Vol. 40 ›› Issue (6): 1127-1133.doi: 10.1007/s40242-024-4033-5

Protonated Mesoporous Aluminosilica Nanospheres Boosting Aza-Michael Cyclization and Diels-Alder Reaction

LI Baoyan¹, MENG Jingjing¹, LI Yingding¹, JIANG Lingxia², CHENG Tanyu¹, LIU Guohua¹

1. The Education Ministry Key Lab of Resource Chemistry, Joint International Research Laboratory of Resource Chemistry, Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, College of Chemistry and Materials Science, Shanghai Normal University, Shanghai 200234, P. R. China;
2. Lianhe Chemical Technology Co., Ltd., Yancheng 224631, P. R. China

收稿日期:2024-02-20 出版日期:2024-12-01 发布日期:2024-10-26
通讯作者: CHENG Tanyu,tycheng@shnu.edu.cn;LIU Guohua,ghliu@shnu.edu.cn E-mail:tycheng@shnu.edu.cn;ghliu@shnu.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (No. 21872095), the “111” Innovation and Talent Recruitment Base on Photochemical and Energy Materials, China (No. D18020), and the Project of Shanghai Engineering Research Center of Green Energy Chemical Engineering, China (No. 18DZ2254200).

Protonated Mesoporous Aluminosilica Nanospheres Boosting Aza-Michael Cyclization and Diels-Alder Reaction

LI Baoyan¹, MENG Jingjing¹, LI Yingding¹, JIANG Lingxia², CHENG Tanyu¹, LIU Guohua¹

1. The Education Ministry Key Lab of Resource Chemistry, Joint International Research Laboratory of Resource Chemistry, Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, College of Chemistry and Materials Science, Shanghai Normal University, Shanghai 200234, P. R. China;
2. Lianhe Chemical Technology Co., Ltd., Yancheng 224631, P. R. China

Received:2024-02-20 Online:2024-12-01 Published:2024-10-26
Contact: CHENG Tanyu,tycheng@shnu.edu.cn;LIU Guohua,ghliu@shnu.edu.cn E-mail:tycheng@shnu.edu.cn;ghliu@shnu.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (No. 21872095), the “111” Innovation and Talent Recruitment Base on Photochemical and Energy Materials, China (No. D18020), and the Project of Shanghai Engineering Research Center of Green Energy Chemical Engineering, China (No. 18DZ2254200).

摘要/Abstract

摘要： Mesoporous aluminosilica hollow nanospheres were prepared easily, which possess very strong acid site. The heterogeneous catalyst can be utilized in both intramolecular aza-Michael addition cyclization and intermolecular Diels-Alder reaction. The catalyst could be easily recovered and reused. Furthermore, the catalyst could be used in continuous flow chemistry for the uninterrupted synthesis of 2,3-dihydroquinolin-4(1H)-ones, which disclosed the potential application of the present solid catalyst in both academic and industrial syntheses. In addition, the catalyst could be recovered and reused at least 7 times without obvious loss of activity.

关键词: Heterogeneous catalyst, Aluminosilica nanosphere, Mesoporous, Aza-Michael cyclization, Diels-Alder reaction

Abstract: Mesoporous aluminosilica hollow nanospheres were prepared easily, which possess very strong acid site. The heterogeneous catalyst can be utilized in both intramolecular aza-Michael addition cyclization and intermolecular Diels-Alder reaction. The catalyst could be easily recovered and reused. Furthermore, the catalyst could be used in continuous flow chemistry for the uninterrupted synthesis of 2,3-dihydroquinolin-4(1H)-ones, which disclosed the potential application of the present solid catalyst in both academic and industrial syntheses. In addition, the catalyst could be recovered and reused at least 7 times without obvious loss of activity.

Key words: Heterogeneous catalyst, Aluminosilica nanosphere, Mesoporous, Aza-Michael cyclization, Diels-Alder reaction

LI Baoyan, MENG Jingjing, LI Yingding, JIANG Lingxia, CHENG Tanyu, LIU Guohua. Protonated Mesoporous Aluminosilica Nanospheres Boosting Aza-Michael Cyclization and Diels-Alder Reaction[J]. 高等学校化学研究, 2024, 40(6): 1127-1133.

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Protonated Mesoporous Aluminosilica Nanospheres Boosting Aza-Michael Cyclization and Diels-Alder Reaction

Protonated Mesoporous Aluminosilica Nanospheres Boosting Aza-Michael Cyclization and Diels-Alder Reaction

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