Prussian Blue Analogue Derived N-Doped Graphitic Carbon Wrapped Iron-Cobalt Nanoparticles as Recyclable Heterogeneous Catalysts for Friedel-Crafts Acylation

doi:10.1007/s40242-024-4020-x

高等学校化学研究 ›› 2024, Vol. 40 ›› Issue (6): 1116-1126.doi: 10.1007/s40242-024-4020-x

Prussian Blue Analogue Derived N-Doped Graphitic Carbon Wrapped Iron-Cobalt Nanoparticles as Recyclable Heterogeneous Catalysts for Friedel-Crafts Acylation

LEI Zhenyu, SUN Honglei, DONG Zhehan, SUN Shuaishuai, BI Chongyao, ZHAN Junling, WU Lin, JIA Mingjun

JIA Mingjun jiamj@jlu. edu. cn Department of Physical Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

收稿日期:2024-01-22 出版日期:2024-12-01 发布日期:2024-10-26
通讯作者: JIA Mingjun,jiamj@jlu.edu.cn E-mail:jiamj@jlu.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (No. 22172058).

Prussian Blue Analogue Derived N-Doped Graphitic Carbon Wrapped Iron-Cobalt Nanoparticles as Recyclable Heterogeneous Catalysts for Friedel-Crafts Acylation

LEI Zhenyu, SUN Honglei, DONG Zhehan, SUN Shuaishuai, BI Chongyao, ZHAN Junling, WU Lin, JIA Mingjun

JIA Mingjun jiamj@jlu. edu. cn Department of Physical Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2024-01-22 Online:2024-12-01 Published:2024-10-26
Contact: JIA Mingjun,jiamj@jlu.edu.cn E-mail:jiamj@jlu.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (No. 22172058).

摘要/Abstract

摘要： The rational design of efficient heterogeneous catalysts for Friedel-Crafts acylation reactions is highly desirable for meeting the need for the industrial production of various aromatic ketone compounds and biomass-derived chemicals. Herein, we reported that graphitic carbon wrapped FeCo bimetallic nanoparticles confined in nitrogen-doped carbon nanotubes, which were prepared by pyrolysis of FeCo-based Prussian blue analogue and melamine via a two-stage programmed heating procedure, exhibited excellent catalytic activity and recyclability for the acylation of aromatic compounds with acyl chlorides. The oxidized bimetallic species embedded in the external graphitic carbon shell should be the main active sites for the acylation reaction. The graphitic carbon shell and the carbon nanotube could provide effective protection on the active metal species against leaching through multiple interactions, leading to the formation of a highly active and durable heterogeneous catalyst for the acylation reaction.

关键词: Prussian blue analogue, N-Doped carbon material, Pyrolysis, Bimetallic nanoparticle, Friedel-Crafts acylation

Abstract: The rational design of efficient heterogeneous catalysts for Friedel-Crafts acylation reactions is highly desirable for meeting the need for the industrial production of various aromatic ketone compounds and biomass-derived chemicals. Herein, we reported that graphitic carbon wrapped FeCo bimetallic nanoparticles confined in nitrogen-doped carbon nanotubes, which were prepared by pyrolysis of FeCo-based Prussian blue analogue and melamine via a two-stage programmed heating procedure, exhibited excellent catalytic activity and recyclability for the acylation of aromatic compounds with acyl chlorides. The oxidized bimetallic species embedded in the external graphitic carbon shell should be the main active sites for the acylation reaction. The graphitic carbon shell and the carbon nanotube could provide effective protection on the active metal species against leaching through multiple interactions, leading to the formation of a highly active and durable heterogeneous catalyst for the acylation reaction.

Key words: Prussian blue analogue, N-Doped carbon material, Pyrolysis, Bimetallic nanoparticle, Friedel-Crafts acylation

LEI Zhenyu, SUN Honglei, DONG Zhehan, SUN Shuaishuai, BI Chongyao, ZHAN Junling, WU Lin, JIA Mingjun. Prussian Blue Analogue Derived N-Doped Graphitic Carbon Wrapped Iron-Cobalt Nanoparticles as Recyclable Heterogeneous Catalysts for Friedel-Crafts Acylation[J]. 高等学校化学研究, 2024, 40(6): 1116-1126.

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Prussian Blue Analogue Derived N-Doped Graphitic Carbon Wrapped Iron-Cobalt Nanoparticles as Recyclable Heterogeneous Catalysts for Friedel-Crafts Acylation

Prussian Blue Analogue Derived N-Doped Graphitic Carbon Wrapped Iron-Cobalt Nanoparticles as Recyclable Heterogeneous Catalysts for Friedel-Crafts Acylation

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