Promoting Effect of ZnO on the Catalytic Performance of CoZSM-5 for CO2-Assisted Dehydrogenation of Ethane

doi:10.1007/s40242-023-3131-0

高等学校化学研究 ›› 2023, Vol. 39 ›› Issue (6): 1064-1069.doi: 10.1007/s40242-023-3131-0

Promoting Effect of ZnO on the Catalytic Performance of CoZSM-5 for CO₂-Assisted Dehydrogenation of Ethane

HE Huan, ZOU Zhengxi, HUA Weiming, YUE Yinghong, and GAO Zi

Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433, P.R. China

收稿日期:2023-05-26 出版日期:2023-12-01 发布日期:2023-11-18
通讯作者: YUE Yinghong E-mail:yhyue@fudan.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (No.22072027) and the Fund of the Science & Technology Commission of Shanghai Municipality, China(No.19DZ2270100).

Promoting Effect of ZnO on the Catalytic Performance of CoZSM-5 for CO₂-Assisted Dehydrogenation of Ethane

HE Huan, ZOU Zhengxi, HUA Weiming, YUE Yinghong, and GAO Zi

Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433, P.R. China

Received:2023-05-26 Online:2023-12-01 Published:2023-11-18
Contact: YUE Yinghong E-mail:yhyue@fudan.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (No.22072027) and the Fund of the Science & Technology Commission of Shanghai Municipality, China(No.19DZ2270100).

摘要/Abstract

摘要： Aseries of ZnO-modified cobaltous ion exchanged ZSM-5 catalysts is prepared using incipient wetness impregnation and characterized by X-ray diffraction (XRD), N₂ adsorption, transmission electron microscopy (TEM), UV-Vis diffuse reflectance spectroscopy (DR UV-Vis), X-ray photoelectron spectroscopy (XPS), pyridine-adsorbed Fourier transform infrared (Py-IR) and Raman. Their catalytic performance towards CO₂-assisted dehydrogenation of ethane to ethylene has been evaluated. The addition of ZnO onto CoZSM-5 obviously improved the yield of ethylene as well as the conversion of CO₂. The promoting effect is attributed to the good activity of ZnO for the reverse water gas shift (RWGS) reaction, which enhances the coupling between RWGS and ethane dehydrogenation.

关键词: Ethane dehydrogenation, CO₂ utilization, ZnO, CoZSM-5, Coupling

Abstract: Aseries of ZnO-modified cobaltous ion exchanged ZSM-5 catalysts is prepared using incipient wetness impregnation and characterized by X-ray diffraction (XRD), N₂ adsorption, transmission electron microscopy (TEM), UV-Vis diffuse reflectance spectroscopy (DR UV-Vis), X-ray photoelectron spectroscopy (XPS), pyridine-adsorbed Fourier transform infrared (Py-IR) and Raman. Their catalytic performance towards CO₂-assisted dehydrogenation of ethane to ethylene has been evaluated. The addition of ZnO onto CoZSM-5 obviously improved the yield of ethylene as well as the conversion of CO₂. The promoting effect is attributed to the good activity of ZnO for the reverse water gas shift (RWGS) reaction, which enhances the coupling between RWGS and ethane dehydrogenation.

Key words: Ethane dehydrogenation, CO₂ utilization, ZnO, CoZSM-5, Coupling

HE Huan, ZOU Zhengxi, HUA Weiming, YUE Yinghong, and GAO Zi. Promoting Effect of ZnO on the Catalytic Performance of CoZSM-5 for CO₂-Assisted Dehydrogenation of Ethane[J]. 高等学校化学研究, 2023, 39(6): 1064-1069.

HE Huan, ZOU Zhengxi, HUA Weiming, YUE Yinghong, and GAO Zi. Promoting Effect of ZnO on the Catalytic Performance of CoZSM-5 for CO₂-Assisted Dehydrogenation of Ethane[J]. Chemical Research in Chinese Universities, 2023, 39(6): 1064-1069.

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Promoting Effect of ZnO on the Catalytic Performance of CoZSM-5 for CO₂-Assisted Dehydrogenation of Ethane

Promoting Effect of ZnO on the Catalytic Performance of CoZSM-5 for CO₂-Assisted Dehydrogenation of Ethane

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