Improving PSCs' Short-circuit Current by Adding NaErF4: 0.5%Tm@NaLuF4 Up-conversion Nanoparticles Insertion Layer

doi:10.1007/s40242-023-3146-6

高等学校化学研究 ›› 2023, Vol. 39 ›› Issue (6): 1070-1076.doi: 10.1007/s40242-023-3146-6

Improving PSCs' Short-circuit Current by Adding NaErF₄: 0.5%Tm@NaLuF₄ Up-conversion Nanoparticles Insertion Layer

LIU Deye, LU Yang, LI Xu, LIU Fengmin, LIU Xiaomin, and LU Geyu

State Key Laboratory of Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130012, P.R. China

收稿日期:2023-06-29 出版日期:2023-12-01 发布日期:2023-11-18
通讯作者: LIU Fengmin E-mail:liufm@jlu.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (Nos.62271225, 61871198 and U2003127) and the Project on Industrial Innovation Capability of Jilin Province, China (No.2020C048).

Improving PSCs' Short-circuit Current by Adding NaErF₄: 0.5%Tm@NaLuF₄ Up-conversion Nanoparticles Insertion Layer

LIU Deye, LU Yang, LI Xu, LIU Fengmin, LIU Xiaomin, and LU Geyu

State Key Laboratory of Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130012, P.R. China

Received:2023-06-29 Online:2023-12-01 Published:2023-11-18
Contact: LIU Fengmin E-mail:liufm@jlu.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos.62271225, 61871198 and U2003127) and the Project on Industrial Innovation Capability of Jilin Province, China (No.2020C048).

摘要/Abstract

摘要： In this study, we synthesized a core-shell structure of up-conversion nanoparticles (UCNPs) and deposited it on the surface of fluorine-doped tin oxide (FTO). Subsequently, we assembled a series of perovskite solar cells with FTO/UCNPs/ c-TiO₂/mp-TiO₂/MAPbI₃/Spiro-OMeTAD/Au structures with an effective area of 0.04 cm². To optimize the devices, we adjusted the concentration of UCNPs precursor. The optimized device showed a power conversion efficiency (PCE) of 16.73% and a short-circuit current density (J_sc) of 26.94 mA/cm² at AM 1.5. These values are 9.20% and 10.47% higher than those of the best performing control device (15.32% for PCE and 24.12 mA/cm² for J_sc), respectively. Furthermore, we characterized the perovskite layer, charge transport layer, and perovskite solar cells using various analytical methods. The results showed that the addition of UCNPs not only improved the charge extraction and transfer, but also enhanced the stability of electron transport layer devices. In conclusion, our findings offer a process for optimizing perovskite cells using UCNPs and preliminarily analyzing their principles.

关键词: Solar cell, Perovskite, Up-conversion

Abstract: In this study, we synthesized a core-shell structure of up-conversion nanoparticles (UCNPs) and deposited it on the surface of fluorine-doped tin oxide (FTO). Subsequently, we assembled a series of perovskite solar cells with FTO/UCNPs/ c-TiO₂/mp-TiO₂/MAPbI₃/Spiro-OMeTAD/Au structures with an effective area of 0.04 cm². To optimize the devices, we adjusted the concentration of UCNPs precursor. The optimized device showed a power conversion efficiency (PCE) of 16.73% and a short-circuit current density (J_sc) of 26.94 mA/cm² at AM 1.5. These values are 9.20% and 10.47% higher than those of the best performing control device (15.32% for PCE and 24.12 mA/cm² for J_sc), respectively. Furthermore, we characterized the perovskite layer, charge transport layer, and perovskite solar cells using various analytical methods. The results showed that the addition of UCNPs not only improved the charge extraction and transfer, but also enhanced the stability of electron transport layer devices. In conclusion, our findings offer a process for optimizing perovskite cells using UCNPs and preliminarily analyzing their principles.

Key words: Solar cell, Perovskite, Up-conversion

LIU Deye, LU Yang, LI Xu, LIU Fengmin, LIU Xiaomin, and LU Geyu. Improving PSCs' Short-circuit Current by Adding NaErF₄: 0.5%Tm@NaLuF₄ Up-conversion Nanoparticles Insertion Layer[J]. 高等学校化学研究, 2023, 39(6): 1070-1076.

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参考文献

[1] Zhang Y., Liu Y., Liu S., Advanced Functional Materials, 2022, 33(9), 2210335
[2] Cheng M., Zuo C., Wu Y., Li Z., Xu B., Hua Y., Ding L., Science Bulletin, 2020, 65(15), 12371
[3] Deng K., Chen Q., Li L., Advanced Functional Materials, 2020, 30(46), 2004209
[4] Zhang Z., Qiao L., Meng K., Long R., Chen G., Gao P., Chemical Society Reviews, 2023, 52(1), 163
[5] Deng K., Li L., Small Methods, 2019, 4(6), 1900150
[6] Li B., Fu L., Li S., Li H., Pan L., Wang L., Chang B., Yin L., Journal of Materials Chemistry A, 2019, 7(36), 20494
[7] Murugadoss G., Thangamuthu R., Solar Energy, 2019, 179(2019), 151
[8] Zheng K., Liu C., Yu K., Meng Y., Yin X., Bu S., Lin S., Liu C., Ge Z., ACS Applied Materials Interfaces, 2023, 15(11), 14748
[9] Li Y., Han L., Liu H., Sun K., Luo D., Guo X., Yu D., Ren T., ACS Applied Electronic Materials, 2022, 4(2), 547
[10] Chen Z., Xue H., Brocks G., Bobbert P. A., Tao S., ACS Energy Letters, 2023, 8(2), 943
[11] Qiu L., Si G., Bao X., Liu J., Guan M., Wu Y., Qi X., Xing G., Dai Z., Bao Q., Li G., Chemical Society Reviews, 2023, 52(1), 212
[12] Suarez B., Gonzalez-Pedro V., Ripolles T. S., Sanchez R. S., Otero L., Mora-Sero I., The Journal of Physical Chemistry Letters, 2014, 5(10), 1628
[13] Wang M., Wang W., Ma B., Shen W., Liu L., Cao K., Chen S., Huang W., Nano-Micro Letters, 2021, 13(1), 62
[14] Xie F., Chen C., Wu Y., Li X., Cai M., Liu X., Yang X., Han L., Energy & Environmental Science, 2017, 10(9), 1942
[15] Liu X., Ding B., Han M., Yang Z., Chen J., Shi P., Xue X., Ghadari R., Zhang X., Wang R., Brooks K., Tao L., Kinge S., Dai S., Sheng J., Dyson P. J., Nazeeruddin M. K., Ding Y., Angewandte Chemie International Edition, 2023, 62(29), e202304350
[16] Zhou Y., Zhang X., Han M., Wu N., Chen J., Rahim G., Wu Y., Dai S., Liu X., Solar Energy Materials and Solar Cells, 2023, 257, 112375
[17] Tzoganakis N., Feng B., Loizos M., Chatzimanolis K., Krassas M., Tsikritzis D., Zhuang X., Kymakis E., Energy Technology, 2022, 11(2), 2201017
[18] Park S. Y., Zhu K., Advanced Materials, 2022, 34(27), 2110438
[19] Xiong L., Guo Y., Wen J., Liu H., Yang G., Qin P., Fang G., Advanced Functional Materials, 2018, 28(35), 1802757
[20] Wang S., Wang A., Deng X., Xie L., Xiao A., Li C., Xiang Y., Li T., Ding L., Hao F., Journal of Materials Chemistry A, 2020, 8(25), 12201
[21] Lu H., Li T., Ma S., Xue X., Wen Q., Feng Y., Zhang X., Zhang L., Wu Z., Wang K., Liu S. (Frank), Small Methods, 2022, 6(12), 2201117
[22] Ma Y., Zhang S., Yi Y., Zhang L., Hu R., Liu W., Du M., Chu L., Zhang J., Li X., Xia R., Huang W., Journal of Materials Chemistry C, 2022, 10(15), 5922
[23] Liu Z., Yang Z., Yang W., Sheng J., Zeng Y., Ye J., Solar Energy, 2022, 236, 100
[24] Tockhorn P., Sutter J., Cruz A., Wagner P., Jäger K., Yoo D., Lang F., Grischek M., Li B., Li J., Shargaieva O., Unger E., Al-Ashouri A., Köhnen E., Stolterfoht M., Neher D., Schlatmann R., Rech B., Stannowski B., Albrecht S., Becker C., Nature Nanotechnology, 2022, 17(11), 1214
[25] Lei Y., Mao L., Zhu H., Yao J., Journal of Applied Polymer Science, 2021, 138(42), 51251
[26] Jin J., Cao Q., Zhao L., Zhou Y., Li Z., Gui L., Chen Z., Wu C., Wang S., Chi B., Materials Today Communications, 2022, 33, 104513
[27] Hong Y.-K., Kim H., Lee G., Kim W., Park J.-I., Cheon J., Koo J.-Y., Applied Physics Letters, 2002, 80(5), 844
[28] Li X., Yang J., Jiang Q., Chu W., Zhang D., Zhou Z., Xin J., ACS Applied Materials & Interfaces, 2017, 9(47), 41354
[29] Ouedraogo N. A. N., Yan H., Han C. B., Zhang Y., Small, 2021, 17(8), 2004081
[30] Wang X., Rakstys K., Jack K., Jin H., Lai J., Li H., Ranasinghe C. S. K., Saghaei J., Zhang G., Burn P. L., Gentle I. R., Shaw P. E., Nature Communications, 2021, 12(1), 52
[31] Liu D., Liu K., Liu Y., Bai J., Dai M., Liu F., Lu G., Solar Energy, 2020, 212, 275
[32] Kakavelakis G., Petridis K., Kymakis E., J. Mater. Chem. A., 2017, 5(41), 21604
[33] Ma D., Shen Y., Su T., Zhao J., Rahman N. U., Xie Z., Shi F., Zheng S., Zhang Y., Chi Z., Materials Chemistry Frontiers, 2019, 3(10), 2058
[34] Bi W., Wu Y., Chen C., Zhou D., Song Z., Li D., Chen G., Dai Q., Zhu Y., Song H., ACS Applied Materials & Interfaces, 2020, 12(22), 24737
[35] Singh R., Madirov E., Busko D., Hossain I. M., Konyushkin V. A., Nakladov A. N., Kuznetsov S. V., Farooq A., Gharibzadeh S., Paetzold U. W., Richards B. S., Turshatov A., ACS Applied Materials & Interfaces, 2021, 13(46), 54874
[36] Yu B. H., Cheng Y., Li M., Tsang S.-W., So F., ACS Applied Materials & Interfaces, 2018, 10(18), 15920
[37] Chen C., Zheng S., Song H., Chemical Society Reviews, 2021, 50(12), 7250
[38] Abdulmalek N. M., Jawad H. A., Optik, 2023, 280, 170808
[39] Manzoor S., Yu Z. J., Ali A., Ali W., Bush K. A., Palmstrom A. F., Bent S. F., McGehee M. D., Holman Z. C., Solar Energy Materials and Solar Cells, 2017, 173, 59
[40] Kim M.-S., Kim B.-G., Kim J., ACS Applied Materials & Interfaces, 2009, 1(6), 1264
[41] Qi B., Wang J., Physical Chemistry Chemical Physics, 2013, 15(23), 8972
[42] Dash D. P., Roshan R., Mahata S., Mallik S., Mahato S. S., Sarkar S. K., Journal of Renewable and Sustainable Energy, 2015, 7(1), 013127
[43] Wu G., Cai M., Cao Y., Li Z., Zhang Z., Yang W., Chen X., Ren D., Mo Y., Yang M., Liu X., Dai S., Journal of Energy Chemistry, 2022, 65, 55
[44] Patil J. V., Mali S. S., Hong C. K., Materials Today Chemistry, 2022, 26, 101118
[45] Cheng Y., Wei Q., Ye Z., Zhang X., Ji P., Wang N., Zan L., Fu F., Liu S., Solar RRL, 2022, 6(9), 2200418
[46] Kim H. D., Ohkita H., Benten H., Ito S., Advanced Materials, 2015, 28(5), 917
[47] Park Y., Lee J.-S., ACS Applied Materials & Interfaces, 2022, 14(3), 4371

Improving PSCs' Short-circuit Current by Adding NaErF₄: 0.5%Tm@NaLuF₄ Up-conversion Nanoparticles Insertion Layer

Improving PSCs' Short-circuit Current by Adding NaErF₄: 0.5%Tm@NaLuF₄ Up-conversion Nanoparticles Insertion Layer

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