Nitrogen-doped Carbon Coated Na3V2(PO4)3 with Superior Sodium Storage Capability

doi:10.1007/s40242-020-9088-3

高等学校化学研究 ›› 2020, Vol. 36 ›› Issue (3): 459-466.doi: 10.1007/s40242-020-9088-3

Nitrogen-doped Carbon Coated Na₃V₂(PO₄)₃ with Superior Sodium Storage Capability

XU Laiqiang¹, LI Jiayang¹, LI Yitong¹, CAI Peng¹, LIU Cheng¹, ZOU Guoqiang¹, HOU Hongshuai¹, HUANG Lanping³, JI Xiaobo^1,2

1. College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China;
2. School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, P. R. China;
3. Science and Technology on High Strength Structural Materials Laboratory, Central South University, Changsha 410083, P. R. China

收稿日期:2019-12-04 修回日期:2020-01-07 出版日期:2020-06-01 发布日期:2020-01-10
通讯作者: HUANG Lanping, JI Xiaobo E-mail:christie@mail.csu.edu.cn;xji@csu.edu.cn
基金资助:
Supported by the National Key Research and Development Program of China(Nos.2017YFB0102000, 2018YFB0104200), the Central South University Postdoctoral Foundation, China(No.140050018), the National Natural Science Foundation of China (Nos.51904342, 51622406, and 21673298), the Young Elite Scientists Sponsorship Program by China Association for Science and Technology(CAST)(No.2017QNRC001), the Innovation Mover Program of Central South University, China(Nos.2018CX005, 2017CX004), and the Hunan Provincial Natural Science Foundation, China(No.2018JJ3633).

Nitrogen-doped Carbon Coated Na₃V₂(PO₄)₃ with Superior Sodium Storage Capability

XU Laiqiang¹, LI Jiayang¹, LI Yitong¹, CAI Peng¹, LIU Cheng¹, ZOU Guoqiang¹, HOU Hongshuai¹, HUANG Lanping³, JI Xiaobo^1,2

1. College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China;
2. School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, P. R. China;
3. Science and Technology on High Strength Structural Materials Laboratory, Central South University, Changsha 410083, P. R. China

Received:2019-12-04 Revised:2020-01-07 Online:2020-06-01 Published:2020-01-10
Contact: HUANG Lanping, JI Xiaobo E-mail:christie@mail.csu.edu.cn;xji@csu.edu.cn
Supported by:
Supported by the National Key Research and Development Program of China(Nos.2017YFB0102000, 2018YFB0104200), the Central South University Postdoctoral Foundation, China(No.140050018), the National Natural Science Foundation of China (Nos.51904342, 51622406, and 21673298), the Young Elite Scientists Sponsorship Program by China Association for Science and Technology(CAST)(No.2017QNRC001), the Innovation Mover Program of Central South University, China(Nos.2018CX005, 2017CX004), and the Hunan Provincial Natural Science Foundation, China(No.2018JJ3633).

摘要/Abstract

摘要： Cathodes with high cycling stability and rate capability are required for ambient temperature sodium ion batteries in renewable energy storage application. Na₃V₂(PO₄)₃ is an attractive cathode material with excellent electrochemical stability and fast ion diffusion coefficient within the 3D NASICON structure. Nevertheless, the practical application of Na₃V₂(PO₄)₃ is seriously hindered by its intrinsically poor electronic conductivity. Herein, solvent evaporation method is presented to obtain the nitrogen-doped carbon coated Na₃V₂(PO₄)₃ cathode material, delivering enhanced electrochemical performances. N-Doped carbon layer coating serves as a highly conducting pathway, and creates numerous extrinsic defects and active sites, which can facilitate the storage and diffusion of Na⁺. Moreover, the N-doped carbon layer can provide a stable framework to accommodate the agglomeration of the electrode upon electrode cycling. N-Doped carbon coated Na₃V₂(PO₄)₃(NC-NVP) exhibits excellent long cycling life and superior rate performances than bare Na₃V₂(PO₄)₃ without carbon coating. NC-NVP delivers a stable capacity of 95.9 mA·h/g after 500 cycles at 1 C rate, which corresponds to high capacity retention(94.6%) with respect to the initial capacity(101.4 mA·h/g). Over 91.3% of the initial capacity is retained after 500 cycles at 5 C, and the capacity can reach 85 mA·h/g at 30 C rate.

关键词: Cathode, Sodium ion battery, Na₃V₂(PO₄)₃, Nitrogen-doped carbon

Abstract: Cathodes with high cycling stability and rate capability are required for ambient temperature sodium ion batteries in renewable energy storage application. Na₃V₂(PO₄)₃ is an attractive cathode material with excellent electrochemical stability and fast ion diffusion coefficient within the 3D NASICON structure. Nevertheless, the practical application of Na₃V₂(PO₄)₃ is seriously hindered by its intrinsically poor electronic conductivity. Herein, solvent evaporation method is presented to obtain the nitrogen-doped carbon coated Na₃V₂(PO₄)₃ cathode material, delivering enhanced electrochemical performances. N-Doped carbon layer coating serves as a highly conducting pathway, and creates numerous extrinsic defects and active sites, which can facilitate the storage and diffusion of Na⁺. Moreover, the N-doped carbon layer can provide a stable framework to accommodate the agglomeration of the electrode upon electrode cycling. N-Doped carbon coated Na₃V₂(PO₄)₃(NC-NVP) exhibits excellent long cycling life and superior rate performances than bare Na₃V₂(PO₄)₃ without carbon coating. NC-NVP delivers a stable capacity of 95.9 mA·h/g after 500 cycles at 1 C rate, which corresponds to high capacity retention(94.6%) with respect to the initial capacity(101.4 mA·h/g). Over 91.3% of the initial capacity is retained after 500 cycles at 5 C, and the capacity can reach 85 mA·h/g at 30 C rate.

Key words: Cathode, Sodium ion battery, Na₃V₂(PO₄)₃, Nitrogen-doped carbon

XU Laiqiang, LI Jiayang, LI Yitong, CAI Peng, LIU Cheng, ZOU Guoqiang, HOU Hongshuai, HUANG Lanping, JI Xiaobo. Nitrogen-doped Carbon Coated Na₃V₂(PO₄)₃ with Superior Sodium Storage Capability[J]. 高等学校化学研究, 2020, 36(3): 459-466.

参考文献 54

[1]	Dunn B., Kamath H., Tarascon J. M., Science, 2011, 334, 928
[2]	Hou H. S., Shao L. D., Zhang Y., Zou G. Q., Chen J., Ji X., Adv. Sci., 2017, 4, 1600243
[3]	Li L., Wu Z. P., Sun H., Chen D. M., Gao J., Suresh S., Chow P., Singh C. V., Koratkar N., ACS Nano, 2015, 9, 11342
[4]	Cao D. P., Yin C. L., Shi D. R., Fu Z. W., Zhang J. C., Li C. L., Adv. Funct. Mater., 2017, 27, 1701130
[5]	Wu Z. P., Liu K. X., Lv C., Zhong S. W., Wang Q. H., Liu T., Liu X. B., Yin Y. H., Hu Y. Y., D. Wei, Liu Z. Y., Small, 2018, 14, 1800414
[6]	Zhu C. J., Chen J., Liu S. S., Cheng B. M., Xu Y., Zhang P. W., Zhang Q., Li Y. T., Zhong S. S., J. Mater. Sci., 2018, 53, 5242
[7]	Ge P., Hou H. S., Cao X. Y., Li S. J., Zhao G. G., Guo T. X., Wang C., Ji X. B., Adv. Sci., 2018, 5, 1800080
[8]	Suresh S., Wu Z. P., Bartolucci S. F., Basu S., Mukherjee R., Gupta T., Hundekar P., Shi Y., Lu T. M., Koratkar N., ACS Nano, 2017, 115051
[9]	Liu X. L., Li D., Mo Q. L., Guo X. Y., Yang X. X., Chen G. X., Zhong S. W., J. Alloys Compd., 2014, 609, 54
[10]	Huang B., Xu B.Y., Li Y.T., Zhou W. D., You Y., Zhong S.W., Wang C. A., Goodenough J. B., ACS Appl. Mater. Interfaces, 2016, 8, 14552
[11]	Cui Z. H., Li C. L., Yu P. F., Yang M. H., Guo X. X., Yin C. L., J. Mater. Chem. A, 2015, 3, 509
[12]	Xu J. T., Wang M., Wickramaratne N. P., Jaroniec M., Dou S. X., Dai L. M., Adv. Mater., 2015, 27, 2042
[13]	Zhang B., Dugas R., Rousse G., Rozier P., Abakumov A. M., Tarascon J. M., Nat. Commun., 2016, 7, 10308
[14]	Li Y. M., Xu S. Y., Wu X. Y., Yu J. Z., Wang Y. S., Hu Y. S., Li H., Chen L. Q., Huang X. J., J. Mater. Chem. A, 2015, 3, 71
[15]	Zhu Y. J., Wen Y., Fan X. L., Gao T., Han F. D., Luo C., Liou S. C., Wang C. S., ACS Nano, 2015, 9, 3254
[16]	Hou H. S., Banks C. E., Jing M. J., Zhang Y., Ji X. B., Adv. Mater., 2015, 27, 7861
[17]	Zou G. Q., Hou H. S., Foster C. W., Banks C. E., Guo T. X., Jiang Y. L., Zhang Y., Ji X. B., Adv. Sci., 2018, 5, 1800241
[18]	Wu T. J., Zhang C. Y., Zou G. Q., Hu J. G., Zhu L. M., Cao X. Y., Hou H. S., Ji X. B., Sci. China Mater., 2019, 62, 1127
[19]	Zhou H. P., CaoY. J., Ma Z. L., Li S. L., Nanotechnol., 2018, 29, 195201
[20]	Kim D. H., Lee E., Slater M., Lu W. Q., Rood S., Johnson C. S., Electrochem. Commun., 2012, 18, 66
[21]	Yu C. Y., Park J. S., Jung H. G., Chung K. Y., Aurbach D., Sun Y. K., Myung S. T., Energy Environ. Sci., 2015, 8, 2019
[22]	Yu H. J., Guo S. H., Zhu Y. B., Ishida M., Zhou H. S., Chem. Commun., 2014, 50, 457
[23]	Han M. H., Gonzalo E., Sharma N., López del Amo J. M., Armand M., Avdeev M., SaizGaritaonandia J. J., Rojo T., Chem. Mater., 2016, 28, 106
[24]	Zhao J., Zhao L.W., Lu X., Dimov N., Okada S., Nishida T., J. Electrochem. Soc., 2013, 160, 3077
[25]	Wang P. F., Xin H. S., Zuo T. T., Li Q. H., Yang X. N., Yin Y. X., Gao X. K., Yu X. Q., Guo Y. G., Angew. Chem., Int. Ed., 2018, 57, 8178
[26]	Li S., Dong Y. F., Xu L., Xu X., He L., Mai L. Q., Adv. Mater., 2014, 26, 3545
[27]	Chao D. L., Lai C. H., Liang P., Wei Q. L., Wang Y. S., Zhu C. R., Deng G., Doan-Nguyen V. V. T., Lin J., Mai L. Q., Fan H. J., Dunn B., Shen Z. X., Adv. Energy Mater., 2018, 8, 1800058
[28]	Zhang J. X., Fang Y. J., Xiao L. F., Qian J. F., Cao Y. L., Ai X. P., Yang H. X., ACS Appl. Mater. Interfaces, 2017, 9, 7177
[29]	Rui X. H., Sun W. P., Wu C., Yu Y., Yan Q. Y., Adv. Mater., 2015, 27, 6670
[30]	Fang Y. J., Xiao L. F., Ai X. P., Cao Y. L., Yang H. X., Adv. Mater., 2015, 27, 5895
[31]	Zhang J. X., Yuan T. C., Wan H. Y., Qian J. F., Ai X. P., Yang H. X., Cao Y. L., Sci. China Chem., 2017, 60, 1546
[32]	Tao S., Cui P. X., Huang W. F., Yu Z., Wang X. B., Wei S. H., Liu D. B., Song L., Chu W. S., Carbon, 2016, 96, 1028
[33]	Wang E. H., Chen M. Z., Liu X. H., Liu Y. M., Guo H. P., Wu Z. G., Xiang W., Zhong B. H., Guo X. D., Chou S. L., Dou S. X., Small Methods, 2019, 3, 1800169
[34]	Liu J., Tang K., Song K. P., van Aken P. A., Yu Y., Maier J., Nanoscale, 2014, 6, 5081
[35]	Jiang Y., Yang Z. Z., Li W. H., Zeng L. C., Pan F. S., Wang M., Wei X., Hu G. T., Gu L., Yu Y., Adv. Energy Mater., 2015, 5, 1402104
[36]	Jian Z. L., Zhao L., Pan H. L., Hu Y. S., Li H., Chen W., Chen L. Q., Electrochem. Commun., 2012, 14, 86
[37]	Zhang L. L., Ma D., Li T., Liu J., Ding X. K., Huang Y. H., Yang X. L., ACS Appl. Mater. Interfaces, 2018, 10, 36851
[38]	Shen W., Wang C., Xu Q. J., Liu H. M., Wang Y. G., Adv. Energy Mater., 2015, 5, 1400982
[39]	Shan T. T., Xin S., You Y., Cong H. P., Yu S. H., Manthiram A., Angew. Chem., Int. Ed., 2016, 55, 12783
[40]	Zhao L., Hu Y. S., Li H., Wang Z. X., Chen L. Q., Adv. Mater., 2011, 23, 1385
[41]	Ding Z. J., Zhao L., Suo L. M., Jiao Y., Meng S., Hu Y. S., Wang Z. X., Chen L. Q., Phys. Chem. Chem. Phys., 2011, 13, 15127
[42]	Liu J.,Tang K., Song K. P., van Aken P. A., Yu Y., Maier J., Nanoscale, 2014, 6, 5081
[43]	Gao R. T., Tan R., Han L., Zhao Y., Wang Z. J., Yang L.Y., Pan F., J. Mater. Chem. A, 2017, 5, 5273
[44]	Ling R., Cai S., Xie D. L., Li X., Wang M. J., Lin Y. S., Jiang S., Shen K., Xiong K.Z., Sun X. H., Chem. Eng. J., 2018, 353, 264
[45]	Li J. W., Cao X. X., Pan A. Q., Zhao Y. L., Yang H. L., Cao G. Z., Liang S. Q., Chem. Eng. J., 2018, 335, 301
[46]	Jian Z. L., Han W. Z., Lu X., Yang H. X., Hu Y. S., Zhou J., Zhou Z. B., Li J. Q., Chen W., Chen D. F., Chen L. Q., Adv. Energy Mater., 2013, 3, 156
[47]	Lei Z. D., Xu L. Q., Jiao Y. L., Du A. J., Zhang Y., Zhang H. J., Small, 2018, 14, 1704410
[48]	Shen W., Wang C., Xu Q. J., Liu H. M., Wang Y. G., Adv. Energy Mater., 2015, 5, 1400982
[49]	Brückner R., Tylkowski M., Hupa L., Brauer D. S., J. Mater. Chem. B, 2016, 4, 3121
[50]	Shen W., Li H., Wang C., Li Z. H., Xu Q. J., Liu H. M., Wang Y. G., J. Mater. Chem. A, 2015, 3, 15190
[51]	Wei T. Y., Yang G. Z., Wang C. X., Nano Energy, 2017, 39, 363
[52]	Zheng L. L., Xue Y., Hao S. E., Wang Z. B., Ceram. Int., 2018, 44, 9880
[53]	Liu H., Cao Q., Fu L. J., Li C., Wu Y. P., Electrochem. Commun., 2006, 8, 1553
[54]	Qiao Y. Q., Wang X. L., Xiang J. Y., Zhang D., Liu W. L., Tu J. P., Electrochim. Acta, 2011, 56, 2269

Nitrogen-doped Carbon Coated Na₃V₂(PO₄)₃ with Superior Sodium Storage Capability

Nitrogen-doped Carbon Coated Na₃V₂(PO₄)₃ with Superior Sodium Storage Capability

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