Enhanced Peroxymonosulfate Activation by NixCo1-xOOH for Efficient Catalytic Oxidation of Organic Pollutants

doi:10.1007/s40242-019-9025-5

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (3): 440-448.doi: 10.1007/s40242-019-9025-5

Enhanced Peroxymonosulfate Activation by Ni_xCo_1-xOOH for Efficient Catalytic Oxidation of Organic Pollutants

LYU Cong^1,2, LI Yicheng^1,2, FANG Chen³, FENG Wei^1,2, SUN Wentian^1,2, ZHANG Qihui^1,2

1. Key Laboratory of Groundwater Resources and Environment, Ministry of Education, Jilin University, Changchun 130021, P. R. China;
2. Jilin Provincial Key Laboratory of Water Resources and Environment, Jilin University, Changchun 130021, P. R. China;
3. Department of Civil and Environmental Engineering, Northeastern University, Boston, Massachusetts 02115, USA

收稿日期:2019-01-29 修回日期:2019-04-16 出版日期:2019-06-01 发布日期:2019-05-29
通讯作者: LYU Cong E-mail:lvcong@jlu.edu.cn
基金资助:
Supported by the Science and Technology Project of the Education Department of Jilin Province, China (No.JJKH20190125KJ) and the Natural Science Foundation of the Science and Technology Department of Jilin Province, China (No.20180101081JC).

Enhanced Peroxymonosulfate Activation by Ni_xCo_1-xOOH for Efficient Catalytic Oxidation of Organic Pollutants

LYU Cong^1,2, LI Yicheng^1,2, FANG Chen³, FENG Wei^1,2, SUN Wentian^1,2, ZHANG Qihui^1,2

1. Key Laboratory of Groundwater Resources and Environment, Ministry of Education, Jilin University, Changchun 130021, P. R. China;
2. Jilin Provincial Key Laboratory of Water Resources and Environment, Jilin University, Changchun 130021, P. R. China;
3. Department of Civil and Environmental Engineering, Northeastern University, Boston, Massachusetts 02115, USA

Received:2019-01-29 Revised:2019-04-16 Online:2019-06-01 Published:2019-05-29
Contact: LYU Cong E-mail:lvcong@jlu.edu.cn
Supported by:
Supported by the Science and Technology Project of the Education Department of Jilin Province, China (No.JJKH20190125KJ) and the Natural Science Foundation of the Science and Technology Department of Jilin Province, China (No.20180101081JC).

摘要/Abstract

摘要： Peroxymonosulfate(PMS) has received increasing attention as viable technology for recalcitrant organics removal from polluted waters. Although promising, alternative heterogeneous catalysts with stable structure, strong hydrophilicity, environmental friendliness and excellent catalytic performance are highly desirable to facilitate the wide industrialization of PMS. In this work, Ni doped CoOOH catalyst was employed as PMS activator. Ni dopant had a significant influence on the morphology, structure and catalytic performance of CoOOH. Ni_0.2Co_0.8OOH exhibited the best catalytic performance. Reaction rate of Ni_0.2Co_0.8OOH was 2, 4, and 4.4 times that of CoOOH, CoFe₂O₄ and Co₃O₄, respectively. Moreover, Ni_0.2Co_0.8OOH/PMS system had potential application to organic pollutants and displayed a great catalytic activity over a broader pH value(e.g., 4-10). More importantly, Ni doping accelerated the transformation of Co(Ⅲ) and Co(Ⅱ) and formed active species CoOH⁺ and NiOH⁺, which were responsible to the enhancement of PMS activation. ^·OH, SO₄^·-, O₂^·- and ¹O₂ were detected, indicating both non-radical and radical processes in the Ni_0.2Co_0.8OOH/PMS system. These findings provide a promising alternative to mixed-metal oxyhydroxides catalysts for PMS activation, demonstrating a great potential in environmental remediation and wastewater treatment.

关键词: Ni dopant, Sulfate radical, Superoxide radical, Singlet oxygen, Electron transfer

Abstract: Peroxymonosulfate(PMS) has received increasing attention as viable technology for recalcitrant organics removal from polluted waters. Although promising, alternative heterogeneous catalysts with stable structure, strong hydrophilicity, environmental friendliness and excellent catalytic performance are highly desirable to facilitate the wide industrialization of PMS. In this work, Ni doped CoOOH catalyst was employed as PMS activator. Ni dopant had a significant influence on the morphology, structure and catalytic performance of CoOOH. Ni_0.2Co_0.8OOH exhibited the best catalytic performance. Reaction rate of Ni_0.2Co_0.8OOH was 2, 4, and 4.4 times that of CoOOH, CoFe₂O₄ and Co₃O₄, respectively. Moreover, Ni_0.2Co_0.8OOH/PMS system had potential application to organic pollutants and displayed a great catalytic activity over a broader pH value(e.g., 4-10). More importantly, Ni doping accelerated the transformation of Co(Ⅲ) and Co(Ⅱ) and formed active species CoOH⁺ and NiOH⁺, which were responsible to the enhancement of PMS activation. ^·OH, SO₄^·-, O₂^·- and ¹O₂ were detected, indicating both non-radical and radical processes in the Ni_0.2Co_0.8OOH/PMS system. These findings provide a promising alternative to mixed-metal oxyhydroxides catalysts for PMS activation, demonstrating a great potential in environmental remediation and wastewater treatment.

Key words: Ni dopant, Sulfate radical, Superoxide radical, Singlet oxygen, Electron transfer

LYU Cong, LI Yicheng, FANG Chen, FENG Wei, SUN Wentian, ZHANG Qihui. Enhanced Peroxymonosulfate Activation by Ni_xCo_1-xOOH for Efficient Catalytic Oxidation of Organic Pollutants[J]. 高等学校化学研究, 2019, 35(3): 440-448.

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Enhanced Peroxymonosulfate Activation by Ni_xCo_1-xOOH for Efficient Catalytic Oxidation of Organic Pollutants

Enhanced Peroxymonosulfate Activation by Ni_xCo_1-xOOH for Efficient Catalytic Oxidation of Organic Pollutants

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