Enhancement of Bio-based para-Xylene Selectivity in Catalytic Fast Pyrolysis of Cellulose Using a Surface-modified Mg/P/HZSM-5 Catalyst

doi:10.1007/s40242-019-9024-6

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (3): 449-456.doi: 10.1007/s40242-019-9024-6

Enhancement of Bio-based para-Xylene Selectivity in Catalytic Fast Pyrolysis of Cellulose Using a Surface-modified Mg/P/HZSM-5 Catalyst

WANG Yulan, FAN Minghui, ZHU Lijuan, WANG Shengfei, HE Yuting, LI Quanxin

Department of Chemical Physics, CAS Key Laboratory of Urban Pollutant Conversion, Chinese Academy of Sciences, Anhui Key Laboratory of Biomass Clean Energy, University of Science & Technology of China, Hefei 230026, P. R. China

收稿日期:2019-01-29 修回日期:2019-03-22 出版日期:2019-06-01 发布日期:2019-04-26
通讯作者: LI Quanxin E-mail:liqx@ustc.edu.cn
基金资助:
Supported by the National Key Research and Development Program of China(No.2018YFB1501404).

Enhancement of Bio-based para-Xylene Selectivity in Catalytic Fast Pyrolysis of Cellulose Using a Surface-modified Mg/P/HZSM-5 Catalyst

WANG Yulan, FAN Minghui, ZHU Lijuan, WANG Shengfei, HE Yuting, LI Quanxin

Department of Chemical Physics, CAS Key Laboratory of Urban Pollutant Conversion, Chinese Academy of Sciences, Anhui Key Laboratory of Biomass Clean Energy, University of Science & Technology of China, Hefei 230026, P. R. China

Received:2019-01-29 Revised:2019-03-22 Online:2019-06-01 Published:2019-04-26
Contact: LI Quanxin E-mail:liqx@ustc.edu.cn
Supported by:
Supported by the National Key Research and Development Program of China(No.2018YFB1501404).

摘要/Abstract

摘要： With the growing consumption of oil, the production of p-xylene(PX) from renewable biomass has gained significant attention recently. This work demonstrated that cellulose, a main component in lignocellulosic biomass, was directly converted into PX over the Mg/P surface-modified zeolites. The catalysts modified by the incorporation of P₂O₅ and MgO into HZSM-5(HZ) promoted the isomerization of m-/o-xylenes to p-xylene. The PX selectivity was greatly enhanced using the modified zeolites due to the deactivation of external surface and the adjustment of pore entrance. In addition, the addition of methanol to cellulose was beneficial to increase the selectivity of xylenes due to the alkylation reactions and the Diels-Alder reactions between cellulose-derived furans and methanol-derived olefins. The highest PX yield of 10.7%(molar fraction) with a high PX selectivity in xylenes(97.1%) was obtained over the 10%Mg/5%P/HZ catalyst. The reaction pathway for the formation of p-xylene was addressed according to the study of the key reactions and the characterization of catalysts.

关键词: Cellulose, p-Xylene, Diels-Alder reaction, Isomerization, Alkylation

Abstract: With the growing consumption of oil, the production of p-xylene(PX) from renewable biomass has gained significant attention recently. This work demonstrated that cellulose, a main component in lignocellulosic biomass, was directly converted into PX over the Mg/P surface-modified zeolites. The catalysts modified by the incorporation of P₂O₅ and MgO into HZSM-5(HZ) promoted the isomerization of m-/o-xylenes to p-xylene. The PX selectivity was greatly enhanced using the modified zeolites due to the deactivation of external surface and the adjustment of pore entrance. In addition, the addition of methanol to cellulose was beneficial to increase the selectivity of xylenes due to the alkylation reactions and the Diels-Alder reactions between cellulose-derived furans and methanol-derived olefins. The highest PX yield of 10.7%(molar fraction) with a high PX selectivity in xylenes(97.1%) was obtained over the 10%Mg/5%P/HZ catalyst. The reaction pathway for the formation of p-xylene was addressed according to the study of the key reactions and the characterization of catalysts.

Key words: Cellulose, p-Xylene, Diels-Alder reaction, Isomerization, Alkylation

WANG Yulan, FAN Minghui, ZHU Lijuan, WANG Shengfei, HE Yuting, LI Quanxin. Enhancement of Bio-based para-Xylene Selectivity in Catalytic Fast Pyrolysis of Cellulose Using a Surface-modified Mg/P/HZSM-5 Catalyst[J]. 高等学校化学研究, 2019, 35(3): 449-456.

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Enhancement of Bio-based para-Xylene Selectivity in Catalytic Fast Pyrolysis of Cellulose Using a Surface-modified Mg/P/HZSM-5 Catalyst

Enhancement of Bio-based para-Xylene Selectivity in Catalytic Fast Pyrolysis of Cellulose Using a Surface-modified Mg/P/HZSM-5 Catalyst

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