Synthesis and Properties of Poly(butylene carbonate-co-spirocyclic carbonate)

doi:10.1007/s40242-019-8355-7

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (4): 729-734.doi: 10.1007/s40242-019-8355-7

Synthesis and Properties of Poly(butylene carbonate-co-spirocyclic carbonate)

ZHU Changliang^1,2, LIU Shaoying¹, WANG Qingyin¹, ZHANG Hua¹, WANG Gongying¹

1. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, P. R. China;
2. National Engineering Laboratory for VOCs Pollution Control Material & amp;Technology, University of Chinese Academy of Sciences, Beijing 101408, P. R. China

收稿日期:2018-11-12 修回日期:2019-04-08 出版日期:2019-08-01 发布日期:2019-08-01
通讯作者: WANG Gongying E-mail:gywang@cioc.ac.cn
基金资助:
Supported by the National Key R&D Program of China(No.2016YFB0301900).

Synthesis and Properties of Poly(butylene carbonate-co-spirocyclic carbonate)

ZHU Changliang^1,2, LIU Shaoying¹, WANG Qingyin¹, ZHANG Hua¹, WANG Gongying¹

1. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, P. R. China;
2. National Engineering Laboratory for VOCs Pollution Control Material & amp;Technology, University of Chinese Academy of Sciences, Beijing 101408, P. R. China

Received:2018-11-12 Revised:2019-04-08 Online:2019-08-01 Published:2019-08-01
Contact: WANG Gongying E-mail:gywang@cioc.ac.cn
Supported by:
Supported by the National Key R&D Program of China(No.2016YFB0301900).

摘要/Abstract

摘要： Poly(butylene carbonate)(PBC) has significantly promising applications as a degradable material in the field of polymers, while its poor thermal performance and low crystallization rate are its main defects. To overcome these shortcomings, a series of poly(butylene carbonate-co-spirocyclic carbonate)(PBSC) copolymers were synthesized from diphenyl carbonate, 1,4-butanediol and spiroglycol via two-step polycondensation reactions, using magnesium oxide as a catalyst. Differential scanning calorimetry(DSC) results indicated that the glass transition temperature(T_g) values of PBSC copolymers were enhanced from -19℃ to 56℃ with rising the spiroacetal moiety content. Thermogravimetric analysis(TGA) results showed that the resulting PBSCs have a higher thermal stability than that of poly(butylene carbonate). Wide angle X-ray diffraction(WXRD) patterns were characterized to investigate the crystallization behaviour of PBSCs. Tensile testing demonstrated that copolymerization of spiroacetal moieties into PBC chains imparted PBSC with favourable mechanical performance. Typically, PBSC30 had a tensile modulus of (1735±430) MPa, a tensile strength of (42±5) MPa and an elongation of 504%±36%.

关键词: Poly(butylene carbonate), Spiroglycol, Diphenyl carbonate, Thermal property

Abstract: Poly(butylene carbonate)(PBC) has significantly promising applications as a degradable material in the field of polymers, while its poor thermal performance and low crystallization rate are its main defects. To overcome these shortcomings, a series of poly(butylene carbonate-co-spirocyclic carbonate)(PBSC) copolymers were synthesized from diphenyl carbonate, 1,4-butanediol and spiroglycol via two-step polycondensation reactions, using magnesium oxide as a catalyst. Differential scanning calorimetry(DSC) results indicated that the glass transition temperature(T_g) values of PBSC copolymers were enhanced from -19℃ to 56℃ with rising the spiroacetal moiety content. Thermogravimetric analysis(TGA) results showed that the resulting PBSCs have a higher thermal stability than that of poly(butylene carbonate). Wide angle X-ray diffraction(WXRD) patterns were characterized to investigate the crystallization behaviour of PBSCs. Tensile testing demonstrated that copolymerization of spiroacetal moieties into PBC chains imparted PBSC with favourable mechanical performance. Typically, PBSC30 had a tensile modulus of (1735±430) MPa, a tensile strength of (42±5) MPa and an elongation of 504%±36%.

Key words: Poly(butylene carbonate), Spiroglycol, Diphenyl carbonate, Thermal property

ZHU Changliang, LIU Shaoying, WANG Qingyin, ZHANG Hua, WANG Gongying. Synthesis and Properties of Poly(butylene carbonate-co-spirocyclic carbonate)[J]. 高等学校化学研究, 2019, 35(4): 729-734.

ZHU Changliang, LIU Shaoying, WANG Qingyin, ZHANG Hua, WANG Gongying. Synthesis and Properties of Poly(butylene carbonate-co-spirocyclic carbonate)[J]. Chemical Research in Chinese Universities, 2019, 35(4): 729-734.

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Synthesis and Properties of Poly(butylene carbonate-co-spirocyclic carbonate)

Synthesis and Properties of Poly(butylene carbonate-co-spirocyclic carbonate)

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