Carboxyl-functionalized Nanocellulose Reinforced Nanocomposite Proton Exchange Membrane

doi:10.1007/s40242-019-8330-3

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (4): 735-741.doi: 10.1007/s40242-019-8330-3

• Articles • 上一篇

Carboxyl-functionalized Nanocellulose Reinforced Nanocomposite Proton Exchange Membrane

YANG Xue¹, WEI Yingcong², CHU Xuefeng³, ZHAO Qi¹, YAN Wenling¹, DONG Chenjun¹, LIU Baijun⁴, SUN Zhaoyan⁵, HU Wei¹, ZHANG Niaona¹

1. College of Chemical Engineering, Changchun University of Technology, Changchun 130012, P. R. China;
2. State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350002, P. R. China;
3. School of Electrical and Electronic Information Engineering, Jilin Jianzhu University, Changchun 130118, P. R. China;
4. College of Chemistry, Jilin University, Changchun 130012, P. R. China;
5. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China

收稿日期:2018-10-15 修回日期:2019-01-17 出版日期:2019-08-01 发布日期:2019-08-01
通讯作者: HU Wei, ZHANG Niaona E-mail:huwei@ccut.edu.cn;zhangniaona@ccut.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.21404013), the Science and Technology Development Plan of Jilin Province, China(Nos.20160101323JC, 20170101110JC, 20180201075GX), the Project of the Jilin Provincial Deve-lopment and Reform Commission, China(No.2018C041-1), the Open Research Fund of State Key Laboratory of Polymer Physics and Chemistry of Chinese Academy of Sciences, and the Open Project of National & Local United Engineering Lab for Power Battery(Northeast Normal University), China(No.130028822).

Carboxyl-functionalized Nanocellulose Reinforced Nanocomposite Proton Exchange Membrane

YANG Xue¹, WEI Yingcong², CHU Xuefeng³, ZHAO Qi¹, YAN Wenling¹, DONG Chenjun¹, LIU Baijun⁴, SUN Zhaoyan⁵, HU Wei¹, ZHANG Niaona¹

1. College of Chemical Engineering, Changchun University of Technology, Changchun 130012, P. R. China;
2. State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350002, P. R. China;
3. School of Electrical and Electronic Information Engineering, Jilin Jianzhu University, Changchun 130118, P. R. China;
4. College of Chemistry, Jilin University, Changchun 130012, P. R. China;
5. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China

Received:2018-10-15 Revised:2019-01-17 Online:2019-08-01 Published:2019-08-01
Contact: HU Wei, ZHANG Niaona E-mail:huwei@ccut.edu.cn;zhangniaona@ccut.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.21404013), the Science and Technology Development Plan of Jilin Province, China(Nos.20160101323JC, 20170101110JC, 20180201075GX), the Project of the Jilin Provincial Deve-lopment and Reform Commission, China(No.2018C041-1), the Open Research Fund of State Key Laboratory of Polymer Physics and Chemistry of Chinese Academy of Sciences, and the Open Project of National & Local United Engineering Lab for Power Battery(Northeast Normal University), China(No.130028822).

摘要/Abstract

摘要： Nanocellulose(NCC) was prepared through the acid hydrolysis of microcellulose(MCC) and was reacted with maleic anhydride to obtain carboxyl-functionized nanocellulose(MA-NCCs). The presence of-OH and-SO₃H on the surface of rod-like MA-NCC was confirmed by Fourier transform infrared spectrometry(FTIR). Sulfonated poly(aryl ether ether ketone ketone)(Ph-SPEEKK) was synthesized with bis(4-fluorophenyl-methanone) and 2-phenylhydroquinone as monomer. MA-NCC/Ph-SPEEKK nanocomposite membranes with different MA-NCCs content were prepared, and their properties were characterized. Compared with Ph-SPEEKK, MA-NCC/Ph-SPEEKK nanocomposite membrane showed better mechanical and thermal properties and higher proton conductivity. The proton conductivity of the composite membrane with 4%(mass fraction) MA-NCCs under 80℃ was 0.095 S/cm. And its tensile strength reached 30.3 MPa, which was 21.2% higher than that of Ph-SPEEKK pure polymer membrane.

关键词: Sulfonated poly(arylether ether ketone ketone), Carboxylation, Nanocellulose, Proton exchange membrane

Abstract: Nanocellulose(NCC) was prepared through the acid hydrolysis of microcellulose(MCC) and was reacted with maleic anhydride to obtain carboxyl-functionized nanocellulose(MA-NCCs). The presence of-OH and-SO₃H on the surface of rod-like MA-NCC was confirmed by Fourier transform infrared spectrometry(FTIR). Sulfonated poly(aryl ether ether ketone ketone)(Ph-SPEEKK) was synthesized with bis(4-fluorophenyl-methanone) and 2-phenylhydroquinone as monomer. MA-NCC/Ph-SPEEKK nanocomposite membranes with different MA-NCCs content were prepared, and their properties were characterized. Compared with Ph-SPEEKK, MA-NCC/Ph-SPEEKK nanocomposite membrane showed better mechanical and thermal properties and higher proton conductivity. The proton conductivity of the composite membrane with 4%(mass fraction) MA-NCCs under 80℃ was 0.095 S/cm. And its tensile strength reached 30.3 MPa, which was 21.2% higher than that of Ph-SPEEKK pure polymer membrane.

Key words: Sulfonated poly(arylether ether ketone ketone), Carboxylation, Nanocellulose, Proton exchange membrane

YANG Xue, WEI Yingcong, CHU Xuefeng, ZHAO Qi, YAN Wenling, DONG Chenjun, LIU Baijun, SUN Zhaoyan, HU Wei, ZHANG Niaona. Carboxyl-functionalized Nanocellulose Reinforced Nanocomposite Proton Exchange Membrane[J]. 高等学校化学研究, 2019, 35(4): 735-741.

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Carboxyl-functionalized Nanocellulose Reinforced Nanocomposite Proton Exchange Membrane

Carboxyl-functionalized Nanocellulose Reinforced Nanocomposite Proton Exchange Membrane

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