Amorphous Cu0 on Carbon Nanofiber as Recyclable Heterogeneous Catalyst for N-Arylation Reactions

doi:10.1007/s40242-019-8338-8

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (2): 256-260.doi: 10.1007/s40242-019-8338-8

Amorphous Cu⁰ on Carbon Nanofiber as Recyclable Heterogeneous Catalyst for N-Arylation Reactions

WANG Junzhong, LI Hengyu, ZHANG Dongdong, BAI Jie

Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051, P. R. China

收稿日期:2018-10-22 修回日期:2018-11-13 出版日期:2019-04-01 发布日期:2019-04-30
通讯作者: BAI Jie E-mail:baijie@imut.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.21766022).

Amorphous Cu⁰ on Carbon Nanofiber as Recyclable Heterogeneous Catalyst for N-Arylation Reactions

WANG Junzhong, LI Hengyu, ZHANG Dongdong, BAI Jie

Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051, P. R. China

Received:2018-10-22 Revised:2018-11-13 Online:2019-04-01 Published:2019-04-30
Contact: BAI Jie E-mail:baijie@imut.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.21766022).

摘要/Abstract

摘要： A novel heterogeneous catalyst, amorphous Cu⁰ on the carbon nanofibers was developed and characterized by means of several characterization techniques. The prepared Cu⁰ was investigated as a heterogeneous catalyst for N-arylation reaction. The results show it is an excellent catalyst with recyclability, high consistency and catalytic activity. After the catalyst was used for 5 cycles in the N-arylation reaction, amorphous Cu⁰ reunited into crystalline copper nanoparticles with different particle sizes and its good heterogeneity in the catalytic system was confirmed after the catalyst recovery.

关键词: Amorphous Cu, Carbon nanofiber, N-Arylation reaction

Abstract: A novel heterogeneous catalyst, amorphous Cu⁰ on the carbon nanofibers was developed and characterized by means of several characterization techniques. The prepared Cu⁰ was investigated as a heterogeneous catalyst for N-arylation reaction. The results show it is an excellent catalyst with recyclability, high consistency and catalytic activity. After the catalyst was used for 5 cycles in the N-arylation reaction, amorphous Cu⁰ reunited into crystalline copper nanoparticles with different particle sizes and its good heterogeneity in the catalytic system was confirmed after the catalyst recovery.

Key words: Amorphous Cu, Carbon nanofiber, N-Arylation reaction

WANG Junzhong, LI Hengyu, ZHANG Dongdong, BAI Jie. Amorphous Cu⁰ on Carbon Nanofiber as Recyclable Heterogeneous Catalyst for N-Arylation Reactions[J]. 高等学校化学研究, 2019, 35(2): 256-260.

WANG Junzhong, LI Hengyu, ZHANG Dongdong, BAI Jie. Amorphous Cu⁰ on Carbon Nanofiber as Recyclable Heterogeneous Catalyst for N-Arylation Reactions[J]. Chemical Research in Chinese Universities, 2019, 35(2): 256-260.

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Amorphous Cu⁰ on Carbon Nanofiber as Recyclable Heterogeneous Catalyst for N-Arylation Reactions

Amorphous Cu⁰ on Carbon Nanofiber as Recyclable Heterogeneous Catalyst for N-Arylation Reactions

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