Highly Porous Amidoximed Carbon Nanofibers Supported Palladium(0) Nanoparticle Catalyzed Heck Reaction

doi:10.1007/s40242-015-5093-3

高等学校化学研究 ›› 2015, Vol. 31 ›› Issue (6): 1072-1077.doi: 10.1007/s40242-015-5093-3

Highly Porous Amidoximed Carbon Nanofibers Supported Palladium(0) Nanoparticle Catalyzed Heck Reaction

MENG Qingrun, BAI Jie, GUO Shoujun, LI Chunping

Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051, P. R. China

收稿日期:2015-03-11 修回日期:2015-07-29 出版日期:2015-11-01 发布日期:2015-11-02
通讯作者: BAI Jie E-mail:baijie@imut.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.21266016).

Highly Porous Amidoximed Carbon Nanofibers Supported Palladium(0) Nanoparticle Catalyzed Heck Reaction

MENG Qingrun, BAI Jie, GUO Shoujun, LI Chunping

Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051, P. R. China

Received:2015-03-11 Revised:2015-07-29 Online:2015-11-01 Published:2015-11-02
Contact: BAI Jie E-mail:baijie@imut.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.21266016).

摘要/Abstract

摘要：

Highly porous amidoximed carbon nanofibers(AOCNFs), which were fabricated via a conventional electrospinning technique followed by chemically modification, impregnation-reduction and carbonization process, had been used for the immobilization of palladium nanoparticles(Pd NPs) catalyst. During the carbonization process, polystyrene(PS) was selectively decomposed from bicomponent fibers, generating porous fibers. Fourier transform infrared spectroscopy(FTIR) result revealed the functional groups on PAN-PS fibers(PAN=polyacrylonitrile), AOPAN-PS fibers and AOCNFs; scanning electron microscopy(SEM) was used to observe the morphology of all stages of nanofibers; transmission electron microscopy(TEM) result gave the structure of through-hole morphology clearly visible and the dispersion of Pd NPs on the surface of nanofibers; and X-ray photoelectron spectra(XPS) confirmed that Pd nanoparticles on the surface of AOCNFs was of the metallic state. Moreover, the as-prepared catalyst exhibited high catalytic activity and efficient recycle for Heck coupling reactions between iodobenzene and acrylates.

关键词: Pd nanoparticle, Carbon nanofiber, Heck reaction

Abstract:

Key words: Pd nanoparticle, Carbon nanofiber, Heck reaction

MENG Qingrun, BAI Jie, GUO Shoujun, LI Chunping. Highly Porous Amidoximed Carbon Nanofibers Supported Palladium(0) Nanoparticle Catalyzed Heck Reaction[J]. 高等学校化学研究, 2015, 31(6): 1072-1077.

MENG Qingrun, BAI Jie, GUO Shoujun, LI Chunping. Highly Porous Amidoximed Carbon Nanofibers Supported Palladium(0) Nanoparticle Catalyzed Heck Reaction[J]. Chemical Research in Chinese Universities, 2015, 31(6): 1072-1077.

参考文献

[1] Lara P., Philippot K., Chaudret B., Chem. Cat. Chem., 2013, 5(1), 28
[2] Yao T. J., Cui T. Y., Fang X., Chem. J. Chinese Universities, 2013, 34(10), 2421
[3] Cai B. T., Gu P., Zeng L. X., Chem. Res. Chinese Universities, 2014, 30(3), 472
[4] Guo L. P., Bai J., Li C. P., Liang H. O., Sun W. Y., Meng Q. R., Xu T., New J. Chem., 2013, 37(12), 4037
[5] Liu B. B., Zhang G. Z., He H., Chem. J. Chinese Universities, 2013, 34(8), 1936
[6] Bhattacharjee S., Bruening M. L., Langmuir, 2008, 24(6), 2916
[7] Torborg C., Beller M., Adv. Synth. Catal., 2009, 351(18) 3027
[8] Coudary B. M., Madhi S., Chowdari N. S., Kantam M. L., Sreedhar B., J. Am. Chem. Soc., 2002, 124(47),14127
[9] Vries de J. G., Can. J. Chem., 2001, 79(5), 1086
[10] Heck R. F., Acc. Chem. Res., 1979, 12(4), 146
[11] Kohler K., Wagner M., Djakovitch L., Catal. Today, 2001, 66(1), 105
[12] Liu J., Yue Z., Fong H., Small, 2009, 5(5), 536
[13] Inagaki M., Yang Y., Kang F., Adv. Mater., 2012, 24(19), 2547
[14] Cramariuc B., Cramariuc R., Scarlet R., Manea L. R., Lupu I. G., Cramariuc O., J. Electrostat., 2013, 71(3), 189
[15] Greiner A., Wendorff J. H., Angew Chem. Int. Ed., 2007, 46(30), 5670
[16] Ji L., Saquing C., Khan S. A., Zhang X. W., Nanotechnology, 2008, 19(8), 085605
[17] Gupta A., Saquing C., Afshari M., Tonelli A., Khan S. A., Kotek R., Macromolecules, 2009, 42(3), 709
[18] Lin J., Ding B., Yu J., Hsieh Y., Macromol. Mater. Eng., 2009, 294(10), 673
[19] Mehmet D., Benoit M., Nagendra A., Behnam P., J. Mater. Sci., 2012, 47(16), 5955
[20] Bognitzki M., Frese T., Steinhart M., Greiner A., Schaper A., Hellwig M., Wendorff J. H., Polym. Eng. Sci., 2001, 41(6), 982
[21] Peng M., Li D., Shen L., Chen Y., Zheng Q., Wang H., Langmuir, 2006, 22(22), 9368
[22] Rao L., Xu J., Zhan R. Y., J. Appl. Polym. Sci., 1994, 53(3), 325
[23] Aneta F. S., Maciej B., Stanislaw B., J. Mater. Sci., 2009, 44(17), 4721
[24] Deng S. B., Bai R. B., Chen J. P., Langmuir, 2003, 19(12), 5058
[25] Saeed K., Haider S., Oh T. J., Park S. Y., J. Membrane Sci., 2008, 322(2), 400
[26] Bilba N., Bilba D., Moroi G., J. Appl. Polym. Sci., 2004, 92(6), 3730
[27] Lutfor M. R., Silong S., Zin W. M., Ab Rahman M. Z., Ahmad Haron M. J., Eur. Polym. J., 2000, 36(10), 2105
[28] Zhang C. Q., Yang Q. B., Zhan N. Q., Sun L., Wang H. G., Song Y., Li Y. X., Colloid Surf. A: Physicochem. Eng. Asp., 2010, 362(59), 58
[29] Shao L. J., Ji W. X., Dong P. D., Zeng M. F., Qi C. Z., Zhang X. M., Appl. Catal. A: Gen., 2012, 413, 267
[30] Zhang B. B., Song J. L., Liu H. Z., Shi J. H., Ma J., Fan H. L., Wang W. T., Zhang P., Han B. X., Green Chem., 2014, 16(3), 1198
[31] Guo L. P., Bai J., Wang J. Z., Liang H. O., Li C. P., Sun W. Y., Meng Q. R., J. Mol. Catal. Chem., 2015, 400, 95

Highly Porous Amidoximed Carbon Nanofibers Supported Palladium(0) Nanoparticle Catalyzed Heck Reaction

Highly Porous Amidoximed Carbon Nanofibers Supported Palladium(0) Nanoparticle Catalyzed Heck Reaction

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