POMs as Active Center for Sensitively Electrochemical Detection of Bisphenol A and Acetaminophen

doi:10.1007/s40242-019-8370-8

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (4): 592-597.doi: 10.1007/s40242-019-8370-8

POMs as Active Center for Sensitively Electrochemical Detection of Bisphenol A and Acetaminophen

DONG Pengfei¹, LI Na¹, ZHAO Haiyan¹, CUI Min¹, ZHANG Cong¹, HAN Hongyan², REN Jujie¹

1. College of Science, Hebei University of Science and Technology, Shijiazhuang 050018, P. R. China;
2. Department of Construction Engineering, Hebei Colleage of Industry and Technology, Shijiazhuang 050018, P. R. China

收稿日期:2018-11-29 修回日期:2019-02-21 出版日期:2019-08-01 发布日期:2019-08-01
通讯作者: LI Na, REN Jujie E-mail:jujieren@163.com;751877132@qq.com
基金资助:
Supported by the National Natural Science Foundation of China(No.81872669), the Program for Science and Technology Research Project of Hebei University, China(Nos.ZC2016069, QN2019032, ZD2018037), the PhD Start-up Fund of Hebei University of Science and Technology, China(No.81/1181222), the Graduate Innovation Funding Projects of Hebei Province, Chi-na(No.CXZZSS2018088) and the Undergraduate Innovation and Entrepreneurship Training Program, China(No.2018065).

POMs as Active Center for Sensitively Electrochemical Detection of Bisphenol A and Acetaminophen

DONG Pengfei¹, LI Na¹, ZHAO Haiyan¹, CUI Min¹, ZHANG Cong¹, HAN Hongyan², REN Jujie¹

1. College of Science, Hebei University of Science and Technology, Shijiazhuang 050018, P. R. China;
2. Department of Construction Engineering, Hebei Colleage of Industry and Technology, Shijiazhuang 050018, P. R. China

Received:2018-11-29 Revised:2019-02-21 Online:2019-08-01 Published:2019-08-01
Contact: LI Na, REN Jujie E-mail:jujieren@163.com;751877132@qq.com
Supported by:
Supported by the National Natural Science Foundation of China(No.81872669), the Program for Science and Technology Research Project of Hebei University, China(Nos.ZC2016069, QN2019032, ZD2018037), the PhD Start-up Fund of Hebei University of Science and Technology, China(No.81/1181222), the Graduate Innovation Funding Projects of Hebei Province, Chi-na(No.CXZZSS2018088) and the Undergraduate Innovation and Entrepreneurship Training Program, China(No.2018065).

摘要/Abstract

摘要： A new type of electrochemical sensor based on multi-walled carbon nanotubes(MWCNTs), K₂H₄SiW₁₁CuO₃₉·6H₂O(SiW₁₁Cu) and gold nanoparticles(AuNPs) was prepared for the simultaneous detection of bisphenol A and acetaminophen. Differential pulse voltammetry(DPV), cyclic voltammetry(CV) and electrochemical impedance spectroscopy(EIS) were used for electrochemical characterization, and Fourier transform infrared spectroscopy(FTIR) was used to characterize the structure of polyoxometalates. Electrochemical experimental results show that the composite modified electrodes have good electrochemical activity as well as current response values of bisphenol A and acetaminophen when pH=7.0. At the same time, the modified electrode exhibits good stability and reproduction, and has good anti-interference ability to other substances. In practical application, the sensor obtained satisfactory results.

关键词: Polyoxometalate, Gold nanoparticles, Electrochemical sensor, Bisphenol A, Acetaminophen

Abstract: A new type of electrochemical sensor based on multi-walled carbon nanotubes(MWCNTs), K₂H₄SiW₁₁CuO₃₉·6H₂O(SiW₁₁Cu) and gold nanoparticles(AuNPs) was prepared for the simultaneous detection of bisphenol A and acetaminophen. Differential pulse voltammetry(DPV), cyclic voltammetry(CV) and electrochemical impedance spectroscopy(EIS) were used for electrochemical characterization, and Fourier transform infrared spectroscopy(FTIR) was used to characterize the structure of polyoxometalates. Electrochemical experimental results show that the composite modified electrodes have good electrochemical activity as well as current response values of bisphenol A and acetaminophen when pH=7.0. At the same time, the modified electrode exhibits good stability and reproduction, and has good anti-interference ability to other substances. In practical application, the sensor obtained satisfactory results.

Key words: Polyoxometalate, Gold nanoparticles, Electrochemical sensor, Bisphenol A, Acetaminophen

DONG Pengfei, LI Na, ZHAO Haiyan, CUI Min, ZHANG Cong, HAN Hongyan, REN Jujie. POMs as Active Center for Sensitively Electrochemical Detection of Bisphenol A and Acetaminophen[J]. 高等学校化学研究, 2019, 35(4): 592-597.

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POMs as Active Center for Sensitively Electrochemical Detection of Bisphenol A and Acetaminophen

POMs as Active Center for Sensitively Electrochemical Detection of Bisphenol A and Acetaminophen

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