Preparation of Au Nanoparticles Decorated Polyaniline Nanotube and Its Catalytic Oxidation to Ascorbic Acid

doi:10.1007/s40242-016-5460-8

高等学校化学研究 ›› 2016, Vol. 32 ›› Issue (4): 702-708.doi: 10.1007/s40242-016-5460-8

• Articles • 上一篇

Preparation of Au Nanoparticles Decorated Polyaniline Nanotube and Its Catalytic Oxidation to Ascorbic Acid

MA Xiaoyu¹, YANG Jianmao², CAI Wenshu¹, ZHU Guodong¹, LIU Jianyun¹

1. State Environmental Protection Engineering Center for Pollution Treatment and Control in Textile Industry, College of Environmental Science and Engineering, Donghua University, Shanghai 201620, P. R. China;
2. Research Center for Analysis & Measurement, Donghua University, Shanghai 201620, P. R. China

收稿日期:2015-11-26 修回日期:2016-01-18 出版日期:2016-08-01 发布日期:2016-05-10
通讯作者: LIU Jianyun E-mail:jianyun.liu@dhu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21105009, 21476047) and the Project of the State Key Laboratory of Electroanalytical Chemistry, China(No.SKLEAC201205).

Preparation of Au Nanoparticles Decorated Polyaniline Nanotube and Its Catalytic Oxidation to Ascorbic Acid

MA Xiaoyu¹, YANG Jianmao², CAI Wenshu¹, ZHU Guodong¹, LIU Jianyun¹

1. State Environmental Protection Engineering Center for Pollution Treatment and Control in Textile Industry, College of Environmental Science and Engineering, Donghua University, Shanghai 201620, P. R. China;
2. Research Center for Analysis & Measurement, Donghua University, Shanghai 201620, P. R. China

Received:2015-11-26 Revised:2016-01-18 Online:2016-08-01 Published:2016-05-10
Contact: LIU Jianyun E-mail:jianyun.liu@dhu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21105009, 21476047) and the Project of the State Key Laboratory of Electroanalytical Chemistry, China(No.SKLEAC201205).

摘要/Abstract

摘要：

With sulfonated electrospun polystyrene fiber as a template, uniform polyaniline(PANI) nanotubes were fabricated via polymerization of aniline followed by template removal. Au nanoparticles(Au_nano) were decorated on the PANI nanotube successfully via auto-reduction of HAuCl₄ on the PANI nanotube. The morphology of the nanotubes was characterized by means of scanning electron microscopy(SEM) and transmittance electron microscopy(TEM). By varying precursor concentration and incubation time, Au_nano-PANI with different size of Au_nano was obtained conveniently. Glassy carbon electrode modified with the Au_nano decorated PANI nanotubes (Au_nano-PANI/GCE) was prepared and used seccessfully for the catalytic oxidation of ascorbic acid(AA). The results of differential pulse voltammetry indicate that there is a good linear relationship between the peak currents and the concentrations of AA in the range of 5-3000 μmol/L, with the limit of detection of 1 μmol/L(S/N>3). There is no mutual interference between AA and dopamine. The electrode has been successfully applied in the detection of AA in vitamin C tablet sample.

关键词: Electrospinning, Polyaniline nanotube, Gold nanoparticle, Ascorbic acid

Abstract:

Key words: Electrospinning, Polyaniline nanotube, Gold nanoparticle, Ascorbic acid

MA Xiaoyu, YANG Jianmao, CAI Wenshu, ZHU Guodong, LIU Jianyun. Preparation of Au Nanoparticles Decorated Polyaniline Nanotube and Its Catalytic Oxidation to Ascorbic Acid[J]. 高等学校化学研究, 2016, 32(4): 702-708.

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Preparation of Au Nanoparticles Decorated Polyaniline Nanotube and Its Catalytic Oxidation to Ascorbic Acid

Preparation of Au Nanoparticles Decorated Polyaniline Nanotube and Its Catalytic Oxidation to Ascorbic Acid

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