Mechanical Properties and Network Structure of Hydrophobic Association Hydrogels Prepared from Octylphenol Polyoxyethylene(7) Acrylate and Sodium Dodecyl Sulfate

doi:10.1007/s40242-015-5122-2

高等学校化学研究 ›› 2015, Vol. 31 ›› Issue (4): 633-639.doi: 10.1007/s40242-015-5122-2

Mechanical Properties and Network Structure of Hydrophobic Association Hydrogels Prepared from Octylphenol Polyoxyethylene(7) Acrylate and Sodium Dodecyl Sulfate

LIANG Zi, GAO Tingting, XU Jianan, LI Zhiying, LIU Xiaoli, LIU Fengqi

College of Chemistry, Jilin University, Changchun 130012, P. R. China

收稿日期:2015-03-26 修回日期:2015-04-23 出版日期:2015-08-01 发布日期:2015-05-04
通讯作者: LIU Fengqi E-mail:liufengqi@jlu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.21174053).

Mechanical Properties and Network Structure of Hydrophobic Association Hydrogels Prepared from Octylphenol Polyoxyethylene(7) Acrylate and Sodium Dodecyl Sulfate

LIANG Zi, GAO Tingting, XU Jianan, LI Zhiying, LIU Xiaoli, LIU Fengqi

College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2015-03-26 Revised:2015-04-23 Online:2015-08-01 Published:2015-05-04
Contact: LIU Fengqi E-mail:liufengqi@jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.21174053).

摘要/Abstract

摘要：

Hydrophobic association hydrogels(HA-gels) with high mechanical strength were prepared by free radical micellar copolymerization in aqueous solutions of acrylamide(AM), anion surfactant sodium dodecyl sulfate(SDS) and a small amount of hydrophobic monomer octylphenol polyoxyethylene(7) acrylate(OP-7-AC). We found that the molar ratio of SDS to OP-7-AC has a great effect on the tensile strength and other mechanical property parameters. The best ratio point R' was determined. On the basis of Mooney theory and statistical theory, the critical tensile ratios and critical tensile strengths of the hydrogels were obtained, elastic parameters C₁and C₂were calculated via uniaxial tensile equation and structural parameters, such as the effective network chain density and the averaged molecular weight of the chain between cross-linking points of all the hydrogels were evaluated. The results indicate that the variation of mechanical property parameters depends on the number of effective cross-linking points and the match degree of long and short chains.

关键词: Hydrophobic association, Cross-linking point, Distribution of chain, Surfactant

Abstract:

Key words: Hydrophobic association, Cross-linking point, Distribution of chain, Surfactant

LIANG Zi, GAO Tingting, XU Jianan, LI Zhiying, LIU Xiaoli, LIU Fengqi. Mechanical Properties and Network Structure of Hydrophobic Association Hydrogels Prepared from Octylphenol Polyoxyethylene(7) Acrylate and Sodium Dodecyl Sulfate[J]. 高等学校化学研究, 2015, 31(4): 633-639.

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Mechanical Properties and Network Structure of Hydrophobic Association Hydrogels Prepared from Octylphenol Polyoxyethylene(7) Acrylate and Sodium Dodecyl Sulfate

Mechanical Properties and Network Structure of Hydrophobic Association Hydrogels Prepared from Octylphenol Polyoxyethylene(7) Acrylate and Sodium Dodecyl Sulfate

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