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高等学校化学研究 ›› 2015, Vol. 31 ›› Issue (4): 640-644.doi: 10.1007/s40242-015-5092-4

• Articles • 上一篇    下一篇

Synthesis and Characterization of Poly(ω-pentadecalactone) for Its Industrial-scale Production

CHANG Qing1, LI Li2, YANG Dalei1, ZHANG Mingyao1, TON-THAT Minh-Tan3, HU Wei1, LÜ Shuai1   

  1. 1. Chemical Engineering Institute, Changchun University of Technology, Changchun 130012, P. R. China;
    2. School of Life Science and Technology, Harbin Institute of Technology, Harbin 150080, P. R. China;
    3. National Research Council, 75 Bd de Mortagne, Boucherville, QC J4B 6Y4, Canada
  • 收稿日期:2015-03-11 修回日期:2015-04-17 出版日期:2015-08-01 发布日期:2015-05-04
  • 通讯作者: HU Wei E-mail:huwei@ccut.edu.cn
  • 基金资助:

    Supported by the National Natural Science Foundation of China(No.21404013), the Science and Technology Development Plan of Jilin Province, China(No.20140204039GX), the Changchun Science and Technology Plan Project, China(No.14KG105), the College Students' Innovation and Entrepreneurship Training Plan of Higher School in Jilin Province, China (No.201410190034) and the Research Project of Science and Technology of the Education Department of Jilin Province During the 12th Five-year Plan Period, China(No.2015-78).

Synthesis and Characterization of Poly(ω-pentadecalactone) for Its Industrial-scale Production

CHANG Qing1, LI Li2, YANG Dalei1, ZHANG Mingyao1, TON-THAT Minh-Tan3, HU Wei1, LÜ Shuai1   

  1. 1. Chemical Engineering Institute, Changchun University of Technology, Changchun 130012, P. R. China;
    2. School of Life Science and Technology, Harbin Institute of Technology, Harbin 150080, P. R. China;
    3. National Research Council, 75 Bd de Mortagne, Boucherville, QC J4B 6Y4, Canada
  • Received:2015-03-11 Revised:2015-04-17 Online:2015-08-01 Published:2015-05-04
  • Contact: HU Wei E-mail:huwei@ccut.edu.cn
  • Supported by:

    Supported by the National Natural Science Foundation of China(No.21404013), the Science and Technology Development Plan of Jilin Province, China(No.20140204039GX), the Changchun Science and Technology Plan Project, China(No.14KG105), the College Students' Innovation and Entrepreneurship Training Plan of Higher School in Jilin Province, China (No.201410190034) and the Research Project of Science and Technology of the Education Department of Jilin Province During the 12th Five-year Plan Period, China(No.2015-78).

摘要：

The synthesis of biomaterial poly(ω-pentadecalactone)(PPDL) with yttrium isopropoxide as initiator in bulk was explored for its industrial-scale production. The weight-average molecular weight(Mw) of PPDL could be controlled by the molar ratio of monomer to initiator(M/I), polymerization temperature(Tp) and period(tp). The syn- thesis conditions were optimized, and a high Mw of 9.2×104 of PPDL could be obtained by the reaction at an M/I molar ratio of 1000/1 and 100 ℃ for only 30 min, which presented tough properties with a tensile strength of about 20 MPa and an elongation at break of about 300%. This mechanical property was comparable to that of high density polyethylene(HDPE). The melting point was about 96 ℃, and 5% of mass loss temperature(T5%) was as high as 340 ℃. Thus, the PPDL with good mechanical properties and high thermal stability can be synthesized without solvent at low expenses.

关键词: Poly(ω-pentadecalactone), Polymerization, Characterization

Abstract:

The synthesis of biomaterial poly(ω-pentadecalactone)(PPDL) with yttrium isopropoxide as initiator in bulk was explored for its industrial-scale production. The weight-average molecular weight(Mw) of PPDL could be controlled by the molar ratio of monomer to initiator(M/I), polymerization temperature(Tp) and period(tp). The syn- thesis conditions were optimized, and a high Mw of 9.2×104 of PPDL could be obtained by the reaction at an M/I molar ratio of 1000/1 and 100 ℃ for only 30 min, which presented tough properties with a tensile strength of about 20 MPa and an elongation at break of about 300%. This mechanical property was comparable to that of high density polyethylene(HDPE). The melting point was about 96 ℃, and 5% of mass loss temperature(T5%) was as high as 340 ℃. Thus, the PPDL with good mechanical properties and high thermal stability can be synthesized without solvent at low expenses.

Key words: Poly(ω-pentadecalactone), Polymerization, Characterization