Electrochemical Study and Electrodeposition of Copper(I) in Ionic Liquid-reline

doi:10.1007/s40242-013-3013-y

高等学校化学研究 ›› 2013, Vol. 29 ›› Issue (5): 991-997.doi: 10.1007/s40242-013-3013-y

Electrochemical Study and Electrodeposition of Copper(I) in Ionic Liquid-reline

POPESCU Ana-Maria¹, COJOCARU Anca², DONATH Cristina¹, CONSTANTIN Virgil¹

1. Laboratory of Molten Salts, "Ilie Murgulescu" Institute of Physical Chemistry of Romanian Academy, Bucharest 060021, Romania;
2. Department of Applied Physical Chemistry and Electrochemistry, University Politehnica of Bucharest, Bucharest 010737, Romania

收稿日期:2013-01-08 修回日期:2013-03-05 出版日期:2013-10-01 发布日期:2013-09-17
通讯作者: CONSTANTIN Virgil E-mail:virgilconstantin@yahoo.com
基金资助:
Supported by the PNCDI-2 Romanian Partnership Programmes-grant Project(No.31066/2007-2010).

Electrochemical Study and Electrodeposition of Copper(I) in Ionic Liquid-reline

POPESCU Ana-Maria¹, COJOCARU Anca², DONATH Cristina¹, CONSTANTIN Virgil¹

1. Laboratory of Molten Salts, "Ilie Murgulescu" Institute of Physical Chemistry of Romanian Academy, Bucharest 060021, Romania;
2. Department of Applied Physical Chemistry and Electrochemistry, University Politehnica of Bucharest, Bucharest 010737, Romania

Received:2013-01-08 Revised:2013-03-05 Online:2013-10-01 Published:2013-09-17
Contact: CONSTANTIN Virgil E-mail:virgilconstantin@yahoo.com
Supported by:
Supported by the PNCDI-2 Romanian Partnership Programmes-grant Project(No.31066/2007-2010).

摘要/Abstract

摘要：

The authors made the electrochemical studies on the electrode processes during copper electrodeposition with ionic liquids-reline as an electrolytic medium. Reline is a commercial name for a eutectic mixture of choline chloride and urea(1:2, molar ratio). This new proposed method of copper deposition is an ecological one because the ionic liquids are recyclable, non-volatile and non-toxic. Cyclic voltammetry investigations were conducted at 343 and 353 K in choline chloride-urea(Reline) deep eutectic solvent with single salt CuCl(generally in 0.05—0.38 mol/L concentration range). Electrochemical impedance spectroscopy investigations were conducted in choline chloride-urea ionic liquid with CuCl(0.05 mol/L). We investigated both cathodic and anodic processes of Cu⁺ ions at different sweep rates in this new electrolytic system based on choline chloride. We have proposed by this an alternative to the classical copper electrodeposition. Coefficient of diffusion, D₀, for the system Reline-CuCl is presented and the value of D₀ is 1.22×10^-8 cm²/s.

关键词: Ionic liquid, Reline, Electrodeposition, Cu(I), Coefficient of diffusion

Abstract:

Key words: Ionic liquid, Reline, Electrodeposition, Cu(I), Coefficient of diffusion

POPESCU Ana-Maria, COJOCARU Anca, DONATH Cristina, CONSTANTIN Virgil. Electrochemical Study and Electrodeposition of Copper(I) in Ionic Liquid-reline[J]. 高等学校化学研究, 2013, 29(5): 991-997.

POPESCU Ana-Maria, COJOCARU Anca, DONATH Cristina, CONSTANTIN Virgil. Electrochemical Study and Electrodeposition of Copper(I) in Ionic Liquid-reline[J]. Chemical Research in Chinese Universities, 2013, 29(5): 991-997.

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Electrochemical Study and Electrodeposition of Copper(I) in Ionic Liquid-reline

Electrochemical Study and Electrodeposition of Copper(I) in Ionic Liquid-reline

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