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高等学校化学研究 ›› 2011, Vol. 27 ›› Issue (1): 49-53.

• Articles • 上一篇    下一篇

Synthesis of Spiro Dihydrofurans and 1,8-Dioxo-xanthenes via DABCO Catalyzed Tandem Reaction of Aldehyde with Cyclohexane-1,3-dione and Dimedone

CHEN Jiao, SHI Jian and YAN Chao-guo*   

  1. College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. China
  • 收稿日期:2010-05-10 修回日期:2010-08-16 出版日期:2011-01-25 发布日期:2011-01-04
  • 通讯作者: YAN Chao-guo E-mail:cgyan@yzu.edu.cn
  • 基金资助:

    Supported by the National Natural Science Foundation of China(No.20972132).

Synthesis of Spiro Dihydrofurans and 1,8-Dioxo-xanthenes via DABCO Catalyzed Tandem Reaction of Aldehyde with Cyclohexane-1,3-dione and Dimedone

CHEN Jiao, SHI Jian and YAN Chao-guo*   

  1. College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. China
  • Received:2010-05-10 Revised:2010-08-16 Online:2011-01-25 Published:2011-01-04
  • Contact: YAN Chao-guo E-mail:cgyan@yzu.edu.cn
  • Supported by:

    Supported by the National Natural Science Foundation of China(No.20972132).

PDF (PC)

摘要： The 1,4-diazabicyclo[2.2.2]octane(DABCO) catalyzed reaction of cyclohexane-1,3-dione or dimedone with various aldehydes in acetonitrile resulted in the polysubstituted tetraketones, spiro dihydrofurans or 1,8-dioxo-xanthenes derivatives as main products respectively according to the structure of reactants and reaction conditions.

关键词: Tandem reaction, Dimedone, Spiro dihydrofuran, Tetraketone, 1,8-Dioxo-xanthene

Abstract: The 1,4-diazabicyclo[2.2.2]octane(DABCO) catalyzed reaction of cyclohexane-1,3-dione or dimedone with various aldehydes in acetonitrile resulted in the polysubstituted tetraketones, spiro dihydrofurans or 1,8-dioxo-xanthenes derivatives as main products respectively according to the structure of reactants and reaction conditions.

Key words: Tandem reaction, Dimedone, Spiro dihydrofuran, Tetraketone, 1,8-Dioxo-xanthene