Highly Sensitive Ethanol Gas Sensor Based on Ag Nanoparticles Decorated In2O3

doi:10.1007/s40242-024-3244-0

高等学校化学研究 ›› 2024, Vol. 40 ›› Issue (6): 1033-1040.doi: 10.1007/s40242-024-3244-0

Highly Sensitive Ethanol Gas Sensor Based on Ag Nanoparticles Decorated In₂O₃

ZHANG Susu, ZHANG Meng, GUO Ying

State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China

收稿日期:2023-11-01 出版日期:2024-12-01 发布日期:2024-10-26
通讯作者: GUO Ying,guoying@mail.buct.edu.cn E-mail:guoying@mail.buct.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (Nos. 52072022, 21627813, 51472021).

Highly Sensitive Ethanol Gas Sensor Based on Ag Nanoparticles Decorated In₂O₃

ZHANG Susu, ZHANG Meng, GUO Ying

State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China

Received:2023-11-01 Online:2024-12-01 Published:2024-10-26
Contact: GUO Ying,guoying@mail.buct.edu.cn E-mail:guoying@mail.buct.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos. 52072022, 21627813, 51472021).

摘要/Abstract

摘要： Ag nanoparticle decorated In₂O₃ composites for high sensitivity and high selectivity detection of ethanol were prepared by hydrothermal and annealing methods. The effects of Ag content on the sensing properties of Ag decorated In₂O₃ sensors were also investigated. It was found that all Ag decorated In₂O₃ sensors exhibited better sensing performance in terms of sensitivity and selectivity compared to pure In₂O₃ sensors. By optimizing the addition amount of Ag, the 7%-Ag/In₂O₃ sensor showed the highest response to ethanol (35.6 vs. 100 ppm, ppm=parts per million), which was about seven times higher than that of the pure In₂O₃ sensor at 270 ℃. The improved performance of the Ag-In₂O₃ composite sensor can be attributed to the catalytic effect of silver and the Schottky barrier formed at the Ag-In₂O₃ interface.

关键词: Ag, In₂O₃, Schottky barrier, Ethanol, Sensor

Abstract: Ag nanoparticle decorated In₂O₃ composites for high sensitivity and high selectivity detection of ethanol were prepared by hydrothermal and annealing methods. The effects of Ag content on the sensing properties of Ag decorated In₂O₃ sensors were also investigated. It was found that all Ag decorated In₂O₃ sensors exhibited better sensing performance in terms of sensitivity and selectivity compared to pure In₂O₃ sensors. By optimizing the addition amount of Ag, the 7%-Ag/In₂O₃ sensor showed the highest response to ethanol (35.6 vs. 100 ppm, ppm=parts per million), which was about seven times higher than that of the pure In₂O₃ sensor at 270 ℃. The improved performance of the Ag-In₂O₃ composite sensor can be attributed to the catalytic effect of silver and the Schottky barrier formed at the Ag-In₂O₃ interface.

Key words: Ag, In₂O₃, Schottky barrier, Ethanol, Sensor

ZHANG Susu, ZHANG Meng, GUO Ying. Highly Sensitive Ethanol Gas Sensor Based on Ag Nanoparticles Decorated In₂O₃[J]. 高等学校化学研究, 2024, 40(6): 1033-1040.

ZHANG Susu, ZHANG Meng, GUO Ying. Highly Sensitive Ethanol Gas Sensor Based on Ag Nanoparticles Decorated In₂O₃[J]. Chemical Research in Chinese Universities, 2024, 40(6): 1033-1040.

参考文献

[1] Song L., Dou K., Wang R., Leng P., Luo L., Yan X., Kaun C., Han N., Wang F., Chen Y., ACS Appl. Mater. Interfaces, 2020, 12, 1270.
[2] Ponzoni A., Comini E., Concina I., Ferroni M., Falasconi M., Gobbi E., Sberveglieri V., Sberveglieri G., Sensors, 2012, 12, 17023.
[3] Pinzi S., Lopez I., Leiva-Candia D. E., Redel-Macias M. D., Herreros J. M., Cubero-Atienza A., Dorado M. P., Appl. Energy, 2018, 224, 409.
[4] Nair S., Cope K., Terence R. H., A. M., Am. J. Gastroenterol., 2001, 96, 1200.
[5] Mirzaei A., Leonardi S. G., Neri G., Ceram. Int., 2016, 42, 15119.
[6] Zhang K., Qin S., Tang P., Feng Y., Li D., J. Hazard Mater., 2020, 391, 122191.
[7] Li Q., Chen D., Miao J., Lin S., Yu Z., Cui D., Yang Z., Chen X., Sens. Actuators, B, 2021, 326, 128952.
[8] Chen G., Ji S., Li H., Kang X., Chang S., Wang Y., Yu G., Lu J., Claverie J., Sang Y., Liu H., ACS Appl. Mater. Interfaces, 2015, 7, 24950.
[9] Umar A., Ibrahim A. A., Kumar R., Albargi H., Ahmed F., Sens. Actuators, B, 2020, 326, 128851.
[10] Chen K., Lu H., Li G., Zhang J., Tian Y., Gao Y., Guo Q., Lu H., Gao J., Sens. Actuators, B, 2020, 308, 127716.
[11] Li P., Fan H., Process, 2015, 29, 83.
[12] Zhang S., Song P., Yang Z., Wang Q., Physica E Low Dimens. Syst. Nanostruct., 2018, 97, 38.
[13] Liu Z., Huang J., Wang Q., Zhou J., Ye J., Li X., Geng Y., Liang Z., Du Y., Tian X., Sens. Actuators, B, 2020, 308,127650.
[14] Wang X., Gao M., Nanoscale, 2018, 10, 12045.
[15] Wang Y., Liu B., Xiao S., Wang X., Sun L., Li H., Xie W., Li Q., Zhang Q., Wang T., ACS Appl. Mater. Interfaces, 2016, 8, 9674.
[16] Tournier G., Pijolat C., Sens. Actuators, B, 1999, 61, 43.
[17] Wang Z., Hou C., De Q., Gu F., Han D., ACS Sens., 2018, 3, 468.
[18] Zhang X., Song D., Liu Q., Chen R., Liu J., Zhang H., Yu J., Liu P., J Wang., CrystEngComm, 2019, 21, 1876.
[19] Xu Y., Zheng W., Liu X., Zhang L., Zheng L., Yang C., Pinna N., Zhang J., Mater. Horiz., 2020, 7, 1519.
[20] Wang Q., Bai J., Hu Q., Hao J., Cheng X., Li J., Xie E., Wang Y., Pan X., Sens. Actuators, B, 2020, 308, 127668.
[21] Neri G., Bonavita A., Micali G., Rizzo G., Galvagno S., Niederberger M., Pinna N., Chem. Commun., 2005, 37, 6032.
[22] Niu X., Zhong H., Wang X., Jiang K., Sens. Actuators, B, 2006, 115, 434.
[23] Liu L., Zhang T., Li S., Wang L., Tian Y., Mater. Lett., 2009, 63, 1975.
[24] Shen S., Cui X., Guo C., Dong X., Xu Y., Rare Metals, 2021, 40, 1554.
[25] Xu W., Zhang Z., Liu C., Ga J., Ye Z., Chen C., Peng Y., Bai X., Miao L., J. Adv. Ceram., 2021, 10, 860.
[26] Agarwal S., Kumar S., Agrawal H., Moinuddin M. G., Kumar M., Sharma S. K., Awasthi K., Sens. Actuators, B, 2021, 346, 130510.
[27] Zhang C., Huan Y., Li Y., Luo Y., Debliquy M., J. Adv. Ceram., 2022, 11, 379.
[28] Zhang C., Wu Q., Zheng B., You J., Luo Y., Ceram. Int., 2018, 44, 20700.
[29] Jun L., Chen Q., Fu W., Yang Y., Zhu W., Zhang J., ACS Appl. Mater. Interfaces, 2020, 12, 38425.
[30] Zhou S., Chen M., Lu Q., Zhang Y., Zhang J., Li B., Wei H., Hu J., Wang H., Liu Q., Nanoscale Res. Lett., 2019, 14, 365.
[31] Wang S., Huang D., Xu S., Jiang W., Wang T., Hu J., Hu N., Su Y., Zhang Y., Yang Z., Phys. Chem. Chem. Phys., 2017, 19, 19043.
[32] Kayaci F., Vempati S., Donmez I., Biyikli N., Uyar T., Nanoscale, 2014, 6, 10224.
[33] Li X., Liu J., Guo H., Zhou X., Wang C., Sun P., Hu X., Lu G., RSC Adv., 2015, 5, 545.
[34] Singh V. N., Mehta B. R., Joshi R. K., Kruis F. E., Shivaprasad S. M., Sens. Actuators, B, 2007, 125, 482.
[35] Wang B., Ji S., Ma Y., Vacuum, 2020, 177, 109428.
[36] Neri G., Bonavita A., Micali G., Rizzo G., Pinna N., Niederberger M., Sens. Actuators, B, 2007, 127, 455.
[37] Ding M., Xie N., Wang C., Kou X., Zhang H., Guo L., Sun Y., Chuai X., Gao Y., Liu F., Sun P., Lu G., Sens. Actuators, B, 2017, 252, 418.
[38] Zhou L., Bai J., Liu Y., Liu F., Wang H., Zhang Y., Lu G., Ceram. Int., 2020, 46, 15764.
[39] Tao Z., Li Y., Zhang B., Sun G., Cao J., Wang Y., Sens. Actuators, B, 2020, 321, 128623.
[40] Sadeghzadeh-Attar A., J. Adv. Ceram., 2020, 9, 107.
[41] Yuan K., Wang C., Zhu L., Cao Q., Yang J., Li X., Huang W., Wang Y., Lu H., Zhang D., ACS Appl. Mater. Interfaces, 2020, 12, 14095.
[42] Zhang L. X., Zhao J. H., Lu H. Q., Li L., Zheng J. F., Zhang J., Li H., Zhu Z. P., Sens. Actuators, B, 2012, 171/172, 1101.
[43] Song L. F., Dou K. P., Wang R. R., Leng P., Luo L. Q., Xi Y., Kaun C. C., Han N., Wang F. Y., Chen Y. F., ACS Appl. Mater. Interfaces, 2020, 12, 1270.
[44] Jiang B., Lu J., Han W., Sun Y., Wang Y., Cheng P., Zhang H., Wang C., Lu G., Sens. Actuators, B, 2022, 357, 131333.
[45] Xing R., Xu L., Song J., Zhou C., Li Q., Liu D., Song H., Sci. Rep., 2015, 5, 10717.
[46] Yang X., Fu H., Zhang L., An X., Xiong S., Jiang X., Yu A., Sens. Actuators, B, 2019, 286, 483.
[47] Liu X., Sun X., Duan X., Zhang C., Zhao K., Xu X., Sens. Actuators, B, 2020, 305, 127450.
[48] Nirala G., Yadav D., Upadhyay S., J. Adv. Ceram., 2020, 9, 129.

Highly Sensitive Ethanol Gas Sensor Based on Ag Nanoparticles Decorated In₂O₃

Highly Sensitive Ethanol Gas Sensor Based on Ag Nanoparticles Decorated In₂O₃

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	LIU Xiangyu, ZHANG Jinrui, XU Haijiao, SHAO Lina, WANG Hongda. Dark-vacuole Bodies Studying by High-resolution Label-free Microscopy Assisted with Fluorescence Technology[J]. 高等学校化学研究, 2024, 40(6): 978-986.
[2]	PAN Lijia, WANG Yuge, WEI Lai, SUN Zhaoyan. Understanding Fatigue Failure in Binary Rubber Blends: Role of Crack Initiation and Propagation[J]. 高等学校化学研究, 2024, 40(6): 987-993.
[3]	CHU Kailiang, WANG Yaquan, LIU Wenrong, BU Lingzhen, HUANG Yitong, GUO Niandong, QU Liping, SANG Juncai, LI Yaoning, SU Xuemei, ZHANG Xian. Organic-free, Ultrafast Synthesis of K-CHA Nano-aggregates with Various Morphologies and Their Adsorption Performances[J]. 高等学校化学研究, 2024, 40(6): 1151-1159.
[4]	ZHANG Junjie, LV Lunan, ZHU Haoran, ZHANG Ying, XU Xiaodi, LONG Lanxin, FU Wei. Molecular Mechanism of Action of GPR91 Agonists and Antagonists: Insights from Molecular Dynamics Simulation[J]. 高等学校化学研究, 2024, 40(6): 1201-1211.
[5]	CAO Heming, SHI Shunli, PENG Hesong, HU Jie, LIAO Sheng, WANG Shuhua, CHEN Chao. Achieving Enhanced Fire Safety of Polyvinyl Chloride Through Rapid Catalytic Carbonization Using a Triple-effect Flame Retardant of Mg(OH)₂-ZnO-TiO₂[J]. 高等学校化学研究, 2024, 40(6): 1233-1244.
[6]	TAJWAR Muhammad Ali, ALI Nasir, ZHANG Xiangru, JABEEN Rubina, LIU Yutong, SHANGGUAN Dihua, QI Li. Construction of Photo- and Thermo-Responsive Polymer-MOF@Enzyme Composites for Enhancing Its Biocatalytic Performance[J]. 高等学校化学研究, 2024, 40(6): 1290-1297.
[7]	QI Yi, FAN Hailong. Recent Progress on Water-based Liquid Embolic Agents in Endovascular Treatment[J]. 高等学校化学研究, 2024, 40(5): 776-785.
[8]	ZHANG Shixue, ZHOU Shengqi, WU Hao, GUO Xingwei. Advancements and Prospects in Continuous Wave Time-resolved Electron Paramagnetic Resonance[J]. 高等学校化学研究, 2024, 40(5): 798-805.
[9]	CHEN Yingqi, BUDIANTA Richard, NING Yingying. Near-infrared Emissive 1,2-Dioxetane-based Chemiluminescent Probes[J]. 高等学校化学研究, 2024, 40(5): 806-823.
[10]	GUO Xiaoqing, ZHANG Xinyuan, HU Shaojun, ZHOU Lipeng, SUN Qingfu. Stereo-control on Lanthanide Triple-stranded Helicates Toward Enhanced Enantioselective Sensing[J]. 高等学校化学研究, 2024, 40(5): 842-848.
[11]	LI Zhaoxian, MENG Xingyu, FANG Chuyao, YI Zhenkai, WU Yaoyao, LIU Xuanxuan, ZHONG Wei, ZHANG Limei, XIE Zhuang. Sandpaper-templated Stretchable Immunosensing Electrodes for Sub-picomolar Progesterone Detection[J]. 高等学校化学研究, 2024, 40(5): 874-880.
[12]	XIONG Jiayu, WU Minjian, YAO Liao-Yuan. Copper(I) Cluster of Aggregation-induced Emission and X-Ray Scintillator Characteristic[J]. 高等学校化学研究, 2024, 40(5): 887-893.
[13]	JIAO Ziyue, WANG Xinli, GAO Jie, HUANG Xiao, WANG Yi. Waterproof Perovskite Quantum Dots for In-vivo Photoluminescence Bioimaging[J]. 高等学校化学研究, 2024, 40(5): 901-906.
[14]	CAI Yuqing, CUI Qingyan, ZHANG Huanrong, MA Xinlei, XUE Mianqi. Promoted Non-enzymatic Glucose Sensor Based on Synergistic Effect of Hydrothermal Synthesized Ni(OH)₂-Graphene Nanocomposite[J]. 高等学校化学研究, 2024, 40(5): 914-921.
[15]	XU Chengxin, ZHANG Wenda, LOU Chenjie, LI Chengyu, XU Ligang, SHI Yongchao, LIU Jie, LUO Huajie, FU Jipeng, KUANG Xiaojun, TANG Mingxue. Low Temperature Tetragonal Tungsten Bronze Oxides for Li-ion Storage[J]. 高等学校化学研究, 2024, 40(5): 922-926.