Recent Advances of Stable Phenoxyl Diradicals

doi:10.1007/s40242-023-3012-6

高等学校化学研究 ›› 2023, Vol. 39 ›› Issue (2): 170-175.doi: 10.1007/s40242-023-3012-6

Recent Advances of Stable Phenoxyl Diradicals

ZHANG Hanjun¹, MIAO Fang², LIU Xiaodong¹, WANG Dongsheng¹, ZHENG Yonghao¹

1. School of Optoelectronic Science and Engineering, University of Electronic Science and Technology of China(UESTC), Chengdu 610054, P. R. China;
2. Institute of Electronic and Information Engineering of UESTC in Guangdong, Dongguan 523808, P. R. China

收稿日期:2023-01-13 出版日期:2023-04-01 发布日期:2023-03-16
通讯作者: ZHENG Yonghao E-mail:zhengyonghao@uestc.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China(No.52203134) and the Open Research Fund of State Key Laboratory of Southwestern Chinese Medicine Resources(Chengdu University of Traditional Chinese Medicine), China(No.SKLTCM2022014), and partially supported by Grant SCITLAB(No. 20012) of Intelligent Terminal Key Laboratory of Sichuan Province and Guangdong Basic, Intelligent Terminal Key Laboratory of Sichuan Province(No.SCITLAB-20013) and the Applied Basic Research Foundation (No.2021A1515110431).

Recent Advances of Stable Phenoxyl Diradicals

ZHANG Hanjun¹, MIAO Fang², LIU Xiaodong¹, WANG Dongsheng¹, ZHENG Yonghao¹

1. School of Optoelectronic Science and Engineering, University of Electronic Science and Technology of China(UESTC), Chengdu 610054, P. R. China;
2. Institute of Electronic and Information Engineering of UESTC in Guangdong, Dongguan 523808, P. R. China

Received:2023-01-13 Online:2023-04-01 Published:2023-03-16
Contact: ZHENG Yonghao E-mail:zhengyonghao@uestc.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China(No.52203134) and the Open Research Fund of State Key Laboratory of Southwestern Chinese Medicine Resources(Chengdu University of Traditional Chinese Medicine), China(No.SKLTCM2022014), and partially supported by Grant SCITLAB(No. 20012) of Intelligent Terminal Key Laboratory of Sichuan Province and Guangdong Basic, Intelligent Terminal Key Laboratory of Sichuan Province(No.SCITLAB-20013) and the Applied Basic Research Foundation (No.2021A1515110431).

摘要/Abstract

摘要： Organic radicals with unpaired electrons have shown great semiconducting properties with potential applications in the field of organic photodetectors, organic light-emitting diodes and organic spintronics. A major problem for limiting radicals from laboratory research to practical applications is the relatively low chemical and physical stabilities. Therefore, the right selection of radical core is the key to meaningful scientific research. Phenoxyl radical is one of the few stable radicals with spin distribution properties. Moreover, phenoxyl diradicals provide extract stability due to multiple resonance structures. Due to the long-distance spin distribution, which makes phenoxyl diradicals show interesting electronic and magnetic properties. In this review, we summarize the progress of phenoxyl diradicals in recent years in terms of syntheses, properties and future perspective.

关键词: Phenoxyl, Diradical, Conjugation, Stability

Abstract: Organic radicals with unpaired electrons have shown great semiconducting properties with potential applications in the field of organic photodetectors, organic light-emitting diodes and organic spintronics. A major problem for limiting radicals from laboratory research to practical applications is the relatively low chemical and physical stabilities. Therefore, the right selection of radical core is the key to meaningful scientific research. Phenoxyl radical is one of the few stable radicals with spin distribution properties. Moreover, phenoxyl diradicals provide extract stability due to multiple resonance structures. Due to the long-distance spin distribution, which makes phenoxyl diradicals show interesting electronic and magnetic properties. In this review, we summarize the progress of phenoxyl diradicals in recent years in terms of syntheses, properties and future perspective.

Key words: Phenoxyl, Diradical, Conjugation, Stability

ZHANG Hanjun, MIAO Fang, LIU Xiaodong, WANG Dongsheng, ZHENG Yonghao. Recent Advances of Stable Phenoxyl Diradicals[J]. 高等学校化学研究, 2023, 39(2): 170-175.

ZHANG Hanjun, MIAO Fang, LIU Xiaodong, WANG Dongsheng, ZHENG Yonghao. Recent Advances of Stable Phenoxyl Diradicals[J]. Chemical Research in Chinese Universities, 2023, 39(2): 170-175.

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Recent Advances of Stable Phenoxyl Diradicals

Recent Advances of Stable Phenoxyl Diradicals

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