Stabilization of Cu/Ni Alloy Nanoparticles with Graphdiyne Enabling Efficient CO2 Reduction

doi:10.1007/s40242-021-1344-7

高等学校化学研究 ›› 2021, Vol. 37 ›› Issue (6): 1328-1333.doi: 10.1007/s40242-021-1344-7

Stabilization of Cu/Ni Alloy Nanoparticles with Graphdiyne Enabling Efficient CO₂ Reduction

FU Xinliang¹, ZHU Aonan¹, CHEN Xiaojie¹, ZHANG Shifu², WANG Mei², YUAN Mingjian¹

1. Key Laboratory of Advanced Energy Materials Chemistry, Ministry of Education, Renewable Energy Conversion and Storage Center(RECAST), College of Chemistry, Nankai University, Tianjin 300071, P. R. China;
2. Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, P. R. China

收稿日期:2021-08-29 修回日期:2021-09-30 出版日期:2021-11-23 发布日期:2021-11-23
通讯作者: WANG Mei, YUAN Mingjian E-mail:meiwang@ouc.edu.cn;yuanmj@nankai.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (Nos.21771114, 91956130) and the Distinguished Young Scholars of Tianjin, China(No.19JCJQJC62000).

Stabilization of Cu/Ni Alloy Nanoparticles with Graphdiyne Enabling Efficient CO₂ Reduction

FU Xinliang¹, ZHU Aonan¹, CHEN Xiaojie¹, ZHANG Shifu², WANG Mei², YUAN Mingjian¹

1. Key Laboratory of Advanced Energy Materials Chemistry, Ministry of Education, Renewable Energy Conversion and Storage Center(RECAST), College of Chemistry, Nankai University, Tianjin 300071, P. R. China;
2. Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, P. R. China

Received:2021-08-29 Revised:2021-09-30 Online:2021-11-23 Published:2021-11-23
Contact: WANG Mei, YUAN Mingjian E-mail:meiwang@ouc.edu.cn;yuanmj@nankai.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos.21771114, 91956130) and the Distinguished Young Scholars of Tianjin, China(No.19JCJQJC62000).

摘要/Abstract

摘要： Electrocatalysis has become an attractive strategy for the artificial reduction of CO₂ to high-value chemicals. However, the design and development of highly selective and stable non-noble metal electrocatalysts that convert CO₂ to CO are still a challenge. As a new type of two-dimensional carbon material, graphdiyne(GDY), is rarely used to explore the application in carbon dioxide reduction reaction(CO₂RR). Therefore, we tried to use GDY as a substrate to stabilize the copper-nickel alloy nanoparticles(NPs) to synthesize Cu/Ni@GDY. Cu/Ni@GDY requires an overpotential (-0.61 V) to 10 mA/cm² for the formation of CO, and it shows better activity than Au and Ag, achieving a higher Faraday efficiency of about 95.2% and high stability of about 26 h at an overpotential (-0.70 V). The electronic interaction between GDY substrate and Cu/Ni alloy NPs and the large specific surface area of GDY is responsible for the high performance.

关键词: Graphdiyne(GDY), Carbon dioxide reduction reaction (CO₂RR), CO, Electrocatalysis, Cu/Ni alloy nanoparticle

Abstract: Electrocatalysis has become an attractive strategy for the artificial reduction of CO₂ to high-value chemicals. However, the design and development of highly selective and stable non-noble metal electrocatalysts that convert CO₂ to CO are still a challenge. As a new type of two-dimensional carbon material, graphdiyne(GDY), is rarely used to explore the application in carbon dioxide reduction reaction(CO₂RR). Therefore, we tried to use GDY as a substrate to stabilize the copper-nickel alloy nanoparticles(NPs) to synthesize Cu/Ni@GDY. Cu/Ni@GDY requires an overpotential (-0.61 V) to 10 mA/cm² for the formation of CO, and it shows better activity than Au and Ag, achieving a higher Faraday efficiency of about 95.2% and high stability of about 26 h at an overpotential (-0.70 V). The electronic interaction between GDY substrate and Cu/Ni alloy NPs and the large specific surface area of GDY is responsible for the high performance.

Key words: Graphdiyne(GDY), Carbon dioxide reduction reaction (CO₂RR), CO, Electrocatalysis, Cu/Ni alloy nanoparticle

FU Xinliang, ZHU Aonan, CHEN Xiaojie, ZHANG Shifu, WANG Mei, YUAN Mingjian. Stabilization of Cu/Ni Alloy Nanoparticles with Graphdiyne Enabling Efficient CO₂ Reduction[J]. 高等学校化学研究, 2021, 37(6): 1328-1333.

FU Xinliang, ZHU Aonan, CHEN Xiaojie, ZHANG Shifu, WANG Mei, YUAN Mingjian. Stabilization of Cu/Ni Alloy Nanoparticles with Graphdiyne Enabling Efficient CO₂ Reduction[J]. Chemical Research in Chinese Universities, 2021, 37(6): 1328-1333.

参考文献

[1] Ringe S., Morales-Guio C. G., Chen L. D., Fields M., Jaramillo T. F., Hahn C., Chan K., Nat. Commun., 2020, 11(1), 33
[2] Bhargava S. S., Proietto F., Azmoodeh D., Cofell E. R., Henckel D. A., Verma S., Brooks C. J., Gewirth A. A., Kenis P. J. A., Chem ElectroChem, 2020, 7 (9), 2001
[3] De Gregorio G. L., Burdyny T., Loiudice A., Iyengar P., Smith W. A., Buonsanti R., ACS Catal., 2020, 10(9), 4854
[4] Li H., Liu T., Wei P., Lin L., Gao D., Wang G., Bao X., Angew Chem. Int. Ed. Engl., 2021, 60(26), 14329
[5] Zhang B., Zhang J., Hua M., Wan Q., Su Z., Tan X., Liu L., Zhang F., Chen G., Tan D., Cheng X., Han B., Zheng L., Mo G., J. Am. Chem. Soc., 2020, 142(31), 13606
[6] Li F., Thevenon A., Rosas-Hernandez A., Wang Z., Li Y., Gabardo C. M., Ozden A., Dinh C. T., Li J., Wang Y., Edwards J. P., Xu Y., McCallum C., Tao L., Liang Z. Q., Luo M., Wang X., Li H., O'Brien C. P., Tan C. S., Nam D. H., Quintero-Bermudez R., Zhuang T. T., Li Y. C., Han Z., Britt R. D., Sinton D., Agapie T., Peters J. C., Sargent E. H., Nature, 2020, 577(7791), 509
[7] Huang J., Mensi M., Oveisi E., Mantella V., Buonsanti R., J. Am. Chem. Soc., 2019, 141(6), 2490
[8] Rong W., Zou H., Zang W., Xi S., Wei S., Long B., Hu J., Ji Y., Duan L., Angew. Chem. Int. Ed. Engl., 2021, 60(1), 466
[9] Wang Z. L., Sun K., Henzie J., Hao X., Li C., Takei T., Kang Y. M., Yamauchi Y., Angew. Chem. Int. Ed. Engl., 2018, 57(20), 5848
[10] Wang C., Guan E., Wang L., Chu X., Wu Z., Zhang J., Yang Z., Jiang Y., Zhang L., Meng X., Gates B. C., Xiao F. S., J. Am. Chem. Soc., 2019, 141(21), 8482
[11] Li X., Yu J., Jia J., Wang A., Zhao L., Xiong T., Liu H., Zhou W., Nano Energy, 2019, 62, 127
[12] Liu M., Liu M., Wang X., Kozlov S. M., Cao Z., de Luna P., Li H., Qiu X., Liu K., Hu J., Jia C., Wang P., Zhou H., He J., Zhong M., Lan X., Zhou Y., Wang Z., Li J., Seifitokaldani A., Dinh C. T., Liang H., Zou C., Zhang D., Yang Y., Chan T.-S., Han Y., Cavallo L., Sham T.-K., Hwang B.-J., Sargent E. H., Joule, 2019, 3(7), 1703
[13] Wang F., Zuo Z., Shang H., Zhao Y., Li Y., ACS Appl. Mater. Interfaces, 2019, 11(3), 2599
[14] Li J., Gao X., Zhu L., Ghazzal M. N., Zhang J., Tung C.-H., Wu L.-Z., Energy Environ. Sci., 2020, 13(5), 1326
[15] Hui L., Xue Y., Yu H., Liu Y., Fang Y., Xing C., Huang B., Li Y., J. Am. Chem. Soc., 2019, 141(27), 10677
[16] Li J., Gao X., Liu B., Feng Q., Li X. B., Huang M. Y., Liu Z., Zhang J., Tung C. H., Wu L. Z., J. Am. Chem. Soc., 2016, 138(12), 3954
[17] Qi H., Yu P., Wang Y., Han G., Liu H., Yi Y., Li Y., Mao L., J. Am. Chem. Soc., 2015, 137(16), 5260
[18] Fang Y., Xue Y., Hui L., Yu H., Liu Y., Xing C., Lu F., He F., Liu H., Li Y., Nano Energy, 2019, 59, 591
[19] Ma X., Qi K., Wei S., Zhang L., Cui X., J. Alloys Compd., 2019, 770, 236
[20] Zhang S., Liu H., Huang C., Cui G., Li Y., Chem. Commun. (Camb), 2015, 51(10), 1834
[21] Shi G., Xie Y., Du L., Fan Z., Chen X., Fu X., Xie W., Wang M., Yuan M., Nano Energy, 2020, 74, 104852
[22] Shi G., Fan Z., Du L., Fu X., Dong C., Xie W., Zhao D., Wang M., Yuan M., Mater. Chem. Front., 2019, 3(5), 821
[23] Zhu D. D., Liu J. L., Qiao S. Z., Adv. Mater., 2016, 28(18), 3423

Stabilization of Cu/Ni Alloy Nanoparticles with Graphdiyne Enabling Efficient CO₂ Reduction

Stabilization of Cu/Ni Alloy Nanoparticles with Graphdiyne Enabling Efficient CO₂ Reduction

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