Three-dimensional Pyrenyl Graphdiyne Supported Pd Nanoparticle as an Efficient and Easily Recyclable Catalyst for Reduction of 4-Nitrophenol

doi:10.1007/s40242-021-1323-z

高等学校化学研究 ›› 2021, Vol. 37 ›› Issue (6): 1296-1300.doi: 10.1007/s40242-021-1323-z

Three-dimensional Pyrenyl Graphdiyne Supported Pd Nanoparticle as an Efficient and Easily Recyclable Catalyst for Reduction of 4-Nitrophenol

RONG Xin, LU Xiuli, LU Tongbu

Institute for New Energy Materials & Low Carbon Technologies, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, P. R. China

收稿日期:2021-08-18 修回日期:2021-09-30 出版日期:2021-11-23 发布日期:2021-11-23
通讯作者: LU Xiuli, LU Tongbu E-mail:luxiuli@email.tjut.edu.cn;lutongbu@tjut.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (Nos.21790052, 21805207, and 21931007) and the “111” Project of China (No.D17003).

Three-dimensional Pyrenyl Graphdiyne Supported Pd Nanoparticle as an Efficient and Easily Recyclable Catalyst for Reduction of 4-Nitrophenol

RONG Xin, LU Xiuli, LU Tongbu

Institute for New Energy Materials & Low Carbon Technologies, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, P. R. China

Received:2021-08-18 Revised:2021-09-30 Online:2021-11-23 Published:2021-11-23
Contact: LU Xiuli, LU Tongbu E-mail:luxiuli@email.tjut.edu.cn;lutongbu@tjut.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos.21790052, 21805207, and 21931007) and the “111” Project of China (No.D17003).

摘要/Abstract

摘要： The fabrication of highly active and easily recyclable Pd-based catalyst is meaningful for their practical application. Herein, a Pd-based dip-catalyst(Pd@Pyr-GDY) is fabricated on graphdiyne(Pyr-GDY) grown on copper foam, and applied in the reduction of nitroarenes. Specially, the as-formed Pd@Pyr-GDY shows good catalytic performance toward the reduction of 4-nitrophenol(4-NP) to 4-aminophenol(4-AP) by NaBH₄ with a rate constant k value of 3.84 min^-1, which is 12-fold higher than that of the commercial Pd/C. More importantly, Pd@Pyr-GDY could be easily and rapidly recovery from the reaction medium and no distinct inactivation was found after six cycles of the reaction. This work presents an easy way to design an efficient and easily recyclable Pd-based catalyst for practical use.

关键词: Pd-based catalyst, Dip-catalyst, Reduction of 4-nitrophenol, Recycling

Abstract: The fabrication of highly active and easily recyclable Pd-based catalyst is meaningful for their practical application. Herein, a Pd-based dip-catalyst(Pd@Pyr-GDY) is fabricated on graphdiyne(Pyr-GDY) grown on copper foam, and applied in the reduction of nitroarenes. Specially, the as-formed Pd@Pyr-GDY shows good catalytic performance toward the reduction of 4-nitrophenol(4-NP) to 4-aminophenol(4-AP) by NaBH₄ with a rate constant k value of 3.84 min^-1, which is 12-fold higher than that of the commercial Pd/C. More importantly, Pd@Pyr-GDY could be easily and rapidly recovery from the reaction medium and no distinct inactivation was found after six cycles of the reaction. This work presents an easy way to design an efficient and easily recyclable Pd-based catalyst for practical use.

Key words: Pd-based catalyst, Dip-catalyst, Reduction of 4-nitrophenol, Recycling

RONG Xin, LU Xiuli, LU Tongbu. Three-dimensional Pyrenyl Graphdiyne Supported Pd Nanoparticle as an Efficient and Easily Recyclable Catalyst for Reduction of 4-Nitrophenol[J]. 高等学校化学研究, 2021, 37(6): 1296-1300.

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Three-dimensional Pyrenyl Graphdiyne Supported Pd Nanoparticle as an Efficient and Easily Recyclable Catalyst for Reduction of 4-Nitrophenol

Three-dimensional Pyrenyl Graphdiyne Supported Pd Nanoparticle as an Efficient and Easily Recyclable Catalyst for Reduction of 4-Nitrophenol

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