Li4Mn5O12Cathode for Both 3 V and 4 V Lithium-ion Batteries

doi:10.1007/s40242-021-1305-1

高等学校化学研究 ›› 2021, Vol. 37 ›› Issue (5): 1031-1043.doi: 10.1007/s40242-021-1305-1

Li₄Mn₅O₁₂Cathode for Both 3 V and 4 V Lithium-ion Batteries

ZHU Ruonan¹, WANG Jun², LI Jie¹

1. Department of Energy, Politecnico di Milano, Via Lambruschini 4, 20156, Milano, Italy;
2. Academy for Advanced Interdisciplinary Studies, Southern University of Science and Technology, Shenzhen 518055, P. R. China

收稿日期:2021-08-09 修回日期:2021-09-04 出版日期:2021-10-01 发布日期:2021-09-07
通讯作者: LI Jie E-mail:jie1.li@polimi.it
基金资助:
This work was supported by the European Union through the Horizon 2020 Framework Program for Research and Innovation within the Projects "SPIDER"(No 814389), the China Scholarship Council(CSC) and the Guangdong Natural Science Foundation for Basic and Applied Basic Research, China (No.2021A1515010138).

Li₄Mn₅O₁₂Cathode for Both 3 V and 4 V Lithium-ion Batteries

ZHU Ruonan¹, WANG Jun², LI Jie¹

1. Department of Energy, Politecnico di Milano, Via Lambruschini 4, 20156, Milano, Italy;
2. Academy for Advanced Interdisciplinary Studies, Southern University of Science and Technology, Shenzhen 518055, P. R. China

Received:2021-08-09 Revised:2021-09-04 Online:2021-10-01 Published:2021-09-07
Contact: LI Jie E-mail:jie1.li@polimi.it
Supported by:
This work was supported by the European Union through the Horizon 2020 Framework Program for Research and Innovation within the Projects "SPIDER"(No 814389), the China Scholarship Council(CSC) and the Guangdong Natural Science Foundation for Basic and Applied Basic Research, China (No.2021A1515010138).

摘要/Abstract

摘要： Spinel Li₄Mn₅O₁₂ has been of economical and academic interest as cathode material for 3 V lithium-ion batteries(LIBs) since the 1990s. Recent studies also demonstrate that the increase of upper cut-off voltage to 5.0 V can significantly promote the specific capacity and the average operating voltage thus enabling its possibility to be used in 4 V LIBs. It is cost-effective and environmentally benign, shows structural stability without suffering from Jahn-Teller distortion due to the tetravalent oxidation state of Mn ion. However, the undesirable decomposition reactions during high-temperature calcination result in the difficulty of fabricating stoichiometric Li₄Mn₅O₁₂ compounds. Meanwhile, the high capacity led by the enlarged voltage window is combined with fast capacity fading due to the poor reversibility of oxygen redox. In this review, the understanding of the relationship between structure and stochiometric chemistry of Li₄Mn₅O₁₂ is discussed and the ways to improving its electrochemical performance are summarized. Our focus is its recent developments of being used as high voltage cathode or "additive" for layered cathodes. At last, we also provide our perspectives on this material regarding to the target of enabling its application in 4 V LIBs.

关键词: Lithium-ion battery, Cathode material, Spinel Li₄Mn₅O₁₂, Stoichiometry, Oxygen redox

Abstract: Spinel Li₄Mn₅O₁₂ has been of economical and academic interest as cathode material for 3 V lithium-ion batteries(LIBs) since the 1990s. Recent studies also demonstrate that the increase of upper cut-off voltage to 5.0 V can significantly promote the specific capacity and the average operating voltage thus enabling its possibility to be used in 4 V LIBs. It is cost-effective and environmentally benign, shows structural stability without suffering from Jahn-Teller distortion due to the tetravalent oxidation state of Mn ion. However, the undesirable decomposition reactions during high-temperature calcination result in the difficulty of fabricating stoichiometric Li₄Mn₅O₁₂ compounds. Meanwhile, the high capacity led by the enlarged voltage window is combined with fast capacity fading due to the poor reversibility of oxygen redox. In this review, the understanding of the relationship between structure and stochiometric chemistry of Li₄Mn₅O₁₂ is discussed and the ways to improving its electrochemical performance are summarized. Our focus is its recent developments of being used as high voltage cathode or "additive" for layered cathodes. At last, we also provide our perspectives on this material regarding to the target of enabling its application in 4 V LIBs.

Key words: Lithium-ion battery, Cathode material, Spinel Li₄Mn₅O₁₂, Stoichiometry, Oxygen redox

ZHU Ruonan, WANG Jun, LI Jie. Li₄Mn₅O₁₂Cathode for Both 3 V and 4 V Lithium-ion Batteries[J]. 高等学校化学研究, 2021, 37(5): 1031-1043.

ZHU Ruonan, WANG Jun, LI Jie. Li₄Mn₅O₁₂Cathode for Both 3 V and 4 V Lithium-ion Batteries[J]. Chemical Research in Chinese Universities, 2021, 37(5): 1031-1043.

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Li₄Mn₅O₁₂Cathode for Both 3 V and 4 V Lithium-ion Batteries

Li₄Mn₅O₁₂Cathode for Both 3 V and 4 V Lithium-ion Batteries

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