AIE Ligand Constructed Zn(II) Complex with Reversible Photo-induced Color and Emission Changes

doi:10.1007/s40242-021-0331-3

高等学校化学研究 ›› 2021, Vol. 37 ›› Issue (1): 123-128.doi: 10.1007/s40242-021-0331-3

AIE Ligand Constructed Zn(II) Complex with Reversible Photo-induced Color and Emission Changes

QIN Yujing, PENG Qiuchen, CHEN Fang, LIU Yuanyuan, LI Kai, ZANG Shuangquan

Green Catalysis Center, College of Chemistry, Zhengzhou University, Zhengzhou 450001, P. R. China

收稿日期:2020-10-20 修回日期:2020-12-11 出版日期:2021-02-01 发布日期:2021-02-03
通讯作者: LI Kai, ZANG Shuangquan E-mail:likai@zzu.edu.cn;zangsqzg@zzu.edu.cn
基金资助:
This work was supported by the National Science Fund for Distinguished Young Scholars of China(No.21825106), the National Natural Science Foundation of China(Nos.21671175, U1904172), the Program for Science & Technology Innovation Talents in Universities of Henan Province, China(No.164100510005), the Program for Innovative Research Team(in Science and Technology) in Universities of Henan Province, China(No.19IRTSTHN022) and the Undergraduate Innovation and Entrepreneurship Training Program of Zhengzhou University, China (No.202010459003).

AIE Ligand Constructed Zn(II) Complex with Reversible Photo-induced Color and Emission Changes

QIN Yujing, PENG Qiuchen, CHEN Fang, LIU Yuanyuan, LI Kai, ZANG Shuangquan

Green Catalysis Center, College of Chemistry, Zhengzhou University, Zhengzhou 450001, P. R. China

Received:2020-10-20 Revised:2020-12-11 Online:2021-02-01 Published:2021-02-03
Contact: LI Kai, ZANG Shuangquan E-mail:likai@zzu.edu.cn;zangsqzg@zzu.edu.cn
Supported by:
This work was supported by the National Science Fund for Distinguished Young Scholars of China(No.21825106), the National Natural Science Foundation of China(Nos.21671175, U1904172), the Program for Science & Technology Innovation Talents in Universities of Henan Province, China(No.164100510005), the Program for Innovative Research Team(in Science and Technology) in Universities of Henan Province, China(No.19IRTSTHN022) and the Undergraduate Innovation and Entrepreneurship Training Program of Zhengzhou University, China (No.202010459003).

摘要/Abstract

摘要： Fluoran salicylaldehyde hydrazone metal complex(FSHMC) is a kind of recently reported photo-responsive system, which has the advantages of simple synthesis, multiple colors as well as distinct color change before and after UV light irradiation. However, the emission property of FSHMC is relatively unitary. In solid state, especially, only fluorescence quench is induced after UV light irradiation, which limits their applications. In this work, a typical aggregation-induced emission(AIE) moiety of tetraphenylethene(TPE) was introduced to the design of FSHMC. The obtained FSHMC, 2-Zn, exhibited reversible color and fluorescence changes upon UV light irradiation. Due to the AIE feature of compound 2, 2-Zn exhibited different emission changes upon UV light irradiation in THF and in solid matrix, because of the fluorescence resonance energy transfer(FRET) process from TPE moiety to rhodamine B moiety.

关键词: Aggregation-induced emission(AIE), Tetraphenylethene, Metal complex, Photochromism

Abstract: Fluoran salicylaldehyde hydrazone metal complex(FSHMC) is a kind of recently reported photo-responsive system, which has the advantages of simple synthesis, multiple colors as well as distinct color change before and after UV light irradiation. However, the emission property of FSHMC is relatively unitary. In solid state, especially, only fluorescence quench is induced after UV light irradiation, which limits their applications. In this work, a typical aggregation-induced emission(AIE) moiety of tetraphenylethene(TPE) was introduced to the design of FSHMC. The obtained FSHMC, 2-Zn, exhibited reversible color and fluorescence changes upon UV light irradiation. Due to the AIE feature of compound 2, 2-Zn exhibited different emission changes upon UV light irradiation in THF and in solid matrix, because of the fluorescence resonance energy transfer(FRET) process from TPE moiety to rhodamine B moiety.

Key words: Aggregation-induced emission(AIE), Tetraphenylethene, Metal complex, Photochromism

QIN Yujing, PENG Qiuchen, CHEN Fang, LIU Yuanyuan, LI Kai, ZANG Shuangquan. AIE Ligand Constructed Zn(II) Complex with Reversible Photo-induced Color and Emission Changes[J]. 高等学校化学研究, 2021, 37(1): 123-128.

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AIE Ligand Constructed Zn(II) Complex with Reversible Photo-induced Color and Emission Changes

AIE Ligand Constructed Zn(II) Complex with Reversible Photo-induced Color and Emission Changes

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