Molecular Motions in Polymer Matrix for Microenvironment Sensing

doi:10.1007/s40242-021-0404-3

高等学校化学研究 ›› 2021, Vol. 37 ›› Issue (1): 90-99.doi: 10.1007/s40242-021-0404-3

Molecular Motions in Polymer Matrix for Microenvironment Sensing

GAO Mengyue, CHENG Yanhua, ZHANG Junyan, XU Chengjian, YU Xiaoxiao, ZHU Meifang

State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, P. R. China

收稿日期:2020-12-01 修回日期:2021-01-04 出版日期:2021-02-01 发布日期:2021-02-03
通讯作者: CHENG Yanhua E-mail:cyh@dhu.edu.cn
基金资助:
This work is supported by the National Natural Science Foundation of China (No.51973030), the Shanghai Rising-Star Program, China(No.20QA1400100), and the Foundation of the Science and Technology Commission of Shanghai Municipality, China(No.20JC1414900).

Molecular Motions in Polymer Matrix for Microenvironment Sensing

GAO Mengyue, CHENG Yanhua, ZHANG Junyan, XU Chengjian, YU Xiaoxiao, ZHU Meifang

State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, P. R. China

Received:2020-12-01 Revised:2021-01-04 Online:2021-02-01 Published:2021-02-03
Contact: CHENG Yanhua E-mail:cyh@dhu.edu.cn
Supported by:
This work is supported by the National Natural Science Foundation of China (No.51973030), the Shanghai Rising-Star Program, China(No.20QA1400100), and the Foundation of the Science and Technology Commission of Shanghai Municipality, China(No.20JC1414900).

摘要/Abstract

摘要： Polymer science entails the structural study at multi-levels from nano-to micro- and mesoscale, which is highly important to transfer or even amplify the molecular information to macroscopic materials. Multiple polymer structural transitions from lower-order to higher-order superstructures are normally involved to achieve selective, efficient and sophisticated functions. Therefore, in-situ visualization of these processes is highly important, not only for fundamental understanding the structural evolution, but also for the optimization of the process flow during the materials processing. Fluorescence imaging based on aggregation-induced emission(AIE) provides an ideal tool that offers a simple, accurate, and easy-readable method to fulfill the above requirements. Owing to the twisted propeller-like structure of AIE luminogens(AIEgens), they show high fluorescence sensitivity to the surrounding microenvironment(e.g., viscosity, rigidity, and polarity) through intramolecular motions. In this short review, we summarize the recent applications of AIEgens to serve as "built-in" sensors to analyze the process of polymerization, microphase separation, glass/vitrification transition, polymer solvation, crystallization, etc. The perspective on the future application of AIE technology in polymer engineering, especially fiber materials, is also discussed.

关键词: Aggregation-induced emission(AIE), Intramolecular motion, Polymer structure, Polymer microenvironment, Visualization

Abstract: Polymer science entails the structural study at multi-levels from nano-to micro- and mesoscale, which is highly important to transfer or even amplify the molecular information to macroscopic materials. Multiple polymer structural transitions from lower-order to higher-order superstructures are normally involved to achieve selective, efficient and sophisticated functions. Therefore, in-situ visualization of these processes is highly important, not only for fundamental understanding the structural evolution, but also for the optimization of the process flow during the materials processing. Fluorescence imaging based on aggregation-induced emission(AIE) provides an ideal tool that offers a simple, accurate, and easy-readable method to fulfill the above requirements. Owing to the twisted propeller-like structure of AIE luminogens(AIEgens), they show high fluorescence sensitivity to the surrounding microenvironment(e.g., viscosity, rigidity, and polarity) through intramolecular motions. In this short review, we summarize the recent applications of AIEgens to serve as "built-in" sensors to analyze the process of polymerization, microphase separation, glass/vitrification transition, polymer solvation, crystallization, etc. The perspective on the future application of AIE technology in polymer engineering, especially fiber materials, is also discussed.

Key words: Aggregation-induced emission(AIE), Intramolecular motion, Polymer structure, Polymer microenvironment, Visualization

GAO Mengyue, CHENG Yanhua, ZHANG Junyan, XU Chengjian, YU Xiaoxiao, ZHU Meifang. Molecular Motions in Polymer Matrix for Microenvironment Sensing[J]. 高等学校化学研究, 2021, 37(1): 90-99.

GAO Mengyue, CHENG Yanhua, ZHANG Junyan, XU Chengjian, YU Xiaoxiao, ZHU Meifang. Molecular Motions in Polymer Matrix for Microenvironment Sensing[J]. Chemical Research in Chinese Universities, 2021, 37(1): 90-99.

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Molecular Motions in Polymer Matrix for Microenvironment Sensing

Molecular Motions in Polymer Matrix for Microenvironment Sensing

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