Ti-MOF Derived N-Doped TiO2 Nanostructure as Visible-light-driven Photocatalyst

doi:10.1007/s40242-020-0106-2

高等学校化学研究 ›› 2020, Vol. 36 ›› Issue (3): 447-452.doi: 10.1007/s40242-020-0106-2

Ti-MOF Derived N-Doped TiO₂ Nanostructure as Visible-light-driven Photocatalyst

HE Yilei¹, ZHANG Xing¹, WEI Yanze^1,2, CHEN Xiaoyu¹, WANG Zumin², YU Ranbo^1,3

1. Department of Physical Chemistry, School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, P. R. China;
2. State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, P. R. China;
3. Key Laboratory of Advanced Material Processing & Mold, Ministry of Education, Zhengzhou University, Zhengzhou 450002, P. R. China

收稿日期:2020-04-13 修回日期:2020-05-12 出版日期:2020-06-01 发布日期:2020-05-30
通讯作者: WANG Zumin, YU Ranbo E-mail:wangzm@ipe.ac.cn;ranboyu@ustb.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21671016, 51872024, 51932001), the National Key R&D Program of China(No.2018YFA0703503) and the China Postdoctoral Science Foundation(No.2019M650849).

Ti-MOF Derived N-Doped TiO₂ Nanostructure as Visible-light-driven Photocatalyst

HE Yilei¹, ZHANG Xing¹, WEI Yanze^1,2, CHEN Xiaoyu¹, WANG Zumin², YU Ranbo^1,3

1. Department of Physical Chemistry, School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, P. R. China;
2. State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, P. R. China;
3. Key Laboratory of Advanced Material Processing & Mold, Ministry of Education, Zhengzhou University, Zhengzhou 450002, P. R. China

Received:2020-04-13 Revised:2020-05-12 Online:2020-06-01 Published:2020-05-30
Contact: WANG Zumin, YU Ranbo E-mail:wangzm@ipe.ac.cn;ranboyu@ustb.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21671016, 51872024, 51932001), the National Key R&D Program of China(No.2018YFA0703503) and the China Postdoctoral Science Foundation(No.2019M650849).

摘要/Abstract

摘要： Nanostructured N-doped TiO₂ photocatalyst has been prepared via a new approach from Ti-based MOF[NH₂-MIL-125(Ti)] precursor. The success of N doping enhances light absorption and narrows the bandgap. Moreover, the as-prepared nanostructure is constructed with tiny nanoparticles and resembles a pie-like morphology inherited from the MOF, which accelerates electron transfer. Hence, as a photocatalyst for the degradation of methylene blue(MB) under visible light irradiation, the N-doped TiO₂(N-TiO₂) nanostructure shows higher photocatalytic activity with a reaction rate constant of 0.018 min^-1 than that of the TiO₂-P25 and TiO₂ under the visible light.

关键词: TiO₂, Metal-organic framework, Photo-degradation, N doped, Visible-light photocatalysis

Abstract: Nanostructured N-doped TiO₂ photocatalyst has been prepared via a new approach from Ti-based MOF[NH₂-MIL-125(Ti)] precursor. The success of N doping enhances light absorption and narrows the bandgap. Moreover, the as-prepared nanostructure is constructed with tiny nanoparticles and resembles a pie-like morphology inherited from the MOF, which accelerates electron transfer. Hence, as a photocatalyst for the degradation of methylene blue(MB) under visible light irradiation, the N-doped TiO₂(N-TiO₂) nanostructure shows higher photocatalytic activity with a reaction rate constant of 0.018 min^-1 than that of the TiO₂-P25 and TiO₂ under the visible light.

Key words: TiO₂, Metal-organic framework, Photo-degradation, N doped, Visible-light photocatalysis

HE Yilei, ZHANG Xing, WEI Yanze, CHEN Xiaoyu, WANG Zumin, YU Ranbo. Ti-MOF Derived N-Doped TiO₂ Nanostructure as Visible-light-driven Photocatalyst[J]. 高等学校化学研究, 2020, 36(3): 447-452.

HE Yilei, ZHANG Xing, WEI Yanze, CHEN Xiaoyu, WANG Zumin, YU Ranbo. Ti-MOF Derived N-Doped TiO₂ Nanostructure as Visible-light-driven Photocatalyst[J]. Chemical Research in Chinese Universities, 2020, 36(3): 447-452.

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Ti-MOF Derived N-Doped TiO₂ Nanostructure as Visible-light-driven Photocatalyst

Ti-MOF Derived N-Doped TiO₂ Nanostructure as Visible-light-driven Photocatalyst

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