Acid-base Vapor Sensing Enabled by ESIPT-attributed Cd(II) Coordination Polymer with Switchable Luminescence

doi:10.1007/s40242-020-0039-9

高等学校化学研究 ›› 2020, Vol. 36 ›› Issue (5): 755-759.doi: 10.1007/s40242-020-0039-9

Acid-base Vapor Sensing Enabled by ESIPT-attributed Cd(II) Coordination Polymer with Switchable Luminescence

FU Pengyan¹, MO Junting¹, SUN Sisi¹, YIN Shaoyun², WANG Haiping³, PAN Mei¹

1. MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, P. R. China;
2. Analysis and Test Center, Guangdong University of Technology, Guangzhou Higher Education Mega Center, Guangzhou 510006, P. R. China;
3. School of Biotechnology and Health Sciences, Wuyi University, Jiangmen 529020, P. R. China

收稿日期:2020-02-24 修回日期:2020-03-17 出版日期:2020-10-01 发布日期:2020-10-01
通讯作者: PAN Mei E-mail:panm@mail.sysu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21771197, 21821003, 21720102007), the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program, China(No.2017BT01C161), and the Fundamental Research Fund(FRF) for the Central Universities, China.

Acid-base Vapor Sensing Enabled by ESIPT-attributed Cd(II) Coordination Polymer with Switchable Luminescence

FU Pengyan¹, MO Junting¹, SUN Sisi¹, YIN Shaoyun², WANG Haiping³, PAN Mei¹

1. MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, P. R. China;
2. Analysis and Test Center, Guangdong University of Technology, Guangzhou Higher Education Mega Center, Guangzhou 510006, P. R. China;
3. School of Biotechnology and Health Sciences, Wuyi University, Jiangmen 529020, P. R. China

Received:2020-02-24 Revised:2020-03-17 Online:2020-10-01 Published:2020-10-01
Contact: PAN Mei E-mail:panm@mail.sysu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21771197, 21821003, 21720102007), the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program, China(No.2017BT01C161), and the Fundamental Research Fund(FRF) for the Central Universities, China.

摘要/Abstract

摘要： Fluorescence materials based on excited state intramolecular proton transfer(ESIPT) have attracted great attention due to the unique four-level energy states. Herein, we report the assembly of a Cd-L_F coordination polymer from purposely designed L_F(H₂hpi2cf) ligand, which can present switchable luminescence behavior by gain or loss protons originated in uncoordinated ESIPT sites and serve as acid-base vapor sensors. Fabricated into in-situ grown film or transparent ink by simple methods, Cd-L_F presents facile and portable amine sensor for food spoilage detection and fluorescent anti-counterfeiting ink applications.

关键词: Excited state intramolecular proton transfer, Coordination polymer, Acid-base vapor, Fluorescence sensor, Anti-counterfeiting ink

Abstract: Fluorescence materials based on excited state intramolecular proton transfer(ESIPT) have attracted great attention due to the unique four-level energy states. Herein, we report the assembly of a Cd-L_F coordination polymer from purposely designed L_F(H₂hpi2cf) ligand, which can present switchable luminescence behavior by gain or loss protons originated in uncoordinated ESIPT sites and serve as acid-base vapor sensors. Fabricated into in-situ grown film or transparent ink by simple methods, Cd-L_F presents facile and portable amine sensor for food spoilage detection and fluorescent anti-counterfeiting ink applications.

Key words: Excited state intramolecular proton transfer, Coordination polymer, Acid-base vapor, Fluorescence sensor, Anti-counterfeiting ink

FU Pengyan, MO Junting, SUN Sisi, YIN Shaoyun, WANG Haiping, PAN Mei. Acid-base Vapor Sensing Enabled by ESIPT-attributed Cd(II) Coordination Polymer with Switchable Luminescence[J]. 高等学校化学研究, 2020, 36(5): 755-759.

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Acid-base Vapor Sensing Enabled by ESIPT-attributed Cd(II) Coordination Polymer with Switchable Luminescence

Acid-base Vapor Sensing Enabled by ESIPT-attributed Cd(II) Coordination Polymer with Switchable Luminescence

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